Experimental studies on pore wetting and displacement of fluid by CO2 in porous media

The study of multiphase flow in porous media is highly relevant to many problems of great scientific importance, such as CO2 storage and enhanced oil recovery. Even though significant progress has been made in these areas, many challenges still remain. For instance, the leakage of stored CO2 may occur due to the capillary trapping failure of cap rock. Approximately 70% of oil cannot be easily recovered from underground, because the oil is held in tight porous rocks. Although CO2 storage and enhanced oil recovery are engineering processes at a geological scale, they are predominantly controlled by the transport and displacement of CO2 and reservoir fluids in aquifers and reservoirs, which are further controlled by wetting and fluid properties at pore scale. This work focuses on experimental investigations of pore-scale wetting and displacement of fluids and CO2 in porous core samples. Pore wetting, which has been measured based on contact angle, is a principal control on multiphase flow through porous media. However, contact angle measurement on other than flat surfaces still remains a challenge. In order to indicate the wetting in a small pore, a new pore contact angle measurement technique is developed in this study to directly measure the contact angles of fluids and CO2 in micron-sized pores. The equilibrium and dynamic contact angles of various liquids are directly measured in single glass capillaries, by studying the effects of surface tension, viscosity and chemical structure. The pore contact angles are compared with the contact angles on a planar substrate. The pore contact angle of a confined liquid in a glass capillary differs from the contact angle measured on a flat glass surface in an open space. Surface tension is not the only dominant factor affecting contact angle. The static contact angle in a glass pore also varies with liquid chemical structure. Viscosity and surface tension can significantly affect the dynamic pore contact angle. A new empirical correlation is developed based on our experimental data to describe dynamic pore wetting. The CO2-fluid contact angle in porous media is an important factor affecting the feasibility of long-term permanent CO2 storage. It determines CO2 flow and distribution in reservoirs or aquifers, and thus ultimately finally the storage capacity. CO2-fluid contact angles were measured in small water-wet pores and oil-wet pores, investigating the effect of CO2 phase (gas/liquid/supercritical). The CO2 phase significantly affects the CO2-fluid contact angle in an oil-wet pore. Supercritical CO2-fluid contact angles are larger than gas CO2-fluid contact angles, but are smaller than liquid CO2-fluid contact angles. However, this significant CO2 phase effect on contact angle was not observed in a water-wet pore. Another key issue considered in this study is two-phase flow displacement in porous media. This strongly relates to the important macroscopic parameters for multiphase flow transport in porous media, such as capillary pressure and relative permeability. Here CO2-water displacements are studied by conducting CO2 flooding experiments in a sandstone core sample, considering the effects of CO2 phase, pressure and CO2 injection rate. The capillary pressure-saturation curve, water production behaviour and relative permeability are investigated for gas CO2-water, liquid CO2-water and supercritical CO2-water displacements in porous media. The pressure-dependant drainage capillary pressures are obtained as a result of CO2-water interfacial tension. Various water production behaviours are obtained for gas CO2-water and liquid CO2-water displacements, mainly due to the effect of CO2 dissolution. The significant irregular capillary pressure-saturation curves and water production behaviors can be observed for the supercritical CO2-water displacements. The water and CO2 relative permeabilities for CO2-water displacements in a porous media are then predicted

Pore Wetting Phenomena: Implications to Enhanced Oil Recovery and Geologic Carbon Storage

AbstractPore wetting has been considered as an important factor in carbon storage and enhanced oil recovery. Previous studies were limited to the wetting measurements on flat substrates; few measurements were directly carried in a pore to indicate the pore wetting. In this paper, we used the pore contact angle measurement technique recently developed in our laboratory to measure the contact angles of fluids in a single capillary, by considering the effects of pore size, applied pressure and temperature and three different CO2 phases (gas, liquid and supercritical). The results indicate that the pore wetting only significantly changes on the CO2 phase transition boundary and then remains unchanged. The effects of pressure and temperature are not significant on the pore wetting when there is no CO2 phase variation. Our data conclude that the pore wetting of liquid in presence of CO2 is in the order of θgasCO2<θsupercritica CO2<θliqui CO2. The pore wetting varies with glass pore size and applied liquid. The contact angles measured in a glass pore are significantly different from the ones measured on a flat glass substrate

SDFE-LV: A Large-Scale, Multi-Source, and Unconstrained Database for Spotting Dynamic Facial Expressions in Long Videos

In this paper, we present a large-scale, multi-source, and unconstrained database called SDFE-LV for spotting the onset and offset frames of a complete dynamic facial expression from long videos, which is known as the topic of dynamic facial expression spotting (DFES) and a vital prior step for lots of facial expression analysis tasks. Specifically, SDFE-LV consists of 1,191 long videos, each of which contains one or more complete dynamic facial expressions. Moreover, each complete dynamic facial expression in its corresponding long video was independently labeled for five times by 10 well-trained annotators. To the best of our knowledge, SDFE-LV is the first unconstrained large-scale database for the DFES task whose long videos are collected from multiple real-world/closely real-world media sources, e.g., TV interviews, documentaries, movies, and we-media short videos. Therefore, DFES tasks on SDFE-LV database will encounter numerous difficulties in practice such as head posture changes, occlusions, and illumination. We also provided a comprehensive benchmark evaluation from different angles by using lots of recent state-of-the-art deep spotting methods and hence researchers interested in DFES can quickly and easily get started. Finally, with the deep discussions on the experimental evaluation results, we attempt to point out several meaningful directions to deal with DFES tasks and hope that DFES can be better advanced in the future. In addition, SDFE-LV will be freely released for academic use only as soon as possible

Shear degradation of corn starches with different amylose contents

This work investigated the effect of shear on the starch degradation, with a particular focus on the changes in molecular and lamellar structures. Corn starches with different amylose/amylopectin ratios (waxy corn starch, or WCS: 1:99; normal corn starch, or NCS: 25:75; and Gelose 80 starch, or G80: 80:20) were used as model materials to be processed using a Haake twin-rotor mixer for different times. Molecular and lamellar structural analysis was performed using size-exclusion chromatography (SEC) and small-angle X-ray scattering (SAXS). The degree of damage of starch at the granule level was evaluated by an assay kit. The results showed that amylose molecules in starch granules did not change significantly, while amylopectin molecules degraded to a stable size caused by the shear treatment. The average thickness of semi-crystalline lamellae disappeared rapidly during processing. A typical positive deviation from Porod's law at a high q region was observed, attributed to the presence of thermal density fluctuations or mixing within phases. Nonetheless, the degree of mixing within phases for the processed samples was lower than the native starch. The study of the mass fractal structure indicated that the scattering objects of the processed starches were more compact than those of the native counterparts. Furthermore, waxy corn starch (containing mostly amylopectin) experienced the greatest granule damage than the other starches. All the results showed that the rigid crystal structure in amylopectin is more sensitive to the shear treatment than the flexible amorphous structure in amylose. This mechanistic understanding at the microstructure level is helpful in designing the processing of starch-based foods or plastics with desired functional properties

Different genetic strategies to generate high amylose starch mutants by engineering the starch biosynthetic pathways

This review systematically documents the major different strategies of generating high-amylose (HAS) starch mutants aiming at providing high resistant starch, by engineering the starch biosynthesis metabolic pathways. We identify three main strategies based on a new representation of the starch structure: 'the building block backbone model': i) suppression of starch synthases for reduction of amylopectin (AP) side-chains; ii) suppression of starch branching enzymes (SBEs) for production of AM-like materials; and iii) suppression of debranching enzymes to restrain the transformation from over-branched pre-AP to more ordered AP. From a biosynthetic perspective, AM generated through the second strategy can be classified into two types: i) normal AM synthesized mainly by regular expression of granule-bound starch synthases, and ii) modified linear AP chains (AM-like material) synthesized by starch synthases due to the suppression of starch branching enzymes. The application of new breeding technologies, especially CRISPR, in the breeding of HAS crops is also reviewed

Food polymers functionality and applications

Food polymers are polymers from edible plants, animals, and microorganisms that can be used in food systems, including proteins, polysaccharides, and peptides. Generally, food polymers can be classified into three groups based on their sources: (1) plant-based food polymers, such as starch, dietary fiber, and cereal protein; (2) animal-based food polymers, such as meal protein; (3) microorganism-based food polymers, such as fungus polysaccharides. The oils and/or lipid from plant and animals could also be considered as food polymers although their molecular weights are relatively small

Study on the Growth Kinetics and Morphology of Methane Hydrate Film in a Porous Glass Microfluidic Device

Natural gas hydrates are widely considered one of the most promising green resources with large reserves. Most natural gas hydrates exist in deep-sea porous sediments. In order to achieve highly efficient exploration of natural gas hydrates, a fundamental understanding of hydrate growth becomes highly significant. Most hydrate film growth studies have been carried out on the surface of fluid droplets in in an open space, but some experimental visual works have been performed in a confined porous space. In this work, the growth behavior of methane hydrate film on pore interior surfaces was directly visualized and studied by using a transparent high-pressure glass microfluidic chip with a porous structure. The lateral growth kinetics of methane hydrate film was directly measured on the glass pore interior surface. The dimensionless parameter (−∆G/(RT)) presented by the Gibbs free energy change was used for the expression of driving force to explain the dependence of methane hydrate film growth kinetics and morphology on the driving force in confined pores. The thickening growth phenomenon of the methane hydrate film in micropores was also visualized. The results confirm that the film thickening growth process is mainly determined by water molecule diffusion in the methane hydrate film in glass-confined pores. The findings obtained in this work could help to develop a solid understanding on the formation and growth mechanisms of methane hydrate film in a confined porous space