571 research outputs found

    Quantum entanglement in plasmonic waveguides with near-zero mode indices

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    We investigate the quantum entanglement between two quantum dots in a plasmonic waveguide with near-zero mode index, considering the dependence of concurrence on interdot distance, quantum dot-waveguide frequency detuning and coupling strength ratio. High concurrence is achieved for a wide range of interdot distance due to the near-zero mode index, which largely relaxes the strict requirement of interdot distance in conventional dielectric waveguides or metal nanowires. The proposed quantum dot-waveguide system with near-zero phase variation along the waveguide near the mode cutoff frequency shows very promising potential in quantum optics and quantum information processing

    Nuclear spin relaxation in cold atom-molecule collisions

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    We explore the quantum dynamics of nuclear spin relaxation in cold collisions of 1Σ+^1\Sigma^+ molecules with structureless atoms in an external magnetic field. To this end, we develop a rigorous coupled-channel methodology, which accounts for rotational and nuclear spin degrees of freedom of 1Σ+^1\Sigma^+ molecules, their interaction with an external magnetic field, as well as for anisotropic atom-molecule interactions. We apply the methodology to study collisional relaxation of the nuclear spin sublevels of 13^{13}CO molecules immersed in a cold buffer gas of 4^4He atoms. We find that nuclear spin relaxation in the ground rotational manifold of CO occurs extremely slowly due to the absence of direct couplings between the nuclear spin sublevels. The rates of collisional transitions between the N=1N=1 nuclear spin states of CO are generally much higher due to the direct nuclear spin-rotation coupling between the states. These transitions obey selection rules, which depend on the values of space-fixed projections of rotational and nuclear spin angular momenta for the initial and final molecular states. For some initial states, we also observe a strong magnetic field dependence, which can be understood using the first Born approximation. We use our calculated nuclear spin relaxation rates to investigate the thermalization of a single nuclear spin state of CO(N=0)(N=0) immersed in a cold buffer gas of He. The calculated nuclear spin relaxation times (T10.5T_1\simeq 0.5 s at T=1T=1 K) display a steep temperature dependence decreasing rapidly at elevated temperatures due to the increased population of rotationally excited states, which undergo nuclear spin relaxation at a much faster rate. Thus, long relaxation times of N=0N=0 nuclear spin states in cold collisions with buffer gas atoms can only be maintained at sufficiently low temperatures (kT2BekT\ll 2B_e), where BeB_e is the rotational constant.Comment: 41 pages, 12 figure

    Influence of Fly Ash on Surface Chloride Concentration Under Shallow Immersion Condition

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    In this paper, the influence of fly ash content on concrete surface chloride concentration was investigated through periodical tests of surface chloride concentration of concrete by immersing three kinds of concrete specimens in 5.0 wt.% sodium chloride solution. One kind of specimen is common concrete without fly ash, whereas the other two kinds of specimens are mixed with fly ash. The results show that the surface chloride ion concentration ranges from 0.295 to 0.777 wt.% for the immersed concrete samples in this study; in the initial stage of immersion, the concrete surface chloride ion concentration is affected by added fly ash, and after 30 days of immersion, the surface chloride concentration of concrete with fly ash is 1.3 times that of concrete without fly ash at the same water–binder ratio; for the concretes without fly ash, the surface chloride concentration is linear with immersion time, whereas for the concrete with fly ash, the surface chloride concentration is nearly linear with square root of immersion time; for the concrete with fly ash, fly ash contents have little impact on the surface chloride concentration, and the surface chloride content of concrete without fly ash is gradually close to that of concrete with 15 and 30 wt.% of fly ash

    A cooperative domain model for multiple phase transitions and complex conformational relaxations in polymers with shape memory effect

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    Shape memory polymers (SMPs) are thermo-rheologically complex materials showing significant temperature and time dependences. Their segments often undergo cooperative phase transitions and conformational relaxations simultaneously along with shape memory effect (SME). In this study, a cooperative domain model is proposed to describe the composition dependence, multiple phase transitions and conformational relaxations of SMPs within their glass transition zones. Variations in local-area compositions and cooperative domains of the amorphous SMPs cause significant differences in their segmental relaxation. At a fixed domain size, both intermolecular activation energy and relaxation time significantly influence the SME and thermomechanical properties of the SMPs. Finally, the model is successfully applied to predict the shape memory behavior of SMPs with one stage SME and triple-SME, and the theoretical results have been validated by the experimental ones. This model could be a powerful tool to understand the working mechanisms and provide a theoretical guidance for the designs of multi-SME in SMPs

    Analysis and Design of the Reconfiguration Motion Qualities of a Deformable Robot Based on a Metamorphic Mechanism

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    Traditional wheel-legged ground mobile robots can only partially deform during wheel-leg switching, resulting in failure to achieve better environmental adaptability. Metamorphic mechanisms can be introduced into car structure designs. A new type of wheel-legged ground mobile robot, namely a deformable robot, is proposed in this study. Compared with traditional wheel-legged ground mobile robots, the deformable robot is capable of global reconfiguration, that is, when transitioning between the wheeled type (vehicle state) and the legged type (humanoid state), the shape, structure, degrees of freedom, and position of the centre of mass will change significantly. First, based on the characteristics of the wheel-legged compound motion, a structural model of the deformable robot was proposed and designed, and its reconfiguration motion was planned. Then, a kinematic model of the coupled reconfiguration process of the deformable robot was established. A horizontal lifting model was created to keep the front body level when lifting. The motion law of each active joint angle over time was designed based on the requirements of the reconfiguration motion smoothness. The criterion of reconfiguration stability was established and measures to improve it were proposed. Finally, based on the simulation verification of the smoothness, horizontality, and stability of the coupled reconfiguration of the system, a prototype of the deformable robot was developed, and a coupled reconfiguration experiment was conducted on an actual road surface. The experiment results show that the reconfiguration motion of the deformable robot between the vehicle state and the humanoid state had good motion qualities

    A hybrid quantum-classical algorithm for multichannel quantum scattering of atoms and molecules

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    We propose a hybrid quantum-classical algorithm for solving the time-independent Schr\"odinger equation for atomic and molecular collisions. The algorithm is based on the SS-matrix version of the Kohn variational principle, which computes the fundamental scattering SS-matrix by inverting the Hamiltonian matrix expressed in the basis of square-integrable functions. The computational bottleneck of the classical algorithm -- symmetric matrix inversion -- is addressed here using the variational quantum linear solver (VQLS), a recently developed noisy intermediate-scale quantum (NISQ) algorithm for solving systems of linear equations. We apply our algorithm to single and multichannel quantum scattering problems, obtaining accurate vibrational relaxation probabilities in collinear atom-molecule collisions. We also show how the algorithm could be scaled up to simulate collisions of large polyatomic molecules. Our results demonstrate that it is possible to calculate scattering cross sections and rates for complex molecular collisions on NISQ quantum processors, opening up the possibility of scalable digital quantum computation of gas-phase bimolecular collisions and reactions of relevance to astrochemistry and ultracold chemistry.Comment: 8 pages,6 figure
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