A triclinic polymorph with Z = 3 of N,N′-bis­(2-pyrid­yl)oxamide

The asymmetric unit of the title compound, C12H10N4O2, contains three half-mol­ecules. Each half-mol­ecule is completed by crystallographic inversion symmetry. The title compound, (I), is a polymorph of the structure, (II), reported by Hsu & Chen [Eur. J. Inorg. Chem. (2004), 1488–1493]. In the original report, the compound crystallized in the tetra­gonal space group P 21c (Z = 8), whereas the structure reported here is triclinic (P , Z = 3). In both forms, each oxamide mol­ecule is almost planar (with maximum deviations are 0.266 and 0.166 Å) and the O atoms are trans oriented. The principal difference between the two forms lies in the different hydrogen-bonding patterns. In (I), two N—H⋯O and one N—H⋯N hydrogen bonds link the mol­ecules, forming a two-dimensional network, whereas in (II) there are no classical hydrogen bonds to O atoms and only weak C—H⋯O inter­actions are found along with rings of N—H⋯N bonds

DEFormer: DCT-driven Enhancement Transformer for Low-light Image and Dark Vision

The goal of low-light image enhancement is to restore the color and details of the image and is of great significance for high-level visual tasks in autonomous driving. However, it is difficult to restore the lost details in the dark area by relying only on the RGB domain. In this paper we introduce frequency as a new clue into the network and propose a novel DCT-driven enhancement transformer (DEFormer). First, we propose a learnable frequency branch (LFB) for frequency enhancement contains DCT processing and curvature-based frequency enhancement (CFE). CFE calculates the curvature of each channel to represent the detail richness of different frequency bands, then we divides the frequency features, which focuses on frequency bands with richer textures. In addition, we propose a cross domain fusion (CDF) for reducing the differences between the RGB domain and the frequency domain. We also adopt DEFormer as a preprocessing in dark detection, DEFormer effectively improves the performance of the detector, bringing 2.1% and 3.4% improvement in ExDark and DARK FACE datasets on mAP respectively.Comment: submit to ICRA202

Recurrence and Polya number of general one-dimensional random walks

The recurrence properties of random walks can be characterized by P\'{o}lya number, i.e., the probability that the walker has returned to the origin at least once. In this paper, we consider recurrence properties for a general 1D random walk on a line, in which at each time step the walker can move to the left or right with probabilities $l$ and $r$, or remain at the same position with probability $o$ ($l+r+o=1$). We calculate P\'{o}lya number $P$ of this model and find a simple expression for $P$ as, $P=1-\Delta$, where $\Delta$ is the absolute difference of $l$ and $r$ ($\Delta=|l-r|$). We prove this rigorous expression by the method of creative telescoping, and our result suggests that the walk is recurrent if and only if the left-moving probability $l$ equals to the right-moving probability $r$.Comment: 3 page short pape

A supramolecular microporous network of zinc(II) coordination polymer for highly selective fluorescent detection of Pb2+

A hydrogen bonded microporous network with Lewis basic N sites, viz., {[Zn(TZ-HIP)(HPYTZ)(H2O)2]·3H2O}n [TZ-HIP = 5-(tetrazol-5-yl)isophthalic acid, HPYTZ = 3,5-di(4-pyridyl)-1H-1,2,4- triazolate ligand] has been obtained from the dual ligand system of polydentate N-heterocyclic carboxylate and dipyridyl-type ligands. Single crystal X-ray diffraction analysis shows that the adjacent Zn(II) centers are bridged by HTZ-H2IP ligand to form 1D chain with HPYTZ molecules as free lateral arms. The paralleled chains are connected by H-bonding interactions to produce the 3D microporous network with 1D pores. It is interesting that the uncoordinated N atoms (Lewis base sites) pores cause Pb2+ ions to produce a remarkably enhancing effect on the luminescent intensity of the zinc complex with high sensitivity in the detection range of 10-3-10-5mol L-1 concentration limit. This coordination polymer may be used as a sensing material for developing a highly selective and sensitive Pb2+ sensor in the biological and environmental materials.

Comparative mRNA and miRNA expression in European mouflon (Ovis musimon) and sheep (Ovis aries) provides novel insights into the genetic mechanisms for female reproductive success

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Effect of post-peak cyclic load on mechanics and seepage characteristics of sandstone under different confining pressures

The mining disturbance causes the rock mass in a certain range of the coal seam floor to be in a post-peak state. Due to the excavation of adjacent roadways and the mining of coal seams, the post-peak rock mass undergoes a cyclic loading-unloading process. In order to explore the influence of post-peak cyclic loading on rock mass structure under different in-situ stress environments and clarify the gestation process of disasters such as water inrush from coal seam floor, post-peak cyclic loading tests of sandstone under 5,10,15,20,25 MPa confining pressure were carried out based on Rock Top multi-field coupling tester. The results show that: ① Before the post-peak cyclic loading, the unit permeability of rock shows a rapid decline-tend to be stable-sudden rise-sudden decline-tend to be stable. In the post-peak cycle stage, the unit permeability of rock is almost inverted with the axial load. ② Rock elastic modulus, crack closure stress, crack initiation stress, damage stress, peak stress and residual stress are positively correlated with confining pressure, while Poisson 's ratio increases first and then decreases with the increase of confining pressure. ③ Under the confining pressure of 5 and 10 MPa, the intermittent failure of rock occurs, and the brittle failure characteristics are weakened. Under the confining pressure of 15, 20 and 25 MPa, the brittle failure characteristics of rock are obvious, and the failure characteristics of rock are determined by the properties of rock itself. ④ The post-peak axial load mainly promotes the increase of rock permeability, but the promotion effect is weaker than that of confining pressure on rock permeability, and confining pressure is the dominant factor affecting the post-peak permeability change of rock. ⑤ Under different confining pressures, a through-shear crack occurs in all rocks, but with the increase of confining pressure, the degree of rock failure gradually weakens and the failure mode tends to be simple