Deformation mechanisms in nanotwinned metal nanopillars

Nanotwinned metals are attractive in many applications because they simultaneously demonstrate high strength and high ductility, characteristics that are usually thought to be mutually exclusive. However, most nanotwinned metals are produced in polycrystalline forms and therefore contain randomly oriented twin and grain boundaries making it difficult to determine the origins of their useful mechanical properties. Here, we report the fabrication of arrays of vertically aligned copper nanopillars that contain a very high density of periodic twin boundaries and no grain boundaries or other microstructural features. We use tension experiments, transmission electron microscopy and atomistic simulations to investigate the influence of diameter, twin-boundary spacing and twin-boundary orientation on the mechanical responses of individual nanopillars. We observe a brittle-to-ductile transition in samples with orthogonally oriented twin boundaries as the twin-boundary spacing decreases below a critical value (~3–4 nm for copper). We also find that nanopillars with slanted twin boundaries deform via shear offsets and significant detwinning. The ability to decouple nanotwins from other microstructural features should lead to an improved understanding of the mechanical properties of nanotwinned metals

Learning the Course of Design and Analyze of Computer Algorithms via Online Coding

The course of design and analysis of computer algorithms is one of the core-course of computer science education; this paper presents an online coding framework to help students to learn the course of design and ananlysis of computer algorithms and other coding-related courses in computer science. With the online coding framework, a student can edit code in any web browser, and then executes it. This online coding framework can connect teachers, curriculum authors, and students in a unique social experience by tracking and streaming progress updates in real time. In particular, with the newly proposed framework, it is not difficult to find interesting and unexpected input values during students’practicing, and then help them to understand what their code is actually doing.DOI: http://dx.doi.org/10.11591/ijere.v2i3.257

Lubrication in Chemical and Mechanical Planarization

Chemical mechanical planarization (CMP) has been widely used in integrated circuit (IC) processing to achieve both local and global surface planarity through combined chemical and mechanical actions. The lubrication plays a significant role in CMP and can be determined by the Stribeck curve since it provides direct evidence of the extent of contact among wafer, pad asperities, and slurry particles. The advancements in the construction of the Stribeck curve are highlighted in this chapter. Traditionally, the procedure for constructing the Stribeck curve is as follows: (1) polish wafers at various pressures and sliding velocities to obtain the coefficient of friction (COF) values; (2) plot the experimental data as COF vs. Sommerfeld number; (3) construct the Stribeck curve via curve fitting. Recently, an alternative method was presented to construct the Stribeck curve via only performing one wafer polishing experiment. Pressure and sliding velocity are varied separately or together for a desired length of time, so that multiple measurements can be taken within one run. In this study, a back-propagation (BP) neural network is proposed to construct the Stribeck curve. Results show that the BP neural network could construct a more accurate Stribeck curve and thus could better provide insight into the lubrication mechanism of CMP processes

Parameter Estimation for Partial Differential Equations by Collage-Based Numerical Approximation

The inverse problem of using measurements to estimate unknown parameters of a system often arises in engineering practice and scientific research. This paper proposes a Collage-based parameter inversion framework for a class of partial differential equations. The Collage method is used to convert the parameter estimation inverse problem into a minimization problem of a function of several variables after the partial differential equation is approximated by a differential dynamical system. Then numerical schemes for solving this minimization problem are proposed, including grid approximation and ant colony optimization. The proposed schemes are applied to a parameter estimation problem for the Belousov-Zhabotinskii equation, and the results show that the proposed approximation method is efficient for both linear and nonlinear partial differential equations with respect to unknown parameters. At worst, the presented method provides an excellent starting point for traditional inversion methods that must first select a good starting point

Study on the application of a new multiepoxy reinforcement agent for sheep leather

Content: Leather is a kind of natural biomass composite material which is made of animal skin as material by a series of chemical and physical processing. Its main structure is Collagen fibers of three-dimensional network structure. As we all know sheep leather always exist a common problem with low strength, while the strength of leather depended on the woven degree of collagen fibers. Through the past decades, many methods have been tried to improve the properties of sheep leather. The most commonly used methods are retanning. However, the strength enhancement of sheep leather is extremely limited by retanning, although the fullness and softness may be improved. In this study, a new type of multi-epoxy reinforcement agent (IGE) and IGE with the synergistic effect of polyamine (IGE-PA) were used to enhance the strength of sheep leather in tanning and fatliquoring process. Comparing with chromium tanned leather, it was found that under the optimized conditions (dosage: 10%, pH: 8, Temperature: 35℃ for penetration and 45℃ for fixation, tanning time: 10 h) with IGE as the main tanning agent, the tearing strength was increased 56.8%. While when the polyamine as the synergetic agent for IGE, the tearing strength was significantly increased 87.9%. While IGE and IGE-PA were used in fatliquoring process, it has significant reinforcement effect for tetrakis hydroxymethyl phosphonium (THP) salt tanned leather. It was found that under the optimized conditions (Dosage: 2.5%, pH: 7-8, Temperature: 50℃, Time: 2h) with IGE in fatliquoring process, the tear strength was increased 50.24%, while the IGE-PA was used, the tear strength was increased 64.3%. Furthermore, TGA results showed that decomposition temperatures of IGE and IGE-PA enhanced leather were all higher than traditional chromium tanned leather. In addition, SEM results showed that IGE and IGE-PA enhanced leather obtained better opened-up fiber structure. Take-Away: 1. A new type of multi-epoxy tanning agent (IGE) has reinforcement effect for sheep leather especially in tear strength. 2. IGE with the synergistic effect of polyamine (IGE-PA) were used in tanning process, which has a significant enhancement for the sheep leather. 3. IGE and IGE-PA can be also used in fatliquoring process to enhance the strength of sheep leather

Multiple Positive Periodic Solutions for a Gilpin-Ayala Competition Predator-Prey System with Harvesting Terms

By applying Mawhin’s continuation theorem of coincidence degree theory, we study the existence of multiple positive periodic solutions for a Gilpin-Ayala competition predator-prey system with harvesting terms and obtain some sufficient conditions for the existence of multiple positive periodic solutions for the system under consideration. The result of this paper is completely new. An example is employed to illustrate our result

Nonsense-Mediated RNA Decay Influences Human Embryonic Stem Cell Fate.

Nonsense-mediated RNA decay (NMD) is a highly conserved pathway that selectively degrades specific subsets of RNA transcripts. Here, we provide evidence that NMD regulates early human developmental cell fate. We found that NMD factors tend to be expressed at higher levels in human pluripotent cells than in differentiated cells, raising the possibility that NMD must be downregulated to permit differentiation. Loss- and gain-of-function experiments in human embryonic stem cells (hESCs) demonstrated that, indeed, NMD downregulation is essential for efficient generation of definitive endoderm. RNA-seq analysis identified NMD target transcripts induced when NMD is suppressed in hESCs, including many encoding signaling components. This led us to test the role of TGF-β and BMP signaling, which we found NMD acts through to influence definitive endoderm versus mesoderm fate. Our results suggest that selective RNA decay is critical for specifying the developmental fate of specific human embryonic cell lineages

Neural Temporal Dynamics of Facial Emotion Processing: Age Effects and Relationship to Cognitive Function

This study used event-related potentials (ERPs) to investigate the effects of age on neural temporal dynamics of processing task-relevant facial expressions and their relationship to cognitive functions. Negative (sad, afraid, angry, and disgusted), positive (happy), and neutral faces were presented to 30 older and 31 young participants who performed a facial emotion categorization task. Behavioral and ERP indices of facial emotion processing were analyzed. An enhanced N170 for negative faces, in addition to intact right-hemispheric N170 for positive faces, was observed in older adults relative to their younger counterparts. Moreover, older adults demonstrated an attenuated within-group N170 laterality effect for neutral faces, while younger adults showed the opposite pattern. Furthermore, older adults exhibited sustained temporo-occipital negativity deflection over the time range of 200–500 ms post-stimulus, while young adults showed posterior positivity and subsequent emotion-specific frontal negativity deflections. In older adults, decreased accuracy for labeling negative faces was positively correlated with Montreal Cognitive Assessment Scores, and accuracy for labeling neutral faces was negatively correlated with age. These findings suggest that older people may exert more effort in structural encoding for negative faces and there are different response patterns for the categorization of different facial emotions. Cognitive functioning may be related to facial emotion categorization deficits observed in older adults. This may not be attributable to positivity effects: it may represent a selective deficit for the processing of negative facial expressions in older adults