Design of uni-traveling-carrier photodiode With Nanoscale Optical Microstructures

In this article, we report a uni-traveling-carrier photodiode (UTC-PD) incorporating nanoscale optical microstructures. We design a waveguide-based UTC-PD containing an internal optical scattering structure to convert incident light from vertical incidence to lateral propagation and to constrain the light within the absorption layer of the UTC-PD as much as possible. In this way, the proposed UTC-PD can have an operating performance like that of a waveguide-type PD under vertical light incidence, and its responsivity will increase. The ideal responsivity of the designed UTC-PD with an absorption layer thickness of 200nm after optimization can reach 0.43A/W, which is 48% higher than that of the traditional structure

New Insight into the Atomic Structure of Electrochemically Delithiated O3-Li_{(1–<i>x</i>)}CoO₂ (0 ≤ <i>x</i> ≤ 0.5) Nanoparticles

Direct observation of delithiated structures of LiCoO₂ at atomic scale has been achieved using spherical aberration-corrected scanning transmission electron microscopy (STEM) with high-angle annular-dark-field (HAADF) and annular-bright-field (ABF) techniques. The ordered Li, Co, and O columns for LiCoO₂ nanoparticles are clearly identified in ABF micrographs. Upon the Li ions extraction from LiCoO₂, the Co-contained (003) planes distort from the bulk to the surface region and the <i>c</i>-axis is expanded significantly. Ordering of lithium ions and lithium vacancies has been observed directly and explained by first-principles simulation. On the basis of HAADF micrographs, it is found that the phase irreversibly changes from O3-type in pristine LiCoO₂ to O1-type Li_<i>x</i>CoO₂ (<i>x</i> ≈ 0.50) after the first electrochemical Li extraction and back to O2-type Li_<i>x</i>CoO₂ (<i>x</i> ≈ 0.93) rather than to O3-stacking after the first electrochemical lithiation. This is the first report of finding O2-Li_<i>x</i>CoO₂ in the phase diagram of O3-LiCoO₂, through which the two previously separated LiCoO₂ phases, i.e. O2 and O3 systems, are connected. These new investigations shed new insight into the lithium storage mechanism in this important cathode material for Li-ion batteries