Determining layer number of two dimensional flakes of transition-metal dichalcogenides by the Raman intensity from substrate

Transition-metal dichalcogenide (TMD) semiconductors have been widely studied due to their distinctive electronic and optical properties. The property of TMD flakes is a function of its thickness, or layer number (N). How to determine N of ultrathin TMDs materials is of primary importance for fundamental study and practical applications. Raman mode intensity from substrates has been used to identify N of intrinsic and defective multilayer graphenes up to N=100. However, such analysis is not applicable for ultrathin TMD flakes due to the lack of a unified complex refractive index ($\tilde{n}$) from monolayer to bulk TMDs. Here, we discuss the N identification of TMD flakes on the SiO$_2$/Si substrate by the intensity ratio between the Si peak from 100-nm (or 89-nm) SiO$_2$/Si substrates underneath TMD flakes and that from bare SiO$_2$/Si substrates. We assume the real part of $\tilde{n}$ of TMD flakes as that of monolayer TMD and treat the imaginary part of $\tilde{n}$ as a fitting parameter to fit the experimental intensity ratio. An empirical $\tilde{n}$, namely, $\tilde{n}_{eff}$, of ultrathin MoS$_{2}$, WS$_{2}$ and WSe$_{2}$ flakes from monolayer to multilayer is obtained for typical laser excitations (2.54 eV, 2.34 eV, or 2.09 eV). The fitted $\tilde{n}_{eff}$ of MoS$_{2}$ has been used to identify N of MoS$_{2}$ flakes deposited on 302-nm SiO$_2$/Si substrate, which agrees well with that determined from their shear and layer-breathing modes. This technique by measuring Raman intensity from the substrate can be extended to identify N of ultrathin 2D flakes with N-dependent $\tilde{n}$ . For the application purpose, the intensity ratio excited by specific laser excitations has been provided for MoS$_{2}$, WS$_{2}$ and WSe$_{2}$ flakes and multilayer graphene flakes deposited on Si substrates covered by 80-110 nm or 280-310 nm SiO$_2$ layer.Comment: 10 pages, 4 figures. Accepted by Nanotechnolog

Tree-Structured Neural Machine for Linguistics-Aware Sentence Generation

Different from other sequential data, sentences in natural language are structured by linguistic grammars. Previous generative conversational models with chain-structured decoder ignore this structure in human language and might generate plausible responses with less satisfactory relevance and fluency. In this study, we aim to incorporate the results from linguistic analysis into the process of sentence generation for high-quality conversation generation. Specifically, we use a dependency parser to transform each response sentence into a dependency tree and construct a training corpus of sentence-tree pairs. A tree-structured decoder is developed to learn the mapping from a sentence to its tree, where different types of hidden states are used to depict the local dependencies from an internal tree node to its children. For training acceleration, we propose a tree canonicalization method, which transforms trees into equivalent ternary trees. Then, with a proposed tree-structured search method, the model is able to generate the most probable responses in the form of dependency trees, which are finally flattened into sequences as the system output. Experimental results demonstrate that the proposed X2Tree framework outperforms baseline methods over 11.15% increase of acceptance ratio

Throughput Maximization Leveraging Just-Enough SNR Margin and Channel Spacing Optimization

Flexible optical network is a promising technology to accommodate high-capacity demands in next-generation networks. To ensure uninterrupted communication, existing lightpath provisioning schemes are mainly done with the assumption of worst-case resource under-provisioning and fixed channel spacing, which preserves an excessive signal-to-noise ratio (SNR) margin. However, under a resource over-provisioning scenario, the excessive SNR margin restricts the transmission bit-rate or transmission reach, leading to physical layer resource waste and stranded transmission capacity. To tackle this challenging problem, we leverage an iterative feedback tuning algorithm to provide a just-enough SNR margin, so as to maximize the network throughput. Specifically, the proposed algorithm is implemented in three steps. First, starting from the high SNR margin setup, we establish an integer linear programming model as well as a heuristic algorithm to maximize the network throughput by solving the problem of routing, modulation format, forward error correction, baud-rate selection, and spectrum assignment. Second, we optimize the channel spacing of the lightpaths obtained from the previous step, thereby increasing the available physical layer resources. Finally, we iteratively reduce the SNR margin of each lightpath until the network throughput cannot be increased. Through numerical simulations, we confirm the throughput improvement in different networks and with different baud-rates. In particular, we find that our algorithm enables over 20\% relative gain when network resource is over-provisioned, compared to the traditional method preserving an excessive SNR margin.Comment: submitted to IEEE JLT, Jul. 17th, 2021. 14 pages, 8 figure

Throughput Maximization in Multi-Band Optical Networks with Column Generation

Multi-band transmission is a promising technical direction for spectrum and capacity expansion of existing optical networks. Due to the increase in the number of usable wavelengths in multi-band optical networks, the complexity of resource allocation problems becomes a major concern. Moreover, the transmission performance, spectrum width, and cost constraint across optical bands may be heterogeneous. Assuming a worst-case transmission margin in U, L, and C-bands, this paper investigates the problem of throughput maximization in multi-band optical networks, including the optimization of route, wavelength, and band assignment. We propose a low-complexity decomposition approach based on Column Generation (CG) to address the scalability issue faced by traditional methodologies. We numerically compare the results obtained by our CG-based approach to an integer linear programming model, confirming the near-optimal network throughput. Our results also demonstrate the scalability of the CG-based approach when the number of wavelengths increases, with the computation time in the magnitude order of 10 s for cases varying from 75 to 1200 wavelength channels per link in a 14-node network.Comment: 6 pages, 4 figures, submitted to IEEE International Conference on Communications 2024 (ICC2024). (Note on arXiv: for beginners in the area of column generation, please refer to the example computation in the file . I have uploaded it to this arXiv project along with other source files.

Maximizing Revenue With Adaptive Modulation and Multiple FECs in Flexible Optical Networks

Flexible optical networks (FONs) are being adopted to accommodate the increasingly heterogeneous traffic in today's Internet. However, in presence of high traffic load, not all offered traffic can be satisfied at all time. As carried traffic load brings revenues to operators, traffic blocking due to limited spectrum resource leads to revenue losses. In this study, given a set of traffic requests to be provisioned, we consider the problem of maximizing operator's revenue, subject to limited spectrum resource and physical layer impairments (PLIs), namely amplified spontaneous emission noise (ASE), self-channel interference (SCI), cross-channel interference (XCI), and node crosstalk. In FONs, adaptive modulation, multiple FEC, and the tuning of power spectrum density (PSD) can be effectively employed to mitigate the impact of PLIs. Hence, in our study, we propose a universal bandwidth-related impairment evaluation model based on channel bandwidth, which allows a performance analysis for different PSD, FEC and modulations. Leveraging this PLI model and a piecewise linear fitting function, we succeed to formulate the revenue maximization problem as a mixed integer linear program. Then, to solve the problem on larger network instances, a fast two-phase heuristic algorithm is also proposed, which is shown to be near-optimal for revenue maximization. Through simulations, we demonstrate that using adaptive modulation enables to significantly increase revenues in the scenario of high signal-to-noise ratio (SNR), where the revenue can even be doubled for high traffic load, while using multiple FECs is more profitable for scenarios with low SNR

Telomere Recombination Accelerates Cellular Aging in Saccharomyces cerevisiae

Telomeres are nucleoprotein structures located at the linear ends of eukaryotic chromosomes. Telomere integrity is required for cell proliferation and survival. Although the vast majority of eukaryotic species use telomerase as a primary means for telomere maintenance, a few species can use recombination or retrotransposon-mediated maintenance pathways. Since Saccharomyces cerevisiae can use both telomerase and recombination to replicate telomeres, budding yeast provides a useful system with which to examine the evolutionary advantages of telomerase and recombination in preserving an organism or cell under natural selection. In this study, we examined the life span in telomerase-null, post-senescent type II survivors that have employed homologous recombination to replicate their telomeres. Type II recombination survivors stably maintained chromosomal integrity but exhibited a significantly reduced replicative life span. Normal patterns of cell morphology at the end of a replicative life span and aging-dependent sterility were observed in telomerase-null type II survivors, suggesting the type II survivors aged prematurely in a manner that is phenotypically consistent with that of wild-type senescent cells. The shortened life span of type II survivors was extended by calorie restriction or TOR1 deletion, but not by Fob1p inactivation or Sir2p over-expression. Intriguingly, rDNA recombination was decreased in type II survivors, indicating that the premature aging of type II survivors was not caused by an increase in extra-chromosomal rDNA circle accumulation. Reintroduction of telomerase activity immediately restored the replicative life span of type II survivors despite their heterogeneous telomeres. These results suggest that telomere recombination accelerates cellular aging in telomerase-null type II survivors and that telomerase is likely a superior telomere maintenance pathway in sustaining yeast replicative life span

2,2′-[(1E)-3-Phenyl­prop-2-ene-1,1-di­yl]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)

In the title mol­ecule, C25H30O4, the two cyclo­hexene rings adopt envelope conformations. The two hy­droxy groups are involved in the formation of intra­molecular O—H⋯O hydrogen bonds. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds link mol­ecules related by translation along the axis a into chains