Anharmonic force field and vibrational frequencies of tetrafluoromethane (CF4_4) and tetrafluorosilane (SiF4_4)

Accurate quartic anharmonic force fields for CF$_4$ and SiF$_4$ have been calculated using the CCSD(T) method and basis sets of $spdf$ quality. Based on the {\it ab initio} force field with a minor empirical adjustment, the vibrational energy levels of these two molecules and their isotopomers are calculated by means of high order Canonical Van Vleck Perturbation Theory(CVPT) based on curvilinear coordinates. The calculated energies agree very well with the experimental data. The full quadratic force field of CF$_4$ is further refined to the experimental data. The symmetrization of the Cartesian basis for any combination bands of $T_d$ group molecules is discussed using the circular promotion operator for the doubly degenerate modes, together with tabulated vector coupling coefficients. The extraction of the spectroscopic constants from our second order transformed Hamiltonian in curvilinear coordinates is discussed, and compared to a similar procedure in rectilinear coordinates.Comment: (submitted to J. Chem. Phys.

Image Storage in Hot Vapors

We theoretically investigate image propagation and storage in hot atomic vapor. A $4f$ system is adopted for imaging and an atomic vapor cell is placed over the transform plane. The Fraunhofer diffraction pattern of an object in the object plane can thus be transformed into atomic Raman coherence according to the idea of ``light storage''. We investigate how the stored diffraction pattern evolves under diffusion. Our result indicates, under appropriate conditions, that an image can be reconstructed with high fidelity. The main reason for this procedure to work is the fact that diffusion of opposite-phase components of the diffraction pattern interfere destructively.Comment: 11 pages, 3 figure

Excitation of nonlinear ion acoustic waves in CH plasmas

Excitation of nonlinear ion acoustic wave (IAW) by an external electric field is demonstrated by Vlasov simulation. The frequency calculated by the dispersion relation with no damping is verified much closer to the resonance frequency of the small-amplitude nonlinear IAW than that calculated by the linear dispersion relation. When the wave number $k\lambda_{De}$ increases, the linear Landau damping of the fast mode (its phase velocity is greater than any ion's thermal velocity) increases obviously in the region of $T_i/T_e < 0.2$ in which the fast mode is weakly damped mode. As a result, the deviation between the frequency calculated by the linear dispersion relation and that by the dispersion relation with no damping becomes larger with $k\lambda_{De}$ increasing. When $k\lambda_{De}$ is not large, such as $k\lambda_{De}=0.1, 0.3, 0.5$, the nonlinear IAW can be excited by the driver with the linear frequency of the modes. However, when $k\lambda_{De}$ is large, such as $k\lambda_{De}=0.7$, the linear frequency can not be applied to exciting the nonlinear IAW, while the frequency calculated by the dispersion relation with no damping can be applied to exciting the nonlinear IAW.Comment: 10 pages, 9 figures, Accepted by POP, Publication in August 1

Decentralized Estimation over Orthogonal Multiple-access Fading Channels in Wireless Sensor Networks - Optimal and Suboptimal Estimators

Optimal and suboptimal decentralized estimators in wireless sensor networks (WSNs) over orthogonal multiple-access fading channels are studied in this paper. Considering multiple-bit quantization before digital transmission, we develop maximum likelihood estimators (MLEs) with both known and unknown channel state information (CSI). When training symbols are available, we derive a MLE that is a special case of the MLE with unknown CSI. It implicitly uses the training symbols to estimate the channel coefficients and exploits the estimated CSI in an optimal way. To reduce the computational complexity, we propose suboptimal estimators. These estimators exploit both signal and data level redundant information to improve the estimation performance. The proposed MLEs reduce to traditional fusion based or diversity based estimators when communications or observations are perfect. By introducing a general message function, the proposed estimators can be applied when various analog or digital transmission schemes are used. The simulations show that the estimators using digital communications with multiple-bit quantization outperform the estimator using analog-and-forwarding transmission in fading channels. When considering the total bandwidth and energy constraints, the MLE using multiple-bit quantization is superior to that using binary quantization at medium and high observation signal-to-noise ratio levels

Heavy-tailed statistics in short-message communication

Short-message (SM) is one of the most frequently used communication channels in the modern society. In this Brief Report, based on the SM communication records provided by some volunteers, we investigate the statistics of SM communication pattern, including the interevent time distributions between two consecutive short messages and two conversations, and the distribution of message number contained by a complete conversation. In the individual level, the current empirical data raises a strong evidence that the human activity pattern, exhibiting a heavy-tailed interevent time distribution, is driven by a non-Poisson nature.Comment: 4 pages, 4 figures and 1 tabl