28,285 research outputs found
Tests of a Novel Design of Resistive Plate Chambers
A novel design of Resistive Plate Chambers (RPCs), using only a single
resistive plate, is being proposed. Based on this design, two large size
prototype chambers were constructed and were tested with cosmic rays and in
particle beams. The tests confirmed the viability of this new approach. In
addition to showing an improved single-particle response compared to the
traditional 2-plate design, the novel chambers also prove to be suitable for
calorimetric applications
Metal-organic-frameworks derived cobalt embedded in various carbon structures as bifunctional electrocatalysts for oxygen reduction and evolution reactions
This is the final version of the article. Available from Springer Nature via the DOI in this record.A series of nanocomposites of cobalt embedded in N-doped nanoporous carbons, carbon nanotubes or hollow carbon onions have been synthesized by a one-step carbonization of metal-organic-framework ZIF-67. The effect of the carbonization temperature on the structural evolution of the resulting nanocomposites has been investigated in detail. Among the as-synthesized materials, the cobalt/nanoporous N-doped carbon composites have demonstrated excellent electrocatalytic activities and durability towards oxygen reduction reaction in alkaline medium. Compared to the benchmark Pt/C catalyst, the optimized Co@C-800 (carbonized at 800 °C) exhibited high oxygen reduction reaction activity with an onset potential of 0.92 V, and a half-wave potential of 0.82 V. Moreover, the optimized Co@C-800 also showed enhanced electrocatalytic activity towards oxygen evolution reaction from water splitting, with a low onset potential of 1.43 V and a potential of 1.61 V at 10 mA cm−2 current density. This work offered a simple solution to develop metal-organic-framework-derived materials for highly efficient electrochemical applications.The financial support by the EPSRC (EP/N034627/1), Royal Society and University of Exeter is greatly acknowledged
Momentum Distribution of Near-Zero-Energy Photoelectrons in the Strong-Field Tunneling Ionization in the Long Wavelength Limit
We investigate the ionization dynamics of Argon atoms irradiated by an
ultrashort intense laser of a wavelength up to 3100 nm, addressing the momentum
distribution of the photoelectrons with near-zero-energy. We find a surprising
accumulation in the momentum distribution corresponding to meV energy and a
\textquotedblleft V"-like structure at the slightly larger transverse momenta.
Semiclassical simulations indicate the crucial role of the Coulomb attraction
between the escaping electron and the remaining ion at extremely large
distance. Tracing back classical trajectories, we find the tunneling electrons
born in a certain window of the field phase and transverse velocity are
responsible for the striking accumulation. Our theoretical results are
consistent with recent meV-resolved high-precision measurements.Comment: 5 pages, 4 figure
Large exchange bias after zero-field cooling from an unmagnetized state
Exchange bias (EB) is usually observed in systems with interface between
different magnetic phases after field cooling. Here we report an unusual
phenomenon in which a large EB can be observed in Ni-Mn-In bulk alloys after
zero-field cooling from an unmagnetized state. We propose this is related to
the newly formed interface between different magnetic phases during the initial
magnetization process. The magnetic unidirectional anisotropy, which is the
origin of EB effect, can be created isothermally below the blocking
temperature.Comment: including supplementary information, Accepted by Physical Review
Letter
Analytic Spectra of CMB Anisotropies and Polarization Generated by Relic Gravitational Waves with Modification due to Neutrino Free-Streaming
We present an analytical calculation of the spectra of CMB anisotropies and
polarizations generated by relic gravitational waves (RGWs). As a substantial
extension to the previous studies, three new ingredients are included in this
work. Firstly, the analytic and are given; especially the
latter can be useful to extract signal of RGWs from the observed data in the
zero multipole method. Secondly, a fitting formula of the decaying factor on
small scales is given, coming from the visibility function around the photon
decoupling. Thirdly, the impacts by the neutrino free-streaming (NFS) is
examined, a process that occurred in the early universe and leaves observable
imprints on CMB via RGWs.
It is found that the analytic and have profiles
agreeing with the numeric ones, except that in a range
and the trough of around have some deviations.
With the new damping factor, the analytic and match with
the numeric ones with the maximum errors only up to the first three
peaks for , improving the previous studies substantially. The
correspondence of the positions of peaks of and those of RGWs are
also demonstrated explicitly. We also find that NFS reduces the amplitudes of
by for and shifts slightly
their peaks to smaller angles. Detailed analyses show that the zero multipoles
, where crosses 0, are shifted to larger values by NFS. This
shifting effect is as important as those causedby different inflation models
and different baryon fractions.Comment: 17 pages, 7 figures. accepted by PR
Measurements of the Rate Capability of Various Resistive Plate Chambers
Resistive Plate Chambers (RPCs) exhibit a significant loss of efficiency for
the detection of particles, when subjected to high particle fluxes. This rate
limitation is related to the usually high resistivity of the resistive plates
used in their construction. This paper reports on measurements of the
performance of three different glass RPC designs featuring a different total
resistance of the resistive plates. The measurements were performed with 120
GeV protons at varying beam intensitie
Improved Hydrogen Release from Ammonia Borane Confined in Microporous Carbon with Narrow Pore Size Distribution
This is the author accepted manuscript. The final version is available from Royal Society of Chemistry via the DOI in this record.Ammonia borane is a promising hydrogen storage candidate due to its high hydrogen capacity and good stability at room temperature, but there are still some barriers to be overcome before it can be used for practical applications. We present the hydrogen release from ammonia borane confined in templated microporous carbon with extremely narrow pore size distribution. Compared with neat ammonia borane, hydrogen release temperature of ammonia borane confined in microporous carbon with pore size of 1.05 nm is significantly reduced, starting at 50 C and with peak dehydrogenation temperature centred at 86 C. The dehydrogenation kinetics of ammonia borane confined in templated microporous carbon is significantly improved and by-products including ammonia and diborane are also completely prohibited without any catalysts involved. The remarkable fast hydrogen release rate and high hydrogen storage capacity from ammonia borane confined in microporous carbon is due to the dramatic decrease in the activation energy of ammonia borane. This is so far the best performance among porous carbon materials used as the confinement scaffolds for ammonia borane in hydrogen storage, making AB confined in microporous carbon a very promising candidate for hydrogen storage.The financial support by the Royal Society and University of Exeter is greatly acknowledged
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