2,2′-(p-Phenyl­enedimethyl­ene)bis­(propane-1,3-diol)

The mol­ecule of the title compound, C14H22O4, is centrosymmetric. In the crystal, the mol­ecules are linked through O—H⋯O hydrogen bonds into a three-dimensional network

Tetraethyl 2,2′-(2,3,5,6-tetrafluoro-p-phenylenedimethylene)dipropanoate1

In the mol­ecule of the title compound, C22H26F4O8, a crystallographic inversion centre is located at the centroid of the benzene ring. C—H⋯F and C—H⋯O intra­molecular hydrogen bonds are observed as well as an inter­molecular C—H⋯O inter­action

7-Amino-4-hy­droxy-4-trifluoro­methyl-3,4-dihydro­quinolin-2(1H)-one

The title compound, C10H9F3N2O2, was prepared by the reaction of m-phenyl­enediamine and ethyl 4,4,4-trifluoro­acetoacetate. In the crystal, inter­molecular C—H⋯ F, N—H⋯F, O—H⋯N and N—H⋯O inter­actions contribute to the crystal packing

1,4-Bis[3-chloro-2-(chloro­meth­yl)prop­yl]benzene

The title mol­ecule, C14H18Cl4, possesses a crystallographically imposed inversion centre, which coincides with the centre of benzene ring. In the absence of classical inter­molecular inter­actions, van der Waals forces help the mol­ecules to pack in the crystal

1,2-Diphenyl­ethane-1,2-diyl diiso­nico­tinate monohydrate1

In the novel title compound, C26H20N2O4·H2O, the two phenyl rings make a dihedral angle of 45.3 (1)° with each other, and the dihedral angle between the two pyridyl planes is 69.8 (1)°

Spatiotemporal evolution and driving factors of the coupling coordination between county land urbanization and grain production: the case of Jiangsu province, China

How to ensure a coordinated development between land urbanization and grain production has been a key issue that needs to be urgently addressed to achieve sustainable development in China. Taking Jiangsu province as an example, this paper measures the coupling coordination degree (CCD) between county land urbanization and grain production from 2010 to 2020 based on the coupling coordination degree model (CCDM). In addition, the exploratory spatial data analysis method and the space Durbin model are combined to explore the spatial correlation and influencing factors of the CCD between land urbanization and grain production. The main conclusions are as follows: (1) From a temporal perspective, the CCD between county land urbanization and grain production in Jiangsu is dominated by basically coordinated, with an overall stable rising trend and a distribution pattern of Northern Jiangsu > Central Jiangsu > Southern Jiangsu. (2) From the perspective of spatial distribution, the CCD between the two is dominated by basically coordinated in the Southern, Central and Northern Jiangsu regions. The spatial clustering characteristics are significant, and the distribution of counties with basically coordinated shows concentrated and contiguous characteristics. (3) From the perspective of spatial correlation, the CCD between the two shows a low level of positive spatial autocorrelation. The state of agglomeration is significant in Northern Jiangsu, while spatial agglomeration is sporadic in Southern Jiangsu and insignificant in Central Jiangsu. (4) The factors affecting the CCD between county land urbanization and grain production in Jiangsu province are determined by many factors together. Based on a driver perspective, Per capita GDP and chemical fertilizer application intensity have a negative effect on it. Highway network density and mobile internet penetration rate have a positive effect on it. Population density, advanced industrial structure, per capita grain planting area and agro-industrial agglomeration are not significant. This study offers useful insights for promoting the coupled and coordinated development of county urbanization and grain production in China

Assessing larval fish diversity and conservation needs in the Luzon strait using DNA barcoding

IntroductionAccurate species identification and biodiversity assessment of larval fish are essential for effective management and conservation of fisheries resources, as it allows for the estimation of parent stocks, assessment of future recruitment, and prediction of spawning and nursing grounds. However, traditional morphology-based identification methods have inherent limitations, highlighting the need for accurate and efficient techniques to address these challenges effectively. The Luzon Strait, a crucial channel connecting the South China Sea to Western Pacific Ocean, is renowned for its fish biodiversity. However, our knowledge of the biodiversity status of larval fish species in this region remains insufficient.MethodsHere we employed DNA barcoding to assess larval fish species diversity in the Luzon Strait and adjacent waters. We investigated the species composition, diversity, and geographical distribution of larval fish communities in the region. Moreover, we assessed habitat types, human uses, and IUCN conservation status of each larval fish species.ResultsA total of 385 larval fish individuals were collected from 15 stations, and 354 individuals were successfully barcoded and identified, representing 147 species from 93 genera, 44 families, and 22 orders. The interspecific Kimura 2-parameter (K2P) divergence exhibited a significant increase of approximately 55-fold higher than intraspecific divergence. The phylogenetic neighbor-joining tree confirmed the distinct lineages for each taxonomic level, demonstrating the feasibility of DNA barcoding. We observed notable variations in fish species diversity and community composition among sampling stations. Non-metric multidimensional scaling analysis revealed greater diversity and dissimilarity of larval fish community compositions in the western regions compared to the eastern regions. This pattern corresponded to the grouping based on the path of the Kuroshio current, suggesting its influence on the fish community structure. Additionally, economically valuable species were identified at these stations, highlighting their ecological significance as potential spawning or nursery grounds for larval fish. We also examined the habitat type, human use, and conservation status of each larval fish species, providing comprehensive insights into their ecological significance and conservation needs.DiscussionThe establishment of a local DNA sequences database through DNA barcoding will greatly enhance the accuracy of species identification in environmental DNA (eDNA) metabarcoding applications. Altogether, this study offers valuable information for identifying important spawning and nursing grounds of fish populations, thereby supporting sustainable management and conservation of fisheries resources in this region