207 research outputs found
STM characterization of the Si-P heterodimer
We use scanning tunneling microscopy (STM) and Auger electron spectroscopy to
study the behavior of adsorbed phosphine (PH) on Si(001), as a function
of annealing temperature, paying particular attention to the formation of the
Si-P heterodimer. Dosing the Si(001) surface with 0.002 Langmuirs of
PH results in the adsorption of PH (x=2,3) onto the surface and
some etching of Si to form individual Si ad-dimers. Annealing to 350C
results in the incorporation of P into the surface layer to form Si-P
heterodimers and the formation of short 1-dimensional Si dimer chains and
monohydrides. In filled state STM images, isolated Si-P heterodimers appear as
zig-zag features on the surface due to the static dimer buckling induced by the
heterodimer. In the presence of a moderate coverage of monohydrides this static
buckling is lifted, rending the Si-P heterodimers invisible in filled state
images. However, we find that we can image the heterodimer at all H coverages
using empty state imaging. The ability to identify single P atoms incorporated
into Si(001) will be invaluable in the development of nanoscale electronic
devices based on controlled atomic-scale doping of Si.Comment: 6 pages, 4 figures (only 72dpi
Split-off dimer defects on the Si(001)2x1 surface
Dimer vacancy (DV) defect complexes in the Si(001)2x1 surface were
investigated using high-resolution scanning tunneling microscopy and first
principles calculations. We find that under low bias filled-state tunneling
conditions, isolated 'split-off' dimers in these defect complexes are imaged as
pairs of protrusions while the surrounding Si surface dimers appear as the
usual 'bean-shaped' protrusions. We attribute this to the formation of pi-bonds
between the two atoms of the split-off dimer and second layer atoms, and
present charge density plots to support this assignment. We observe a local
brightness enhancement due to strain for different DV complexes and provide the
first experimental confirmation of an earlier prediction that the 1+2-DV
induces less surface strain than other DV complexes. Finally, we present a
previously unreported triangular shaped split-off dimer defect complex that
exists at SB-type step edges, and propose a structure for this defect involving
a bound Si monomer.Comment: 8 pages, 7 figures, submitted to Phys. Rev.
Empirical Phi-Discrepancies and Quasi-Empirical Likelihood: Exponential Bounds
We review some recent extensions of the so-called generalized empirical likelihood method, when the Kullback distance is replaced by some general convex divergence. We propose to use, instead of empirical likelihood, some regularized form or quasi-empirical likelihood method, corresponding to a convex combination of Kullback and χ2 discrepancies. We show that for some adequate choice of the weight in this combination, the corresponding quasi-empirical likelihood is Bartlett-correctable. We also establish some non-asymptotic exponential bounds for the confidence regions obtained by using this method. These bounds are derived via bounds for self-normalized sums in the multivariate case obtained in a previous work by the authors. We also show that this kind of results may be extended to process valued infinite dimensional parameters. In this case some known results about self-normalized processes may be used to control the behavior of generalized empirical likelihood
Fragmentation and Multifragmentation of 10.6A GeV Gold Nuclei
We present the results of a study performed on the interactions of 10.6A GeV
gold nuclei in nuclear emulsions. In a minimum bias sample of 1311 interac-
tions, 5260 helium nuclei and 2622 heavy fragments were observed as Au projec-
tile fragments. The experimental data are analyzed with particular emphasis of
target separation interactions in emulsions and study of criticalexponents.
Multiplicity distributions of the fast-moving projectile fragments are inves-
tigated. Charged fragment moments, conditional moments as well as two and three
-body asymmetries of the fast moving projectile particles are determined in
terms of the total charge remaining bound in the multiply charged projectile
fragments. Some differences in the average yields of helium nuclei and heavier
fragments are observed, which may be attributed to a target effect. However,
two and three-body asymmetries and conditional moments indicate that the
breakup mechanism of the projectile seems to be independent of target mass. We
looked for evidence of critical point observable in finite nuclei by study the
resulting charged fragments distributions. We have obtained the values for the
critical exponents gamma, beta and tau and compare our results with those at
lower energy experiment (1.0A GeV data). The values suggest that a phase
transition like behavior, is observed.Comment: latex, revtex, 28 pages, 12 figures, 3tables, submitted to Europysics
Journal
A case-only study to identify genetic modifiers of breast cancer risk for BRCA1/BRCA2 mutation carriers
Breast cancer (BC) risk for BRCA1 and BRCA2 mutation carriers varies by genetic and familial factors. About 50 common variants have been shown to modify BC risk for mutation carriers. All but three, were identified in general population studies. Other mutation carrier-specific susceptibility variants may exist but studies of mutation carriers have so far been underpowered. We conduct a novel case-only genome-wide association study comparing genotype frequencies between 60,212 general population BC cases and 13,007 cases with BRCA1 or BRCA2 mutations. We identify robust novel associations for 2 variants with BC for BRCA1 and 3 for BRCA2 mutation carriers, P < 10−8, at 5 loci, which are not associated with risk in the general population. They include rs60882887 at 11p11.2 where MADD, SP11 and EIF1, genes previously implicated in BC biology, are predicted as potential targets. These findings will contribute towards customising BC polygenic risk scores for BRCA1 and BRCA2 mutation carriers
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Diffusional kinetics of SiGe Dimers on Si(100) using atom-tracking scanning tunneling microscopy
Quantitative measurements of the diffusion of adsorbed mixed Ge-Si dimers on the Si(100) surface have been made as a function of temperature using atom-tracking scanning tunneling microscopy. These mixed dimers are distinguishable from pure Si-Si dimers by their characteristic kinetics--a 180-degree rotation between two highly buckled configurations. At temperatures at which the mixed dimers diffuse, atomic-exchange events occur, in which the Ge atom in the adsorbed dimer exchanges with a substrate Si atom. Re-exchange can also occur when the diffusing Si-Si dimer revisits the original site of exchange
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