Very fast formation of superconducting MgB2/Fe wires with high Jc

In this paper we have investigated the effects of sintering time and temperature on the formation and critical current densities of Fe-clad MgB2 wires. MgB2 wires were fabricated using the powder-in-tube process and sintered for different periods of time at predetermined temperatures. All the samples were examined using XRD, SEM and magnetisation measurements. In contrast to the common practice of sintering for several hours, the present results show that there is no need for prolonged heat treatment in the fabrication of Fe-clad MgB2 wires. A total time in the furnace of several minutes is more than enough to form nearly pure MgB2 with high performance characteristics. The results from Tc, Jc and Hirr show convincingly that the samples which were sintered for 3 minutes above 800 oC are as good as those sintered for longer times. In fact, the Jc field performance for the most rapidly sintered sample is slightly better than for all other samples. Jc of 4.5 times 10 ^5 A/cm2 in zero field and above 10 ^5 A/cm2 in 2T at 15 K has been achieved for the best Fe-clad MgB2 wires. As a result of such a short sintering there is no need for using high purity argon protection and it is possible to carry out the heat treatment in a much less protective atmosphere or in air. These findings substantially simplify the fabrication process, making it possible to have a continuous process for fabrication and reducing the costs for large-scale production of MgB2 wires.Comment: 15 pages, one table, 9 figures, submitted to Physica C on June 8, 200

Local disorder and optical properties in V-shaped quantum wires : towards one-dimensional exciton systems

The exciton localization is studied in GaAs/GaAlAs V-shaped quantum wires (QWRs) by high spatial resolution spectroscopy. Scanning optical imaging of different generations of samples shows that the localization length has been enhanced as the growth techniques were improved. In the best samples, excitons are delocalized in islands of length of the order of 1 micron, and form a continuum of 1D states in each of them, as evidenced by the sqrt(T) dependence of the radiative lifetime. On the opposite, in the previous generation of QWRs, the localization length is typically 50 nm and the QWR behaves as a collection of quantum boxes. These localization properties are compared to structural properties and related to the progresses of the growth techniques. The presence of residual disorder is evidenced in the best samples and explained by the separation of electrons and holes due to the large in-built piezo-electric field present in the structure.Comment: 8 figure

Influence of chemical treatment on the recycling of composites before pyrolysis

Recycling of carbon fibers is one of the upcoming global research topics in composite engineering. This work investigates the influence of chemical treatment on the recovery of carbon fibers from carbon fiber reinforced plastic before pyrolysis. The chemical pretreatment was achieved using a zinc chloride/ethanol solution. The pyrolysis process was conducted in a sliding furnace. The effect of such pre-treatment on thermal degradation behaviour was determined by a thermogravimetric analyser (TGA). An original sample was also investigated for benchmarking. After the thermal pyrolysis process, the fiber tensile properties were measured using a single fiber tester. The surface functional groups and graphitization degree recovered carbon fiber were characterized using X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. The surface morphology of recycled carbon fibers was investigated by SEM. Pristine carbon fibers were also included in the study for benchmarking. During the pyrolysis process, the devolatilisation temperature of the pre-impregnated prepregreduced by around 40-50°C and the peak temperature was 40-50°C lower compared to that of the original prepreg. The chemical pre-treatment process reduces the pyrolysis temperature compared to the conventional pyrolysis process. After pyrolysis in nitrogen with a small amount of air, loose carbon fibers were recovered, and their surface was clean. The similar surface functional groups and the decrease of degree of graphitization were detected on the recycled carbon fiber

Effect of anaerobic fermentation residues on a chromium-contaminated soil-vegetable system

AbstractWastewater irrigation and the deposit of chromium residues during the course of chromate production had caused serious chromium pollution in farmland. The aim of this study was to use anaerobic fermentation residues to treat with a chromium-contaminated soil-vegetable system. Pot experiment with Chinese cabbage, indoor cultivation experiment and soil adsorption experiments were conducted in this study. The results indicated that both yields and residual chromium in Chinese cabbages with the treatment of anaerobic fermentation residues were generally better than that with the treatment of chemical fertilizer. At the second experiment, compared with raw soil, mineralized potential and mineralized rate of nitrogen increased 29.2% and 15.4% respectively after adding anaerobic fermentation residues. Experimental results were fitted to Langmuir equation, Freundlich equation and Temkin equation, Langmuir equation was found to be the best to describe the adsorption of phosphor, and Temkin equation was the fittest for describing the adsorption of potassium. The supply of nitrogen, phosphor and potassium from soil were enhanced in varying degree (nitrogen > phosphor >potassium). Thus anaerobic fermentation residues may be considered as a widespread, effective and safe strategy for deal with chromium-contaminated soil-vegetable system in future

Shredding energy consumption of GFRP composite waste

This work investigated effect of glass fibre fabric structures, feedstock feed rate and screen size on specific shredding energy of glass fibre reinforced plastics (GFRP) waste via a two-level factorial design of experiment study. Four types of fabric structure, i.e. unidirectional (UD), biaxial (BIAX), triaxial (TRIAX) and chopped strand mat (CSM), were impregnated separately with unsaturated polyester resin to manufacture GFRP plates. The shredding energy was measured using a two-wattmeter approach. During shredding, CSM demonstrated a relatively flat power consumption curve compared to other fabric types. It was also noticed that the GFRP plate reinforced with more complex woven structure, i.e. TRIAX, required higher energy for shredding, especially with a combination of high feed rate and small screen size. It was found that mechanical efficiency was only around 8.2-15.7% and 0.8-2.2% for shredding at feed rate of 60 kg/hr and 10 kg/hr respectively. It was also found that adopting a larger screen size and lower feed rate could reduce the specific shredding energy

Flux Jumping and a Bulk-to-Granular Transition in the Magnetization of a Compacted and Sintered MgB2 Superconductor

The recent discovery of intermediate-temperature superconductivity (ITC) in MgB2 by Akimitsu et al. and its almost simultaneous explanation in terms of a hole-carrier-based pairing mechanism by Hirsch, has triggered an avalanche of studies of its structural, magnetic and transport properties. As a further contribution to the field we report the results of field (H) and temperature (T) dependent magnetization (M) measurements of a pellet of uniform, large-grain sintered MgB2. We show that at low temperatures the size of the pellet and its critical current density, Jc(H) - i.e. its M(H) - ensure low field flux jumping, which of course ceases when M(H) drops below a critical value. With further increase of H and T the individual grains decouple and the M(H) loops drop to lower lying branches, unresolved in the usual full M(H) representation. After taking into account the sample size and grain size, respectively, the bulk sample and the grains were deduced to exhibit the same magnetically determined Jc s (e.g. 105 A/cm2, 20 K, 0T) and hence that for each temperature of measurement Jc(H) decreased monotonically with H over the entire field range, except for a gap within the grain-decoupling zone.Comment: 7 pages, 6 figures, Changes: Fig 6 Vertical scale an order of magnitude out (changed figure and associated text). Also corrected typo in last sectio

The simulation of magnetorheological elastomers adaptive tuned dynamic vibration absorber for automobile engine vibration control

The aim of this article is to investigate the use of a Dynamic Vibration Absorber to control vibration of engine by using simulation. Traditional means of vibration control have involved the use of passive and more recently, active methods. This study is different in that it involves an adaptive component in the design of vibration absorber using magnetorheological elastomers (MREs) as the adaptive spring. MREs are kind of novel smart material whose shear modulus can be controlled by applied magnetic field. In this paper, the vibration mode of a simple model of automobile engine is simulated by Finite Element Method (FEM) analysis. Based on the analysis, the MREs Adaptive Tuned Dynamic Vibration Absorber (ATDVA) is presented to reduce the vibration of the engine. Simulation result indicate that the control frequency of ATDVA can be changed by modifing the shear modulus of MREs and the vibraion reduction efficiency of ATDVA are also evaluated by FEM analysis

Effect of Chinese herbal medicines on rumen fermentation, methanogenesis and microbial flora in vitro

This study was carried out to evaluate the effects of three Chinese herbal medicines (CHMs) on rumen fermentation, methane emission and population of ruminal microbes using an in vitro gas production technique. Three healthy wethers of Dazu Black goats with similar bodyweights and permanent rumen fistulae were utilized as donors of ruminal fluid. The three botanical medicines were cablin patchouli herb (CPH), atractylodes rhizome (AR) and Amur cork tree (AC). Each CHM was added at a level of 25 g/kg to the substrate dry matter. In vitro gas production was recorded, and methane concentration was determined at 12 and 24 hours of incubation. After 24 hours, the incubation was stopped, and the inoculants were measured for pH, ammonia nitrogen and volatile fatty acids (VFAs) concentrations. Total deoxyribonucleic acid of ruminal microbes was extracted from the inocula, and populations were determined by a real-time quantitative polymerase chain reaction. Populations of total rumen methanogens, protozoa, total fungi, Ruminococcus albus, Fibrobacter succinogenes and Ruminococcus flavefaciens were expressed as a proportion of total rumen bacterial 16S ribosomal deoxyribonucleic acid. Compared to the control, CPH decreased gas production and methane production at 12 and 24 hours of incubation, and inhibited methanogens and total fungi growth. AR decreased acetate to propionate ratio, and methanogens and total fungi populations, but increased propionate molar proportion. AC decreased total VFA concentration, acetate to propionate ratio, gas production at 12 and 24 hours of incubation, methane production at 12 and 24 hours of incubation, and methanogens and total fungi growth, but increased the propionate molar proportion. In conclusion, CPH and AC both suppressed methanogenesis significantly, and the suppression was mediated primarily via the direct action against the rumen microbes involved in methane formation. AC also indirectly abates methane release by occupying the hydrogen (H2) normally utilized for methanogenesis.Keywords: In vitro gas production, methane, rumen fermentation parameter, rumen microbe

Responses of chemical composition, amino acid and fatty acid profiles of breast muscle to dietary crude fibre levels in China Micro-Ducks

The effects of dietary crude fibre (CF) levels on the chemical composition, amino acid (AA) and fatty acid (FA) profiles of breast muscle in male China Micro-ducks (21 - 56 d) were investigated in this study. The birds were randomly allocated to four treatments, of which dietary CF levels were 16.7, 42.6, 77.9 and 101.6 g/kg of dry matter (DM), respectively. No influences on the proportions of crude ash, crude protein, lysine, methionine, threonine, phenylalanine, histidine, arginine, aspartic acid, glutamic acid, glycine, alanine, serine, cysteine, tyrosine, proline, C12:0, C18:0, C18:1n9, C20:0 and C22:1n9 in muscle were observed across the treatments. Consequently, the concentrations of semi-essential AA, non-essential AA, total AA, aromatic AA and delicious AA in muscle, along with the Δ-9-desaturase (18) index, were not affected by the treatments. Significant lower concentrations of valine, leucine, isoleucine, essential AA, branched-chain AA, C16:1n7 and monounsaturated FA in muscle, along with a lower ratio of branched-chain to aromatic AA, were noted in a dietary treatment with a CF level of 16.7 g/kg DM compared to other dietary treatments. The rise of the dietary CF level significantly increased the proportions of DM, ether extract, gross energy, C18:2n6, C18:3n3, C20:4n6, unsaturated FA, total FA, polyunsaturated FA, n-3 polyunsaturated FA, n-6 polyunsaturated FA, essential FA, and the Δ-9-desaturase (16) index. Furthermore, the rise of the dietary CF level increased the ratios of unsaturated to saturated FA, polyunsaturated to saturated FA, and n-6 to n-3 polyunsaturated FA in muscle. However, it decreased the atherogenic index and the proportions of C14:0, C16:0, and saturated FA significantly. In conclusion, depending largely on dietary levels, CF profoundly and positively influenced the nutritional quality of breast muscle, especially the FA profile.Keywords: China Micro-duck, dietary fibre, fatty acid, nutritional quality of meat, fatty aci