12,472 research outputs found

    Fe-doping induced superconductivity in charge-density-wave system 1T-TaS2

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    We report the interplay between charge-density-wave (CDW) and superconductivity of 1TT-Fex_{x}Ta1−x_{1-x}S2_{2} (0≤x≤0.050\leq x \leq 0.05) single crystals. The CDW order is gradually suppressed by Fe-doping, accompanied by the disappearance of pseudogap/Mott-gap as shown by the density functional theory (DFT) calculations. The superconducting state develops at low temperatures within the CDW state for the samples with the moderate doping levels. The superconductivity strongly depends on xx within a narrow range, and the maximum superconducting transition temperature is 2.8 K as x=0.02x=0.02. We propose that the induced superconductivity and CDW phases are separated in real space. For high doping level (x>0.04x>0.04), the Anderson localization (AL) state appears, resulting in a large increase of resistivity. We present a complete electronic phase diagram of 1TT-Fex_{x}Ta1−x_{1-x}S2_{2} system that shows a dome-like Tc(x)T_{c}(x)

    Hot electrons in low-dimensional phonon systems

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    A simple bulk model of electron-phonon coupling in metals has been surprisingly successful in explaining experiments on metal films that actually involve surface- or other low-dimensional phonons. However, by an exact application of this standard model to a semi-infinite substrate with a free surface, making use of the actual vibrational modes of the substrate, we show that such agreement is fortuitous, and that the model actually predicts a low-temperature crossover from the familiar T^5 temperature dependence to a stronger T^6 log T scaling. Comparison with existing experiments suggests a widespread breakdown of the standard model of electron-phonon thermalization in metals

    The instability of diffusive convection and its implication for the thermohaline staircases in the deep Arctic Ocean

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    In the present study, the classical description of diffusive convection is updated to interpret the instability of diffusive interfaces and the dynamical evolution of the bottom layer in the deep Arctic Ocean. In the new consideration of convective instability, both the background salinity stratification and rotation are involved. The critical Rayleigh number of diffusive convection is found to vary from 10<sup>3</sup> to 10<sup>11</sup> in the deep Arctic Ocean as well as in other oceans and lakes. In such a wide range of conditions, the interface-induced thermal Rayleigh number is shown to be consistent with the critical Rayleigh number of diffusive convection. In most regions, background salinity stratification is found to be the main hindrance to the occurrence of convecting layers. With the new parameterization, it is predicted that the maximum thickness of the bottom layer is 1051 m in the deep Arctic Ocean, which is close to the observed value of 929 m. The evolution time of the bottom layer is predicted to be ~ 100 yr, which is on the same order as that based on <sup>14</sup>C isolation age estimation

    A refined invariant subspace method and applications to evolution equations

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    The invariant subspace method is refined to present more unity and more diversity of exact solutions to evolution equations. The key idea is to take subspaces of solutions to linear ordinary differential equations as invariant subspaces that evolution equations admit. A two-component nonlinear system of dissipative equations was analyzed to shed light on the resulting theory, and two concrete examples are given to find invariant subspaces associated with 2nd-order and 3rd-order linear ordinary differential equations and their corresponding exact solutions with generalized separated variables.Comment: 16 page

    Role of Glycol Chitosan-incorporated Ursolic Acid Nanoparticles in the Treatment of Osteosarcoma

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    Purpose: To investigate the effect of ursolic acid (UA)-incorporated glycol chitosan (GC) nanoparticles on inhibition of human osteosarcoma.Methods: U2OS and Saos-2 osteosarcoma cells were transfected with ursolic acid (UA) incorporated glycol chitosan (GC) nanoparticles. Ultraviolet (UV)  spectrophotometry was used to measure drug contents in nanoparticles at 365 nm with empty GC vehicles as blank. Bicinchoninic acid assay (BCA) method was employed to determine protein concentration. Identification of apoptosis and necrosis in osteosarcoma cells was performed by propidium iodide and FITC-annexin V reagents, respectively. FAC Scan flow cytometry was used to analyse apoptotic cells.Results: Among the range of UA concentrations tested, the minimum effective concentration was 10 μM with half inhibitory concentration IC50 of 25 μM. In U2OS cells, treatment with 10 and 25 μM UAinduced apoptosis in 5.89 ± 3.90 and 60.54 ± 5.40 % cells, respectively, compared to 2.05 ± 1.01 % cells for control. In Saos-2 cells, exposure to 10 and 25 μM UA induced apoptosis in 9.86 ± 8.89 and 47.54 ± 14.5 % cells, respectively, compared to 1.79 ± 0.23 % for control cells. Western blot analysis revealed  translocation of Bax and Bcl-2 proteins from mitochondria to cell cytosol. Increase in UA concentration  from 10 μM to 25 μM led to increase in the proportion of cells in G0/G1 phase and decrease in the number of cells in S and G2/M phases. These results confirm that UA transfection arrests cell cycle in G0/G1 phase in human osteosarcoma cell lines.Conclusion: UA transfection resulted in the inhibition of cell proliferation, Ezh2 expression inhibition, and apoptosis via mitochondrial pathway due to decrease in membrane potential and release of cytochrome C, as well as cell cycle arrest in G0/G1 phase.Keywords: Osteosarcoma, Cell cycle arrest, Palliation, Glycol chitosan, Ursolic aci

    Push-out tests and bond strength of rectangular CFST columns

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    Push-out tests have been conducted on 18 rectangular concrete-filled steel tubular (CFST) columns with the aim of studying the bond behaviour between the steel tube and the concrete infill. The obtained load-slip response and the distribution of the interface bond stress along the member length and around the cross-section for various load levels, as derived from measured axial strain gradients in the steel tube, are reported. Concrete compressive strength, interface length, cross-sectional dimensions and different interface conditions were varied to assess their effect on the ultimate bond stress. The test results indicate that lubricating the steel-concrete interface always had a significant adverse effect on the interface bond strength. Among the other variables considered, concrete compressive strength and cross-section size were found to have a pronounced effect on the bond strength of non-lubricated specimens for the range of cross-section geometries considered, which is not reflected in the European structural design code for composite structures, EN 1994-1-1 (2004). Finally, based on nonlinear regression of the test data generated in the present study, supplemented by additional data obtained from the literature, an empirical equation has been proposed for predicting the average ultimate bond strength for SHS and RHS filled with normal strength concrete
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