Effect of distribution of stickers along backbone on temperature-dependent structural properties in associative polymer solutions

Effect of distribution of stickers along the backbone on structural properties in associating polymer solutions is studied using self-consistent field lattice model. Only two inhomogeneous morphologies, i.e., microfluctuation homogenous (MFH) and micelle morphologies, are observed. If the system is cooled, the solvent content within the aggregates decreases. When the spacing of stickers along the backbone is increased the temperature-dependent range of aggregation in MFH morphology and half-width of specific heat peak for homogenous solutions-MFH transition increase, and the symmetry of the peak decreases. However, with increasing spacing of stickers, the above three corresponding quantities related to micelles behave differently. It is demonstrated that the broad nature of the observed transitions can be ascribed to the structural changes which accompany the replacement of solvents in aggregates by polymer, which is consistent with the experimental conclusion. It is found that different effect of spacing of stickers on the two transitions can be interpreted in terms of intrachain and interchain associations.Comment: 10 pages, 4 figures. arXiv admin note: text overlap with arXiv:1202.459

Evolution of binary stars and its implications for evolutionary population synthesis

Most stars are members of binaries, and the evolution of a star in a close binary system differs from that of an ioslated star due to the proximity of its companion star. The components in a binary system interact in many ways and binary evolution leads to the formation of many peculiar stars, including blue stragglers and hot subdwarfs. We will discuss binary evolution and the formation of blue stragglers and hot subdwarfs, and show that those hot objects are important in the study of evolutionary population synthesis (EPS), and conclude that binary interactions should be included in the study of EPS. Indeed, binary interactions make a stellar population younger (hotter), and the far-ultraviolet (UV) excess in elliptical galaxies is shown to be most likely resulted from binary interactions. This has major implications for understanding the evolution of the far-UV excess and elliptical galaxies in general. In particular, it implies that the far-UV excess is not a sign of age, as had been postulated prviously and predicts that it should not be strongly dependent on the metallicity of the population, but exists universally from dwarf ellipticals to giant ellipticals.Comment: Oral talk on IAUS 262, Brazi

Thermal and non-thermal emission in the Cygnus X region

Radio continuum observations detect non-thermal synchrotron and thermal bremsstrahlung radiation. Separation of the two different emission components is crucial to study the properties of diffuse interstellar medium. The Cygnus X region is one of the most complex areas in the radio sky which contains a number of massive stars and HII regions on the diffuse thermal and non-thermal background. More supernova remnants are expected to be discovered. We aim to develop a method which can properly separate the non-thermal and thermal radio continuum emission and apply it to the Cygnus X region. The result can be used to study the properties of different emission components and search for new supernova remnants in the complex. Multi-frequency radio continuum data from large-scale surveys are used to develop a new component separation method. Spectral analysis is done pixel by pixel for the non-thermal synchrotron emission with a realistic spectral index distribution and a fixed spectral index of beta = -2.1 for the thermal bremsstrahlung emission. With the new method, we separate the non-thermal and thermal components of the Cygnus X region at an angular resolution of 9.5arcmin. The thermal emission component is found to comprise 75% of the total continuum emission at 6cm. Thermal diffuse emission, rather than the discrete HII regions, is found to be the major contributor to the entire thermal budget. A smooth non-thermal emission background of 100 mK Tb is found. We successfully make the large-extent known supernova remnants and the HII regions embedded in the complex standing out, but no new large SNRs brighter than Sigma_1GHz = 3.7 x 10^-21 W m^-2 Hz^-1 sr^-1 are found.Comment: 9 pages, 5 figures, accepted by A&A. The quality of the figures is reduced due to file size limit of the websit

Shotgun Lipidomics Identifies a Paired Rule for the Presence of Isomeric Ether Phospholipid Molecular Species

Ether phospholipids are abundant membrane constituents present in electrically active tissues (e.g., heart and the brain) that play important roles in cellular function. Alterations of ether phospholipid molecular species contents are associated with a number of genetic disorders and human diseases.Herein, the power of shotgun lipidomics, in combination with high mass accuracy/high resolution mass spectrometry, was explored to identify a paired rule for the presence of isomeric ether phospholipid molecular species in cellular lipidomes. The rule predicts that if an ether phospholipid A'-B is present in a lipidome, its isomeric counterpart B'-A is also present (where the ' represents an ether linkage). The biochemical basis of this rule results from the fact that the enzymes which participate in either the sequential oxidation of aliphatic alcohols to fatty acids, or the reduction of long chain fatty acids to aliphatic alcohols (metabolic precursors of ether lipid synthesis), are not entirely selective with respect to acyl chain length or degree of unsaturation. Moreover, the enzymatic selectivity for the incorporation of different aliphatic chains into the obligatory precursor of ether lipids (i.e., 1-O-alkyl-glycero-3-phosphate) is also limited.This intrinsic amplification of the number of lipid molecular species present in biological membranes predicted by this rule and demonstrated in this study greatly expands the number of ether lipid molecular species present in cellular lipidomes. Application of this rule to mass spectrometric analyses provides predictive clues to the presence of specific molecular species and greatly expands the number of identifiable and quantifiable ether lipid species present in biological samples. Through appropriate alterations in the database, use of the paired rule increases the number of identifiable metabolites in metabolic networks, thereby facilitating identification of biomarkers presaging disease states

Birthrates and delay times of Type Ia supernovae

Type Ia supernovae (SNe Ia) play an important role in diverse areas of astrophysics, from the chemical evolution of galaxies to observational cosmology. However, the nature of the progenitors of SNe Ia is still unclear. In this paper, according to a detailed binary population synthesis study, we obtained SN Ia birthrates and delay times from different progenitor models, and compared them with observations. We find that the Galactic SN Ia birthrate from the double-degenerate (DD) model is close to those inferred from observations, while the birthrate from the single-degenerate (SD) model accounts for only about 1/2-2/3 of the observations. If a single starburst is assumed, the distribution of the delay times of SNe Ia from the SD model is a weak bimodality, where the WD + He channel contributes to the SNe Ia with delay times shorter than 100Myr, and the WD + MS and WD + RG channels to those with age longer than 1Gyr.Comment: 11 pages, 2 figures, accepted by Science in China Series G (Dec.30, 2009

Momentum Distribution of Near-Zero-Energy Photoelectrons in the Strong-Field Tunneling Ionization in the Long Wavelength Limit

We investigate the ionization dynamics of Argon atoms irradiated by an ultrashort intense laser of a wavelength up to 3100 nm, addressing the momentum distribution of the photoelectrons with near-zero-energy. We find a surprising accumulation in the momentum distribution corresponding to meV energy and a \textquotedblleft V"-like structure at the slightly larger transverse momenta. Semiclassical simulations indicate the crucial role of the Coulomb attraction between the escaping electron and the remaining ion at extremely large distance. Tracing back classical trajectories, we find the tunneling electrons born in a certain window of the field phase and transverse velocity are responsible for the striking accumulation. Our theoretical results are consistent with recent meV-resolved high-precision measurements.Comment: 5 pages, 4 figure