A micro-magneto-Raman scattering study of graphene on a bulk graphite substrate

We report on a magneto-Raman scattering study of graphene flakes located on the surface of a bulk graphite substrate. By spatially mapping the Raman scattering response of the surface of bulk graphite with an applied magnetic field, we pinpoint specific locations which show the electronic excitation spectrum of graphene. We present the characteristic Raman scattering signatures of these specific locations. We show that such flakes can be superimposed with another flake and still exhibit a graphene-like excitation spectrum. Two different excitation laser energies (514.5 and 720 nm) are used to investigate the excitation wavelength dependence of the electronic Raman scattering signal.Comment: 6 pages, 5 figure

Astronomical optical frequency comb generation and test in a fiber-fed MUSE spectrograph

We here report on recent progress on astronomical optical frequency comb generation at innoFSPEC-Potsdam and present preliminary test results using the fiber-fed Multi Unit Spectroscopic Explorer (MUSE) spectrograph. The frequency comb is generated by propagating two free-running lasers at 1554.3 and 1558.9 nm through two dispersionoptimized nonlinear fibers. The generated comb is centered at 1590 nm and comprises more than one hundred lines with an optical-signal-to-noise ratio larger than 30 dB. A nonlinear crystal is used to frequency double the whole comb spectrum, which is efficiently converted into the 800 nm spectral band. We evaluate first the wavelength stability using an optical spectrum analyzer with 0.02 nm resolution and wavelength grid of 0.01 nm. After confirming the stability within 0.01 nm, we compare the spectra of the astro-comb and the Ne and Hg calibration lamps: the astro-comb exhibits a much larger number of lines than lamp calibration sources. A series of preliminary tests using a fiber-fed MUSE spectrograph are subsequently carried out with the main goal of assessing the equidistancy of the comb lines. Using a P3d data reduction software we determine the centroid and the width of each comb line (for each of the 400 fibers feeding the spectrograph): equidistancy is confirmed with an absolute accuracy of 0.4 pm

Magnetopolaron Effect on Shallow Donors in GaN

Resonant interaction between longitudinal-optic (LO) phonons and electrons bound on shallow donors in GaN is studied using magnetoluminescence of neutral-donor bound excitons (D0X). The experiments were performed on high-quality freestanding GaN material and heteroepitaxial GaN layers grown on sapphire. In addition to the principal recombination channel of D0X, in which donors are left in their ground states, two-electron satellites (TES) involving different excited donor excitations, as well as replicas of the principal D0X transition due to LO phonons, were observed for the oxygen and silicon donors. In order to separate transitions involving ground and excited D0X states, variable-temperature experiments were performed. The application of high magnetic fields allows tuning of the donor excitations into resonance with the LO phonon energy. This results in a strong enhancement of TES intensity and the appearance of several anticrossing processes in the vicinity of a LO phonon replica of the principal D0X transition. The observed behavior is explained in terms of a resonant interaction between LO phonons and donor-bound electrons (magnetopolaron effect). The experimental data are described using a phenomenological model that combines the theory of a hydrogen atom in a magnetic field with a model which includes the effects of nonparabolicity, nonresonant polaron corrections, and the resonant magnetopolaron effect on electrons bound to donors. It was found that the interaction in the resonant magnetopolaron regime is stronger for the oxygen than for the silicon donor

Raman Studies of Defects in Graphene Grown on SiC

The Raman scattering studies of multi-layer graphene obtained by high temperature annealing of carbon terminated face of 4H-SiC(000-1) substrates are presented. Intensity ratio of the D and G bands was used to estimate the average size of the graphene flakes constituting carbon structures. The obtained estimates were compared with flake sizes from atomic force microscopy data. We found that even the smallest structures observed by atomic force microscopy images are much bigger than the estimates obtained from the Raman scattering data. The obtained results are discussed in terms of different average flake sizes inside and on the surface of the multi-layer graphene structure, as well as different type of defects which would be present in the investigated structures apart from edge defects

Recombination of Excitons Bound to Oxygen and Silicon Donors in Freestanding GaN

The neutral donor bound exciton recombination processes in freestanding GaN have been studied. The photoluminescence spectrum shows emission lines related to silicon and oxygen donors. Time-resolved luminescence allows us to correlate the principal donor bound exciton lines with their two-electron satellites. The magnetic field splitting of the two-electron lines is well described by the theory of the hydrogen atom in a magnetic field. For the oxygen donor a 1.5 meV chemical shift and a 30.8 meV effective Rydberg have been evaluated. Two-electron satellites involving excitations to the 2p and 2s donor states are separated by an energy of 1.0 and 1.3 meV for O and Si impurity, respectively. The temperature dependence of the two-electron emission clearly shows that this separation arises from a splitting of the ground state of the neutral donor bound exciton complex. The nature of this splitting is discussed and it is suggested that it is due to rotational states of donor bound excitons