Carbonate mineral saturation states in the East China Sea: present conditions and future scenarios

To assess the impact of rising atmospheric CO₂ and eutrophication on the carbonate chemistry of the East China Sea shelf waters, saturation states (Ω) for two important biologically relevant carbonate minerals – calcite (Ω_c) and aragonite (Ω_a) – were calculated throughout the water column from dissolved inorganic carbon (DIC) and total alkalinity (TA) data collected in spring and summer of 2009. Results show that the highest Ω_c (∼9.0) and Ω_a (∼5.8) values were found in surface water of the Changjiang plume area in summer, whereas the lowest values (Ω_c = ∼2.7 and Ω_a = ∼1.7) were concurrently observed in the bottom water of the same area. This divergent behavior of saturation states in surface and bottom waters was driven by intensive biological production and strong stratification of the water column. The high rate of phytoplankton production, stimulated by the enormous nutrient discharge from the Changjiang, acts to decrease the ratio of DIC to TA, and thereby increases Ω values. In contrast, remineralization of organic matter in the bottom water acts to increase the DIC to TA ratio, and thus decreases Ω values. The projected result shows that continued increases of atmospheric CO₂ under the IS92a emission scenario will decrease Ω values by 40–50% by the end of this century, but both the surface and bottom waters will remain supersaturated with respect to calcite and aragonite. Nevertheless, superimposed on such Ω decrease is the increasing eutrophication, which would mitigate or enhance the Ω decline caused by anthropogenic CO₂ uptake in surface and bottom waters, respectively. Our simulation reveals that, under the combined impact of eutrophication and augmentation of atmospheric CO₂, the bottom water of the Changjiang plume area will become undersaturated with respect to aragonite (Ω_a = ∼0.8) by the end of this century, which would threaten the health of the benthic ecosystem

Processing of strong flux trapping high T(subc) oxide superconductors: Center director's discretionary fund

Magnetic suspension effect was first observed in samples of YBa2Cu3O7/AgO(Y-123/AgO) composites. Magnetization measurements of these samples show a much larger hysteresis which corresponds to a large critical current density. In addition to the Y-123AgO composites, recently similar suspension effects in other RE-123/AgO, where RE stands for rare-Earth elements, were also observed. Some samples exhibit even stronger flux pinning than that of the Y-123/AgO sample. An interesting observation was that in order to form the composite which exhibits strong flux trapping effect the sintering temperature depends on the particular RE-123 compound used. The paper presents the detailed processing conditions for the formation of these RE-123/AgO composites, as well as the magnetization and critical field data

Nonstoichiometric doping and Bi antisite defect in single crystal Bi2Se3

We studied the defects of Bi2Se3 generated from Bridgman growth of stoichiometric and nonstoichiometric self-fluxes. Growth habit, lattice size, and transport properties are strongly affected by the types of defect generated. Major defect types of Bi_Se antisite and partial Bi_2-layer intercalation are identified through combined studies of direct atomic-scale imaging with scanning transmission electron microscopy (STEM) in conjunction with energy-dispersive X-ray spectroscopy (STEM-EDX), X-ray diffraction, and Hall effect measurements. We propose a consistent explanation to the origin of defect type, growth morphology, and transport property.Comment: 5 pages, 5 figure