Origin of Anomalous Water Permeation through Graphene Oxide Membrane

Water inside the low dimensional carbon structures has been considered seriously owing to fundamental interest in its flow and structures as well as its practical impact. Recently, the anomalous perfect penetration of water through graphene oxide membrane was demonstrated although the membrane was impenetrable for other liquids and even gases. The unusual auxetic behavior of graphene oxide in the presence of water was also reported. Here, based on first-principles calculations, we establish atomistic models for hybrid systems composed of water and graphene oxides revealing the anomalous water behavior inside the stacked graphene oxides. We show that formation of hexagonal ice bilayer in between the flakes as well as melting transition of ice at the edges of flakes are crucial to realize the perfect water permeation across the whole stacked structures. The distance between adjacent layers that can be controlled either by oxygen reduction process or pressure is shown to determine the water flow thus highlighting a unique water dynamics in randomly connected two-dimensional spaces.Comment: 5 pages, 4 figures, to appear in Nano Letter

Evaluation of Half-metallic Antiferromagnetism in A2{\cal A}_2CrFeO6_6 ({A\cal A}=La, Sr

The nearly well-ordered double perovskite La$_2$CrFeO$_6$ has been synthesized recently. Contrary to previous theoretical predictions, but in agreement with experimental observations, our first principle calculations indicate an insulating ferrimagnet La$_2$CrFeO$_6$ with antialigned S=3/2 Cr$^{3+}$ and S=5/2 Fe$^{3+}$ ions,using the local spin density approximation (LSDA), a correlated band theory LDA+U, and a semilocal functional modified Becke-Johnson method. Additionally, we investigated the double perovskite Sr$_2$CrFeO$_6$, which is as yet unsynthesized. In LSDA calculations, this system shows formally tetravalent Cr and Fe ions both having antialigned $S$=1 moments, but is a simple metal. Once applying on-site Coulomb repulsion U on both Cr and Fe ions, this system becomes half-metallic and the moment of Fe is substantially reduced, resulting in zero net moment. These results are consistent with our fixed spin moment studies. Our results suggest a precisely compensated half-metallic Sr$_2$CrFeO$_6$.Comment: 7 page

On Models of New Physics for the Tevatron Top A_FB

CDF has observed a top forward-backward asymmetry discrepant with the Standard Model prediction at 3.4 \sigma. We analyze models that could generate the asymmetry, including flavor-violating W's, horizontal Z'_Hs, triplet and sextet diquarks, and axigluons. We consider the detailed predictions of these models for the invariant mass and rapidity distributions of the asymmetry at the parton level, comparing against the unfolded parton-level CDF results. While all models can reproduce the asymmetry with the appropriate choice of mass and couplings, it appears at first examination that the extracted parton-level invariant mass distribution for all models are in conflict with Tevatron observations. We show on closer examination, however, that t tbar events in Z'_H and W' models have considerably lower selection efficiencies in high invariant mass bins as compared to the Standard Model, so that W', Z'_H, and axigluon models can generate the observed asymmetry while being consistent with the total cross-section and invariant mass spectrum. Triplet and sextet models have greater difficulty producing the observed asymmetry while remaining consistent with the total cross-section and invariant mass distribution. To more directly match the models and the CDF results, we proceed to decay and reconstruct the tops, comparing our results against the "raw" CDF asymmetry and invariant mass distributions. We find that the models that successfully generate the corrected CDF asymmetry at the parton level reproduce very well the more finely binned uncorrected asymmetry. Finally, we discuss the early LHC reach for discovery of these models, based on our previous analysis [arXiv:1102.0018].Comment: 29 pages, 14 figures, 2 table

Near-field spectroscopy of bimodal size distribution of InAs/AlGaAs quantum dots

We report on high-resolution photoluminescence (PL) spectroscopy of spatial structure of InAs/AlGaAs quantum dots (QDs) by using a near-field scanning optical microscope (NSOM). The double-peaked distribution of PL spectra is clearly observed, which is associated with the bimodal size distribution of single QDs. In particular, the size difference of single QDs, represented by the doublet spectral distribution, can be directly observed by the NSOM images of PL.Comment: 3pages, 3figue

Nonlinear optimal guidance algorithms Interim report

Nonlinear optimal guidance algorithms for space mission

The syntax of the aspectual particles in Mandarin Chinese

Linguistic studies on the aspectual system of natural language have mainly focused on its semantics and morphology; the syntax of aspect has not yet received as much attention. In this dissertation, I provide a syntactic analysis of the aspectual system of Chinese. In analyzing the properties of situation aspect, I propose a unified syntactic structure that accounts for the two mechanisms of telicity marking in Chinese. First, I argue that like pre-verbs in Slavic languages, Chinese also has overt telic morphemes which are used to turn an atelic event into a telic one. For example, I claim that the morpheme wan 'to finish' is base-generated as the head of Inner Aspect Phrase in between vP and VP. This functional phrase is responsible for the telic reading of a sentence. I also claim that differently from languages such as English, whose telicity marking mainly depends on the quantity of the object, countability and boundedness of direct objects in Chinese are not directly responsible for telicity marking. Secondly, I demonstrate that the proposed analysis of telicity marking can also be used to account for the syntactic distributions of the resultative V-V compounds and V-de phrases. I argue that these two types of sentences also contain Inner Aspect Phrase that is responsible for the telic reading. I also claim that the difference in word order between these two constructions is due to morphological requirements and I illustrate how morphology may affect syntax in the derivation. Finally, I discuss imperfective viewpoint aspect in analyzing the distributions of the progressive zai and the durative -zhe. Starting from the close relation between locative expressions and progressive aspect cross-linguistically, I demonstrate that zai always functions as a preposition and is not itself the source of the progressive aspect. I also analyze the usages of -zhe and argue that like English present particle morpheme -ing, this imperfective particle also functions as a verbal suffix of two different types of imperfective aspect. It can be used to express progressive aspect as well as resultative imperfective aspect. The analysis provides a generalization of the imperfective viewpoint aspect in Chinese

Electron and phonon band-structure calculations for the antipolar SrPt3_{3}P antiperovskite superconductor: Evidence of low-energy two-dimensional phonons

SrPt3P has recently been reported to exhibit superconductivity with Tc = 8.4 K. To explore its superconducting mechanism, we have performed electron and phonon band calculations based on the density functional theory, and found that the superconductivity in SrPt3P is well described by the strong coupling phonon-mediated mechanism. We have demonstrated that superconducting charge carriers come from pd\pi-hybridized bands between Pt and P ions, which couple to low energy (~ 5 meV) phonon modes confined on the ab in-plane. These in-plane phonon modes, which do not break antipolar nature of SrPt3P, enhance both the electron-phonon coupling constant \lambda and the critical temperature Tc. There is no hint of a specific phonon softening feature in the phonon dispersion, and the effect of the spin-orbit coupling on the superconductivity is found to be negligible.Comment: 5 pages, 5 figures, 1 tabl

Curvature-induced spin-orbit coupling and spin relaxation in a chemically clean single-layer graphene

The study of spin-related phenomena in materials requires knowledge on the precise form of effective spin-orbit coupling of conducting carriers in the solid-states systems. We demonstrate theoretically that curvature induced by corrugations or periodic ripples in single-layer graphenes generates two types of effective spin-orbit coupling. In addition to the spin-orbit coupling reported previously that couples with sublattice pseudospin and corresponds to the Rashba-type spin-orbit coupling in a corrugated single-layer graphene, there is an additional spin-orbit coupling that does not couple with the pseudospin, which can not be obtained from the extension of the curvature-induced spin-orbit coupling of carbon nanotubes. Via numerical calculation we show that both types of the curvature-induced spin-orbit coupling make the same order of contribution to spin relaxation in chemically clean single-layer graphene with nanoscale corrugation. The spin relaxation dependence on the corrugation roughness is also studied.Comment: 8 pages, 4 figure

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