Dielectric response of a ferroelectric nematic liquid crystalline phase in thin cells

We studied dielectric properties of a polar nematic phase (NF) sandwiched between two gold or ITO electrodes, serving as a cell surfaces. In bulk, NF is expected to exhibit a Goldstone mode (phason), because polarization can uniformly rotate with no energy cost. However, because the coupling between the direction of nematic director and polarization is finite, and the confinement, even in the absence of the aligning surface layer, induces some energy cost for a reorientation of polarization, the phason dielectric relaxation frequency is measured in a kHz regime. The phason mode is easily quenched by a bias electric field, which enables fluctuations in the magnitude of polarization to be followed in both, the ferronematic and nematic phases. This amplitude (soft) mode is also influenced by boundary conditions. A theory describing the phase and amplitude fluctuations in the NF phase shows that the free energy of the system and, consequently, the dielectric response are dominated by polarization-related terms with the flexoelectricity being relevant only at a very weak surface anchoring. Contributions due to the nematic elastic terms are always negligible. The model relates the observed low frequency mode to the director fluctuations weakly coupled to polarization fluctuations

Intrinsically chiral ferronematic liquid crystals : An inversion of the helical twist sense at the chiral nematic – Chiral ferronematic phase transition

Funding Information: The research was supported by the National Science Centre (Poland) under the grant no. 2016/22/A/ST5/00319. C.T.I. and J.M.D.S. acknowledge the financial support of the Engineering and Physical Sciences Research Council [EP/V048775/1].Peer reviewedPostprin

Directing Polymorphism in the Helical Nanofilament Phase

Herein, it is reported that the polymorphism in the helical nanofilament (HNF, B-4) liquid-crystalline phase depends on the fabrication methods, that is, UV-driven formation and template-assisted self-assembly in the nanoconfined geometry. As a result, uniaxially oriented HNFs with different helical structures were obtained, in which generation of the twisted-ribbon and cylindrical-ribbon polymorphs showed that even the molecular lattice has a different orientation. The detailed structures were directly observed by SEM and grazing-incidence X-ray diffraction with synchrotron radiation. The resultant polymorphs could be used in chiro-optical applications due to the capability for fine control of the helical structures

Security use of the chiral photonic film made of helical liquid crystal structures

The color change of photonic crystals (PCs) has been widely studied due to their beauty and anti-counterfeiting applications. Herein, we demonstrated security codes based on chiral PCs that cannot be easily mimicked and are quite different from the conventional technology used currently. The chiral PCs can be made by self-assembly and the structural colors change based on the polarization of the light in the transmission mode. These color changes are easily detected in real-time and are useful in the fabrication of anti-counterfeiting patterns that show beautiful and diverse color changes with rotating polarizers. We believe this can provide a new platform in various security and color-based applications11Nsciescopu