Automated precolumn derivatization procedures in HPLC for biomedical and clinical applications

This thesis describes three automated precolumn derivatization procedures for the analysis of carboxylic group-containing compounds. After derivatization with a suitable label, the derivatives are separated on reversed-phashed HPLC and detected by fluorescence. ... Zie: Summar

Automated precolumn derivatization procedures in HPLC for biomedical and clinical applications

This thesis describes three automated precolumn derivatization procedures for the analysis of carboxylic group-containing compounds. After derivatization with a suitable label, the derivatives are separated on reversed-phashed HPLC and detected by fluorescence. ... Zie: Summar

The Solution Precursor Plasma Spraying Process for Making Zirconia Based Electrolytes

Ceramic layers, such as yttria-stabilized zirconia or scandia-stabilized zirconia, used for functional layers of solid oxide fuel cells, i.e. the gas tight oxygen ion conductive electrolyte or as ceramic component in the porous cermet anode, were obtained by the Solution Precursor Plasma Spray (SPPS) process. The influence of different solvent types on microstructure was analyzed by comparison of coatings sprayed with water-based solution to ethanol-based one. Use of solvent with low surface tension and low boiling point enhances splat formation, coating micro-structure and crystalline structure. Parameter adjustment to receive coatings from nitrate solutions with ethanol as solvent was carried out. Results of Raman spectroscopy indicate that an intermediate of both nitrates (zirconyl and scandium nitrate hydrate) was deposited

Modulation of internuclear communication in multinuclear Ruthenium(II) polypyridyl complexes

The syntheses and characterisation of a series of mononuclear and dinuclear ruthenium polypyridyl complexes based on the bridging ligands 1,3-bis-[5-(2-pyridyl)-1H-1,2,4-triazol-3-yl]benzene, 1,4-bis-[5-(2-pyridyl)-1H-1,2,4-triazol-3-yl]benzene, 2,5-bis-[5-(2-pyridyl)-1H-1,2,4-triazol-3-yl]thiophene, 2,5-bis-[5-pyrazinyl-1H-1,2,4-triazol-3-yl]thiophene are reported. Electrochemical studies indicate that in these systems, the ground state interaction is critically dependent on the nature of the bridging ligand and its protonation state, with strong and weak interactions being observed for thiophene- and phenylene-bridged complexes, respectively

Economic and legal aspects of international environmental agreements: The case of enforcing and stabilising an international CO 2 agreement

The protection of the global environment is impeded by multilateral externalities which the international community attempts to bring under control by entering into international agreements. International agreements, however, can suffer from non-compliance and free-riding behaviour by sovereign states and must therefore be enforced and stabilised internationally. This paper describes instruments for the enforcement and stabilisation of an international CO2 agreement and evaluates them in the light of economic and legal theory. Economic instruments build on repetition and use utility transfers, economic sanctions and flexible treaty adjustments. Important legal instruments are reciprocal obligations and cooperation duties, international funding and transfer rules, treaty suspension, retorsions and reprisals, treaty revision, and monitoring. The paper shows that economic and legal instruments are compatible to a considerable extent. It develops proposals for the enforcement and stabilisation of a global CO2 agreement and other multilateral treaties.International environmental agreements,international cooperation,non-compliance,enforcement,global warming,international law

International Taxation and Takeover Premiums in Cross-border M&As

Cross-border M&As can trigger a higher international taxation of the target’s income. Non-resident dividend withholding taxes may be imposed by the target country, while additional corporate income taxation can be imposed by the acquiring country. Our evidence suggests that takeover premiums fully reflect non-resident dividend withholding taxes, while there is some evidence that they reflect corporate income taxation by the acquiring country as well. In contrast, acquiring firm stock market returns around the bid announcement do not appear to reflect either type of taxation. These results are consistent with previous findings that the gains of M&As primarily accrue to target shareholders