Dynamic charge distribution of pyrazine: Hartree-Fock-Slater calculation and comparison with X-ray diffraction results

The dynamic charge distribution of pyrazine (1,4-diazabenzene) has been calculated using a Hartree—Fock—Slater type wavefunction. The calculations were done in direct space employing a Taylor-series expansion. The calculated charge distribution shows approximate agreement with the results of an accurate X-ray diffraction experiment. A discussion of several factors affecting the agreement between experimental and theoretical results is given

The Notostigmata, a new suborder of Acari

The following studies on this new suborder have been made on material included in the famous French Arachnologist E. Simon's rich collection and lent by him to Drs. H. J. Hansen and W. Sørensen. ..

Crystal structure and charge distribution of pyrazine: effects of extinction, thermal diffuse scattering and series termination

The crystal structure and electronic charge distribution of pyrazine (1,4-diazabenzene) has been determined at 184 K by X-ray methods. The structural results of Wheatley [Acta Cryst. (1957), 10, 182-187] have been confirmed. A clear indication of bonding effects is obtained. Neither positional and thermal parameters nor difference-Fourier maps are affected by extinction. The effect of thermal diffuse scattering (TDS) on positional parameters is also negligible. However, after correction for TDS, thermal parameters increase significantly. The difference-Fourier map is influenced by TDS as well as the inclusion of high-order Fourier terms

Curves and cycles on K3 surfaces

The notion of constant cycle curves on K3 surfaces is introduced. These are curves that do not contribute to the Chow group of the ambient K3 surface. Rational curves are the most prominent examples. We show that constant cycle curves behave in some respects like rational curves. E.g. using Hodge theory one finds that in each linear system there are at most finitely many such curves of bounded order. Over finite fields, any curve is expected to be a constant cycle curve, whereas over number fields this does not hold. The relation to the Bloch--Beilinson conjectures for K3 surfaces over global fields is discussed.Comment: 44 pages, minor revision, reference adde

Piloted simulator study of allowable time delays in large-airplane response

A piloted simulation was performed to determine the permissible time delay and phase shift in the flight control system of a specific large transport-type airplane. The study was conducted with a six degree of freedom ground-based simulator and a math model similar to an advanced wide-body jet transport. Time delays in discrete and lagged form were incorporated into the longitudinal, lateral, and directional control systems of the airplane. Three experienced pilots flew simulated approaches and landings with random localizer and glide slope offsets during instrument tracking as their principal evaluation task. Results of the present study suggest a level 1 (satisfactory) handling qualities limit for the effective time delay of 0.15 sec in both the pitch and roll axes, as opposed to a 0.10-sec limit of the present specification (MIL-F-8785C) for both axes. Also, the present results suggest a level 2 (acceptable but unsatisfactory) handling qualities limit for an effective time delay of 0.82 sec and 0.57 sec for the pitch and roll axes, respectively, as opposed to 0.20 sec of the present specifications for both axes. In the area of phase shift between cockpit input and control surface deflection,the results of this study, flown in turbulent air, suggest less severe phase shift limitations for the approach and landing task-approximately 50 deg. in pitch and 40 deg. in roll - as opposed to 15 deg. of the present specifications for both axes