Spinodal fractionation in a polydisperse square well fluid

Using Kinetic Monte Carlo simulation, we model gas-liquid spinodal decomposition in a size-polydisperse square well fluid, representing a 'near-monodisperse' colloidal dispersion. We find that fractionation (demixing) of particle sizes between the phases begins asserting itself shortly after the onset of phase ordering. Strikingly, the direction of size fractionation can be reversed by a seemingly trivial choice between two inter-particle potentials which, in the monodisperse case, are identical -- we rationalise this in terms of a perturbative, equilibrium theory of polydispersity. Furthermore, our quantitative results show that Kinetic Monte Carlo simulation can provide detailed insight into the role of fractionation in real colloidal systems.Comment: 7 pages, 7 figures, to be published in Phys. Rev.

Radio-wave propagation in the non-Gaussian interstellar medium

Radio waves propagating from distant pulsars in the interstellar medium (ISM), are refracted by electron density inhomogeneities, so that the intensity of observed pulses fluctuates with time. The theory relating the observed pulse time-shapes to the electron-density correlation function has developed for 30 years, however, two puzzles have remained. First, observational scaling of pulse broadening with the pulsar distance is anomalously strong; it is consistent with the standard model only when non-uniform statistics of electron fluctuations along the line of sight are assumed. Second, the observed pulse shapes are consistent with the standard model only when the scattering material is concentrated in a narrow slab between the pulsar and the Earth. We propose that both paradoxes are resolved at once if one assumes stationary and uniform, but non-Gaussian statistics of the electron-density distribution. Such statistics must be of Levy type, and the propagating ray should exhibit a Levy flight. We propose that a natural realization of such statistics may be provided by the interstellar medium with random electron-density discontinuities. We develop a theory of wave propagation in such a non-Gaussian random medium, and demonstrate its good agreement with observations. The qualitative introduction of the approach and the resolution of the anomalous-scaling paradox was presented earlier in [PRL 91, 131101 (2003); ApJ 584, 791 (2003)].Comment: 27 pages, changes to match published versio

An exploratory randomised controlled trial comparing telephone and hospital follow-up after treatment for colorectal cancer

Aim:  Following treatment for colorectal cancer it is common practice for patients to attend hospital clinics at regular intervals for routine monitoring, although debate persists on the benefits of this approach. Nurse-led telephone follow-up is effective in meeting information and psycho-social needs in other patient groups. We explored the potential benefits of nurse-led telephone follow-up for colorectal cancer patients. Method:  Sixty-five patients were randomised to either telephone or hospital follow-up in an exploratory randomised trial. Results:  The telephone intervention was deliverable in clinical practice and acceptable to patients and health professionals. Seventy-five percent of eligible patients agreed to randomization. High levels of satisfaction were evident in both study groups. Appointments in the hospital group were shorter (median 14.0 minutes) than appointments in the telephone group (median 28.9 minutes). Patients in the telephone arm were more likely to raise concerns during consultations. Conclusion:  Historical approaches to follow-up unsupported by evidence of effectiveness and efficiency are not sustainable. Telephone follow-up by specialist nurses may be a feasible option. A main trial comparing hospital and telephone follow-up is justified although consideration needs to be given to trial design and practical issues related to the availability of specialist nurses at study locations

A CLEAN-based Method for Deconvolving Interstellar Pulse Broadening from Radio Pulses

Multipath propagation in the interstellar medium distorts radio pulses, an effect predominant for distant pulsars observed at low frequencies. Typically, broadened pulses are analyzed to determine the amount of propagation-induced pulse broadening, but with little interest in determining the undistorted pulse shapes. In this paper we develop and apply a method that recovers both the intrinsic pulse shape and the pulse broadening function that describes the scattering of an impulse. The method resembles the CLEAN algorithm used in synthesis imaging applications, although we search for the best pulse broadening function, and perform a true deconvolution to recover intrinsic pulse structre. As figures of merit to optimize the deconvolution, we use the positivity and symmetry of the deconvolved result along with the mean square residual and the number of points below a given threshold. Our method makes no prior assumptions about the intrinsic pulse shape and can be used for a range of scattering functions for the interstellar medium. It can therefore be applied to a wider variety of measured pulse shapes and degrees of scattering than the previous approaches. We apply the technique to both simulated data and data from Arecibo observations.Comment: 9 pages, 6 figures, Accepted for publication in the Astrophysical Journa

Anomalous Radio-Wave Scattering from Interstellar Plasma Structures

This paper considers scattering screens that have arbitrary spatial variations of scattering strength transverse to the line of sight, including screens that are spatially well confined, such as disks and filaments. We calculate the scattered image of a point source and the observed pulse shape of a scattered impulse. The consequences of screen confinement include: (1) Source image shapes that are determined by the physical extent of the screen rather than by the shapes of much-smaller diffracting microirregularities. These include image elongations and orientations that are frequency dependent. (2) Variation with frequency of angular broadening that is much weaker than the trademark \nu^{-2} scaling law (for a cold, unmagnetized plasma), including frequency-independent cases; and (3) Similar departure of the pulse broadening time from the usually expected \nu^{-4} scaling law. We briefly discuss applications that include scattering of pulses from the Crab pulsar by filaments in the Crab Nebula; image asymmetries from Galactic scattering of the sources Cyg X-3, Sgr A*, and NGC 6334B; and scattering of background active galactic nuclei by intervening galaxies. We also address the consequences for inferences about the shape of the wavenumber spectrum of electron density irregularities, which depend on scaling laws for the image size and the pulse broadening. Future low-frequency (< 100 MHz) array observations will also be strongly affected by the Galactic structure of scattering material. Our formalism is derived in the context of radio scattering by plasma density fluctuations. It is also applicable to optical, UV and X-ray scattering by grains in the interstellar medium.Comment: 21 pages, LaTeX2e with AASTeX-4.0, 6 PostScript figures, accepted by ApJ, revised version has minor changes to respond to referee comments and suggestion

Diffusion Quantum Monte Carlo Calculations of Excited States of Silicon

The band structure of silicon is calculated at the Gamma, X, and L wave vectors using diffusion quantum Monte Carlo methods. Excited states are formed by promoting an electron from the valence band into the conduction band. We obtain good agreement with experiment for states around the gap region and demonstrate that the method works equally well for direct and indirect excitations, and that one can calculate many excited states at each wave vector. This work establishes the fixed-node DMC approach as an accurate method for calculating the energies of low lying excitations in solids.Comment: 5 pages, 1 figur

Non-Gaussian Radio-Wave Scattering in the Interstellar Medium

It was recently suggested by Boldyrev & Gwinn that the characteristics of radio scintillations from distant pulsars are best understood if the interstellar electron-density fluctuations that cause the time broadening of the radio pulses obey non-Gaussian statistics. In this picture the density fluctuations are inferred to be strong on very small scales ($\sim 10^8-10^{10} {cm}$). We argue that such density structures could correspond to the ionized boundaries of molecular regions (clouds) and demonstrate that the power-law distribution of scattering angles that is required to match the observations arises naturally from the expected intersections of our line of sight with randomly distributed, thin, approximately spherical ionized shells of this type. We show that the observed change in the time-broadening behavior for pulsar dispersion measures $\lesssim 30 {\rm pc} {\rm cm}^{-3}$ is consistent with the expected effect of the general ISM turbulence, which should dominate the scattering for nearby pulsars. We also point out that if the clouds are ionized by nearby stars, then their boundaries may become turbulent on account of an ionization front instability. This turbulence could be an alternative cause of the inferred density structures. An additional effect that might contribute to the strength of the small-scale fluctuations in this case is the expected flattening of the turbulent density spectrum when the eddy sizes approach the proton gyroscale.Comment: 15 pages, 3 figures, accepted to Ap