Immunological studies on the light-harvesting polypeptides of photosystems I and II

AbstractMonoclonal and polyclonal antibodies have been raised against the three apoproteins of the peripheral light-harvesting complex of photosystem I (LHC I) from Pisum sativum L. These antibodies have been used to study the immunological relatedness of the light-harvesting polypeptides of photosystems I and II. The results suggest that there is no immunological/structural relationship between the two light-harvesting systems. The apoproteins of the LHC I fall into two distinct groups corresponding to the two chlorophyllab complexes comprising the PS I antenna

Development of a thin steel strip casting process. Final report

This is a comprehensive effort to develop direct strip casting to the point where a pilot scale program for casting carbon steel strip could be initiated. All important aspects of the technology were being investigated, however the program was terminated early due to a change in the business strategy of the primary contractor, Armco Inc. (focus to be directed at specialty steels, not low carbon steel). At termination, the project was on target on all milestones and under budget. Major part was casting of strip at the experiment casting facility. A new caster, capable of producing direct cast strip of up to 12 in. wide in heats of 1000 and 3000 lb, was used. A total of 81 1000-1200 lb heats were cast as well as one test heat of 3000 lb. Most produced strip of from 0.016 to 0.085 in. thick. Process reliability was excellent for short casting times; quality was generally poor from modern hot strip mill standards, but the practices necessary for good surface quality were identified

Fault seal controls on security of CO2 storage in aquifers

Structural traps for engineered storage of CO2 usually rely on a component of fault seal. In assessing the performance risk of storage sites, the conditions under which natural CO2 and CO2/hydrocarbon mixtures are retained by faults is poorly known. Mechanical failure can occur by flow along the fault plane due to extension, compression or shear. Geometric juxtaposition of aquifers or lack of low permeability fault gouge can enable flow across the fault plane. It is well established that faults which are close to being critically stressed have markedly different properties with respect to both their fluid flow and geomechanical characteristics. Here we examine three case studies. In the first two, the Rotliegend Sandstone reservoirs of the Oak and Fizzy Fields in the Southern North Sea, both of which are natural fault-bound gas fields with high CO2 content, we modify standard fault seal approaches to account for the different physical and chemical properties of CO2 to oil and CH4. In particular the impact of IFT and contact angle on threshold capillary pressure is investigated. Faults of both the Oak and Fizzy fields are analysed for fracture stability and slip tendency and are found to be stable (relative to present-day stresses) in all modelled scenarios and could withstand CO2 column heights in excess of trap height. However, under detailed assessment of fault seal potential for CO2-CH4 mixtures, both fields appear to be limited in column height by cross-fault leakage through carbonate layers of the overlying Zechstein Group. The third case study assessed the Captain Sandstone saline aquifer of the Inner Moray Firth. The in situ stress field was characterised using data available from hydrocarbon exploration wells. A range of potential stress fields were identified, and regional 3D geometric mapping of the major faults was then used to assess fault stability under the different potential stress regimes. Additionally, stereographic plots of fault dip angle and strike were used to deduce the pore pressure perturbation that could cause the mechanical reactivation of faults of any orientation. This accounted for unmapped faults that might truncate the storage reservoir and its overburden. In the stress scenario with the highest differential stress magnitudes low overpressures in the region of ~1.5 MPa could cause the reactivation of preferentially oriented faults, whereas higher induced pressures may be supported in lower differential stress regimes. Higher overpressure would also be required to cause the reactivation of the non-optimally oriented faults

Oxygen non-stoichiometry in Ru-1212 and Ru-1222 magnetosuperconductors

Here we report the results of thermogravimetric (TG) analysis on the oxygen non-stoichiometry of RuSr2GdCu2O8 (Ru-1212) and RuSr2(Gd0.75Ce0.25)2Cu2O10(Ru-1222) samples. With TG annealings carried out in O2 and Ar atmospheres it was found that the oxygen content in Ru-1212 remains less affected upon various annealings, while for Ru-1222 wider-range oxygen-content tuning is possible. When heated in H2/Ar atmosphere the both phases release oxygen upon breaking down to mixtures of metals (Ru and Cu) and binary oxides (CeO2, Gd2O3, and SrO) in two distinct steps around 300 and 450 oC. This reductive decomposition reaction carried out in a thermobalance was utilized in precise oxygen content determination for these phases. It was found that the 100-atm O2-annealed Ru-1212 sample was nearly stoichiometric, while the similarly treated Ru-1222 sample was clearly oxygen deficient. X-ray absorption near-edge (XANES) spectroscopy was applied to estimate the valence of Ru in the samples. In spite of the fact that the Ru-1212 phase was shown to possess less oxygen-deficient RuO2 layer, the valence of Ru as probed with XANES was found to be lower in Ru-1212 than that in Ru-1222.Comment: 11 pages text, 4 pages Figs. To ISS 2002 YOKOHAMA for PHYSICA

Molecular dynamics simulations of oxide memristors: crystal field effects

We present molecular-dynamic simulations of memory resistors (memristors) including the crystal field effects on mobile ionic species such as oxygen vacancies appearing during operation of the device. Vacancy distributions show different patterns depending on the ratio of a spatial period of the crystal field to a characteristic radius of the vacancy-vacancy interaction. There are signatures of the orientational order and of spatial voids in the vacancy distributions for some crystal field potentials. The crystal field stabilizes the patterns after they are formed, resulting in a non-volatile switching of the simulated devices

Research of Gravitation in Flat Minkowski Space

In this paper it is introduced and studied an alternative theory of gravitation in flat Minkowski space. Using an antisymmetric tensor, which is analogous to the tensor of electromagnetic field, a non-linear connection is introduced. It is very convenient for studying the perihelion/periastron shift, deflection of the light rays near the Sun and the frame dragging together with geodetic precession, i.e. effects where angles are involved. Although the corresponding results are obtained in rather different way, they are the same as in the General Relativity. The results about the barycenter of two bodies are also the same as in the General Relativity. Comparing the derived equations of motion for the $n$-body problem with the Einstein-Infeld-Hoffmann equations, it is found that they differ from the EIH equations by Lorentz invariant terms of order $c^{-2}$.Comment: 28 page

The Isotope Effect in Superconductors

We review some aspects of the isotope effect (IE) in superconductors. Our focus is on the influence of factors not related to the pairing mechanism. After summarizing the main results obtained for conventional superconductors, we review the effect of magnetic impurities, the proximity effect and non-adiabaticity on the value of the isotope coefficient (IC). We discuss the isotope effect of $T_c$ and of the penetration depth $\delta$. The theory is applied to conventional and high-$T_c$ superconductors. Experimental results obtained for YBa$_2$Cu$_3$O$_{7-\delta}$ related materials (Zn and Pr-substituted as well as oxygen-depleted systems) and for La$_{2-x}$Sr$_x$CuO$_4$ are discussed.Comment: 31 pages, 10 figures. Review article to appear in "Pair Correlation in Many Fermions Systems", Plenum Press 199

Observability and nonlinear filtering

This paper develops a connection between the asymptotic stability of nonlinear filters and a notion of observability. We consider a general class of hidden Markov models in continuous time with compact signal state space, and call such a model observable if no two initial measures of the signal process give rise to the same law of the observation process. We demonstrate that observability implies stability of the filter, i.e., the filtered estimates become insensitive to the initial measure at large times. For the special case where the signal is a finite-state Markov process and the observations are of the white noise type, a complete (necessary and sufficient) characterization of filter stability is obtained in terms of a slightly weaker detectability condition. In addition to observability, the role of controllability in filter stability is explored. Finally, the results are partially extended to non-compact signal state spaces

Synthesis effects on the magnetic and superconducting properties of RuSr2GdCu2O8

A systematic study on the synthesis of the Ru-1212 compound by preparing a series of samples that were annealed at increasing temperatures and then quenched has been performed. It results that the optimal temperature for the annealing lies around 1060-1065 C; a further temperature increase worsens the phase formation. Structural order is very important and the subsequent grinding and annealing improves it. Even if from the structural point of view the samples appear substantially similar, the physical characterization highlight great differences both in the electrical and magnetic properties related to intrinsic properties of the phase as well as to the connection between the grains as inferred from the resistive and the Curie Weiss behaviour at high temperature as well as in the visibility of ZFC anf FC magnetic signals.Comment: 17 pages, 12 figures. Proc. Int. Workshop " Ruthenate and rutheno-cuprate materials: theory and experiments", Vietri, October 2001. To be published on LNP Series, Springer Verlag, Berlin, C. Noce, A. Vecchione, M. Cuoco, A. Romano Eds, 200