11,194 research outputs found

    Yttrium-catalysed dehydrocoupling of alanes with amines.

    Get PDF

    Thermodynamic Losses in a Gas Spring: Comparison of Experimental and Numerical Results

    Get PDF
    Reciprocating-piston devices can be used as high-efficiency compressors and/or expanders. With an optimal valve design and by carefully adjusting valve timing, pressure losses during intake and exhaust can be largely reduced. The main loss mechanism in reciprocating devices is then the thermal irreversibility due to the unsteady heat transfer between the compressed/expanded gas and the surrounding cylinder walls. In this paper, pressure, volume and temperature measurements in a piston-cylinder crankshaft driven gas spring are compared to numerical results. The experimental apparatus experiences mass leakage while the CFD code predicts heat transfer in an ideal closed gas spring. Comparison of experimental and numerical results allows one to better understand the loss mechanisms in play. Heat and mass losses in the experiment are decoupled and the system losses are calculated over a range of frequencies. As expected, compression and expansion approach adiabatic processes for higher frequencies, resulting in higher efficiency. The objective of this study is to observe and explain the discrepancies obtained between the computational and experimental results and to propose further steps to improve the analysis of the loss mechanisms

    Urban Water Futures: Trends and Potential Disruptions

    Full text link
    Now an ideal time to reflect, to take stock of where the Australian water industry is at, to scan the trends, disruptions and innovation opportunities that lie ahead, to imagine what the water industry could look like in the next 20 to 30 years, and to work out what it would take to realise that vision. As the weight of history, the push of the present and the pull of the future unfold, there is a need to take control, innovate, advocate and consciously head in the desired direction to ensure that the collective vision of the future water industry is fulfilled. The Water Services Association of Australia (WSAA), the peak industry body that represents over 70 public and privately, owned water or water related organisations, commissioned the Institute to research and write this discussion paper on the trends and potential disruptions to Australia’s urban water futures

    A comparison of radial-flow and axial-flow packed beds for thermal energy storage

    Get PDF
    Packed-bed thermal reservoirs are an integral component in a number of electrical energy storage technologies. The present paper concentrates on packed beds where the heat transfer fluid travels along the radial co-ordinate. The governing energy equations and various mechanisms that cause exergetic losses are discussed. The radial-flow packed bed is compared to a dimensionally similar axial-flow packed bed. This approach provides a fair assessment of the underlying behaviour of the two designs. Multi-objective optimisation allows a wide range of design variables to be considered, and is employed to compare optimal radial-flow and axial-flow stores. Axial-flow stores that have been segmented into layers are also considered. The results indicate that radial-flow stores have a comparable thermodynamic performance, but that the additional volume required for by-pass flows leads to higher capital costs.The work described in this paper was undertaken as part of a project funded by the UK Engineering and Physical Sciences Research Council (EPSRC Grant No. EP/J006246/1). The first author was supported by an EPSRC-funded studentship. All authors gratefully acknowledge this support

    Metabolism, personality and pace of life in the Trinidadian guppy, Poecilia reticulata

    Get PDF
    This is the author accepted manuscript. The final version is available from Brill Academic Publishers via the DOI in this record.While among-individual variation in behaviour, or personality, is common across taxa, its mechanistic underpinnings are poorly understood. The Pace of Life syndrome (POLS) provides one possible explanation for maintenance of personality differences. POLS predicts that metabolic differences will covary with behavioural variation, with high metabolism associated with risk prone behaviour and ‘faster’ life histories (e.g., high growth, early maturation). We used a repeated measures approach, assaying metabolic traits (rate and scope), behaviour and growth to test these predictions in the Trinidadian guppy, Poecilia reticulata. We found that while individuals varied significantly in their behaviour and growth rate, more risk prone individuals did not grow significantly faster. Furthermore, after accounting for body size there was no support for among-individual variation in metabolic traits. Thus, while personality differences are clearly present in this population, they do not covary with metabolism and the POLS framework is not supported
    • …
    corecore