1,802 research outputs found
Laser pulses for coherent xuv Raman excitation
We combine multi-channel electronic structure theory with quantum optimal
control to derive Raman pulse sequences that coherently populate a valence
excited state. For a neon atom, Raman target populations of up to 13% are
obtained. Superpositions of the ground and valence Raman states with a
controllable relative phase are found to be reachable with up to 4.5%
population and phase control facilitated by the pump pulse carrier envelope
phase. Our results open a route to creating core-hole excitations in molecules
and aggregates that locally address specific atoms and represent the first step
towards realization of multidimensional spectroscopy in the xuv and x-ray
regimes
Structure and spectroscopy of doped helium clusters using quantum Monte Carlo techniques
We present a comparative study of the rotational characteristics of various
molecule-doped 4He clusters using quantum Monte Carlo techniques. The
theoretical conclusions obtained from both zero and finite temperature Monte
Carlo studies confirm the presence of two different dynamical regimes that
correlate with the magnitude of the rotational constant of the molecule, i.e.,
fast or slow rotors. For a slow rotor, the effective rotational constant for
the molecule inside the helium droplet can be determined by a microscopic
two-fluid model in which helium densities computed by path integral Monte Carlo
are used as input, as well as by direct computation of excited energy levels.
For a faster rotor, the conditions for application of the two-fluid model for
dynamical analysis are usually not fulfilled and the direct determination of
excitation energies is then mandatory. Quantitative studies for three molecules
are summarized, showing in each case excellent agreement with experimental
results
Hybrid Optimization Schemes for Quantum Control
Optimal control theory is a powerful tool for solving control problems in
quantum mechanics, ranging from the control of chemical reactions to the
implementation of gates in a quantum computer. Gradient-based optimization
methods are able to find high fidelity controls, but require considerable
numerical effort and often yield highly complex solutions. We propose here to
employ a two-stage optimization scheme to significantly speed up convergence
and achieve simpler controls. The control is initially parametrized using only
a few free parameters, such that optimization in this pruned search space can
be performed with a simplex method. The result, considered now simply as an
arbitrary function on a time grid, is the starting point for further
optimization with a gradient-based method that can quickly converge to high
fidelities. We illustrate the success of this hybrid technique by optimizing a
holonomic phasegate for two superconducting transmon qubits coupled with a
shared transmission line resonator, showing that a combination of Nelder-Mead
simplex and Krotov's method yields considerably better results than either one
of the two methods alone.Comment: 17 pages, 5 figures, 2 table
Charting the circuit QED design landscape using optimal control theory
With recent improvements in coherence times, superconducting transmon qubits
have become a promising platform for quantum computing. They can be flexibly
engineered over a wide range of parameters, but also require us to identify an
efficient operating regime. Using state-of-the-art quantum optimal control
techniques, we exhaustively explore the landscape for creation and removal of
entanglement over a wide range of design parameters. We identify an optimal
operating region outside of the usually considered strongly dispersive regime,
where multiple sources of entanglement interfere simultaneously, which we name
the quasi-dispersive straddling qutrits (QuaDiSQ) regime. At a chosen point in
this region, a universal gate set is realized by applying microwave fields for
gate durations of 50 ns, with errors approaching the limit of intrinsic
transmon coherence. Our systematic quantum optimal control approach is easily
adapted to explore the parameter landscape of other quantum technology
platforms.Comment: 13 pages, 5 figures, 2 pages supplementary, 1 supplementary figur
The political-military exercise : a progress report
Cover title"August 16, 1963.""#1393"--handwritten on coverIncludes bibliographical referencesProgress report; August 16, 196
Robustness of high-fidelity Rydberg gates with single-site addressability
Controlled phase (CPHASE) gates can in principle be realized with trapped
neutral atoms by making use of the Rydberg blockade. Achieving the ultra-high
fidelities required for quantum computation with such Rydberg gates is however
compromised by experimental inaccuracies in pulse amplitudes and timings, as
well as by stray fields that cause fluctuations of the Rydberg levels. We
report here a comparative study of analytic and numerical pulse sequences for
the Rydberg CPHASE gate that specifically examines the robustness of the gate
fidelity with respect to such experimental perturbations. Analytical pulse
sequences of both simultaneous and stimulated Raman adiabatic passage (STIRAP)
are found to be at best moderately robust under these perturbations. In
contrast, optimal control theory is seen to allow generation of numerical
pulses that are inherently robust within a predefined tolerance window. The
resulting numerical pulse shapes display simple modulation patterns and their
spectra contain only one additional frequency beyond the basic resonant Rydberg
gate frequencies. Pulses of such low complexity should be experimentally
feasible, allowing gate fidelities of order 99.90 - 99.99% to be achievable
under realistic experimental conditions.Comment: 12 pages, 14 figure
Collective Effects in Linear Spectroscopy of Dipole-Coupled Molecular Arrays
We present a consistent analysis of linear spectroscopy for arrays of nearest
neighbor dipole-coupled two-level molecules that reveals distinct signatures of
weak and strong coupling regimes separated for infinite size arrays by a
quantum critical point. In the weak coupling regime, the ground state of the
molecular array is disordered, but in the strong coupling regime it has
(anti)ferroelectric ordering. We show that multiple molecular excitations
(odd/even in weak/strong coupling regime) can be accessed directly from the
ground state. We analyze the scaling of absorption and emission with system
size and find that the oscillator strengths show enhanced superradiant behavior
in both ordered and disordered phases. As the coupling increases, the single
excitation oscillator strength rapidly exceeds the well known Heitler-London
value. In the strong coupling regime we show the existence of a unique spectral
transition with excitation energy that can be tuned by varying the system size
and that asymptotically approaches zero for large systems. The oscillator
strength for this transition scales quadratically with system size, showing an
anomalous one-photon superradiance. For systems of infinite size, we find a
novel, singular spectroscopic signature of the quantum phase transition between
disordered and ordered ground states. We outline how arrays of ultra cold
dipolar molecules trapped in an optical lattice can be used to access the
strong coupling regime and observe the anomalous superradiant effects
associated with this regime.Comment: 12 pages, 7 figures main tex
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