Electrochemical Radical Retro-Allylation of Homoallylic Alcohols with Sulfonyl Hydrazides

We report herein the first examples of electrochemical radical retro-allylation of homoallylic alcohols via the cleavage of the C(sp3)–C(sp3) bond. In this reaction, a variety of sulfonyl hydrazides were employed as the environmentally friendly radical sources via an electrochemical dehydrazination with the release of N2 and H2 as the byproducts, leading to sulfonyl allylic compounds in moderate to good yields. The reaction features metal- and base-free reaction conditions, broad functional group tolerance, and a broad substrate scope

Additional file 1: of A novel RASA1 mutation causing capillary malformation-arteriovenous malformation (CM-AVM): the first genetic clinical report in East Asia

Cutaneous findings of the proband’s family. (DOC 37 kb

Additional file 2: of A novel RASA1 mutation causing capillary malformation-arteriovenous malformation (CM-AVM): the first genetic clinical report in East Asia

Information about the primers used to detect the c.3070A > T (p.Lys1024*) variant. (DOC 35 kb