Teff and log g dependence of velocity fields in M-stars

We present an investigation of velocity fields in early to late M-type hydrodynamic stellar atmosphere models. These velocities will be expressed in classical terms of micro- and macro-turbulent velocities for usage in 1D spectral synthesis. The M-star model parameters range between log g of 3.0 - 5.0 and Teff of 2500 K - 4000 K. We characterize the Teff- and log g-dependence of the hydrodynamical velocity fields in these models with a binning method, and for the determination of micro-turbulent velocities, the Curve of Growth method is used. The macro-turbulent velocities are obtained by convolutions with Gaussian profiles. Velocity fields in M-stars strongly depend on log g and Teff. Their velocity amplitudes increase with decreasing log g and increasing Teff. The 3D hydrodynamical and 1D macro-turbulent velocities range from ~100 m/s for cool high gravity models to ~ 800 m/s - 1000 m/s for hot models or models with low log g. The micro-turbulent velocities range in the order of ~100 m/s for cool models, to ~600 m/s for hot or low log g models. Our M-star structure models are calculated with the 3D radiative-hydrodynamics (RHD) code CO5BOLD. The spectral synthesis on these models is performed with the line synthesis code LINFOR3D.Comment: 8 pages, 6 Figures, Proceeding fot the "Recent directions in astrophysical quantitative spectroscopy and radiation hydrodynamics" conferenc

Teff and logg dependence of FeH in M-dwarfs

We present synthetic FeH band spectra in the z-filter range for several M-dwarf models with logg=3.0-5.0 [cgs] and Teff=2800K -3450K. Our aim is to characterize convective velocities in M-dwarfs and to give a rough estimate of the range in which 3D-atmosphere treatment is necessary and where 1D-atmosphere models suffice for the interpretation of molecular spectral features. This is also important in order to distinguish between the velocity-broadening and the rotational- or Zeeman-broadening. The synthetic spectra were calculated using 3D CO5BOLD radiative-hydrodynamic (RHD) models and the line synthesis code LINFOR3D. We used complete 3D-models and high resolution 3D spectral synthesis for the detailed study of some well isolated FeH lines. The FeH line strength shows a dependence on surface gravity and effective temperature and could be employed to measure both quantities in M-type objects. The line width is related to the velocity-field in the model stars, which depends strongly on surface gravity. Furthermore, we investigate the velocity-field in the 3D M-dwarf models together with the related micro- and macro-turbulent velocities in the 1D case. We also search for effects on the lineshapes.Comment: Cool Stars 15 Conference Proceeding, 4 page

Teff and logg dependence of FeH in M-dwarfs

We present synthetic FeH band spectra in the z-filter range for several M-dwarf models with logg=3.0-5.0 [cgs] and Teff=2800K -3450K. Our aim is to characterize convective velocities in M-dwarfs and to give a rough estimate of the range in which 3D-atmosphere treatment is necessary and where 1D-atmosphere models suffice for the interpretation of molecular spectral features. This is also important in order to distinguish between the velocity-broadening and the rotational- or Zeeman-broadening. The synthetic spectra were calculated using 3D CO5BOLD radiative-hydrodynamic (RHD) models and the line synthesis code LINFOR3D. We used complete 3D-models and high resolution 3D spectral synthesis for the detailed study of some well isolated FeH lines. The FeH line strength shows a dependence on surface gravity and effective temperature and could be employed to measure both quantities in M-type objects. The line width is related to the velocity-field in the model stars, which depends strongly on surface gravity. Furthermore, we investigate the velocity-field in the 3D M-dwarf models together with the related micro- and macro-turbulent velocities in the 1D case. We also search for effects on the lineshapes.Comment: Cool Stars 15 Conference Proceeding, 4 page

Doping of inorganic materials in microreactors – preparation of Zn doped Fe₃O₄ nanoparticles

Microreactor systems are now used more and more for the continuous production of metal nanoparticles and metal oxide nanoparticles owing to the controllability of the particle size, an important property in many applications. Here, for the first time, we used microreactors to prepare metal oxide nanoparticles with controlled and varying metal stoichiometry. We prepared and characterised Zn-substituted Fe₃O₄ nanoparticles with linear increase of Zn content (ZnxFe₃−xO₄ with 0 ≤ x ≤ 0.48), which causes linear increases in properties such as the saturation magnetization, relative to pure Fe₃O₄. The methodology is simple and low cost and has great potential to be adapted to the targeted doping of a vast array of other inorganic materials, allowing greater control on the chemical stoichiometry for nanoparticles prepared in microreactors

Drifting inwards in protoplanetary discs I Sticking of chondritic dust at increasing temperatures

Sticking properties rule the early phases of pebble growth in protoplanetary discs in which grains regularly travel from cold, water-rich regions to the warm inner part. This drift affects composition, grain size, morphology, and water content as grains experience ever higher temperatures. In this study we tempered chondritic dust under vacuum up to 1400 K. Afterwards, we measured the splitting tensile strength of millimetre-sized dust aggregates. The deduced effective surface energy starts out as $\gamma_e = 0.07\,\rm J/m^2$. This value is dominated by abundant iron-oxides as measured by M\"ossbauer spectroscopy. Up to 1250 K, $\gamma_e$ continuously decreases by up to a factor five. Olivines dominate at higher temperature. Beyond 1300 K dust grains significantly grow in size. The $\gamma_e$ no longer decreases but the large grain size restricts the capability of growing aggregates. Beyond 1400 K aggregation is no longer possible. Overall, under the conditions probed, the stability of dust pebbles would decrease towards the star. In view of a minimum aggregate size required to trigger drag instabilities it becomes increasingly harder to seed planetesimal formation closer to a star

The digital data processing concepts of the LOFT mission

The Large Observatory for X-ray Timing (LOFT) is one of the five mission candidates that were considered by ESA for an M3 mission (with a launch opportunity in 2022 - 2024). LOFT features two instruments: the Large Area Detector (LAD) and the Wide Field Monitor (WFM). The LAD is a 10 m 2 -class instrument with approximately 15 times the collecting area of the largest timing mission so far (RXTE) for the first time combined with CCD-class spectral resolution. The WFM will continuously monitor the sky and recognise changes in source states, detect transient and bursting phenomena and will allow the mission to respond to this. Observing the brightest X-ray sources with the effective area of the LAD leads to enormous data rates that need to be processed on several levels, filtered and compressed in real-time already on board. The WFM data processing on the other hand puts rather low constraints on the data rate but requires algorithms to find the photon interaction location on the detector and then to deconvolve the detector image in order to obtain the sky coordinates of observed transient sources. In the following, we want to give an overview of the data handling concepts that were developed during the study phase.Comment: Proc. SPIE 9144, Space Telescopes and Instrumentation 2014: Ultraviolet to Gamma Ray, 91446

Biocompatible magnetic fluids of co-doped iron oxide nanoparticles with tunable magnetic properties

Magnetite (Fe3O4) particles with a diameter around 10 nm have a very low coercivity (Hc) and relative remnant magnetization (Mr/Ms), which is unfavorable for magnetic fluid hyperthermia. In contrast, cobalt ferrite (CoFe2O4) particles of the same size have a very high Hc and Mr/Ms, which is magnetically too hard to obtain suitable specific heating power (SHP) in hyperthermia. For the optimization of the magnetic properties, the Fe2+ ions of magnetite were substituted by Co2+ step by step, which results in a Co doped iron oxide inverse spinel with an adjustable Fe2+ substitution degree in the full range of pure iron oxide up to pure cobalt ferrite. The obtained magnetic nanoparticles were characterized regarding their structural and magnetic properties as well as their cell toxicity. The pure iron oxide particles showed an average size of 8 nm, which increased up to 12 nm for the cobalt ferrite. For ferrofluids containing the prepared particles, only a limited dependence of Hc and Mr/Ms on the Co content in the particles was found, which confirms a stable dispersion of the particles within the ferrofluid. For dry particles, a strong correlation between the Co content and the resulting Hc and Mr/Ms was detected. For small substitution degrees, only a slight increase in Hc was found for the increasing Co content, whereas for a substitution of more than 10% of the Fe atoms by Co, a strong linear increase in Hc and Mr/Ms was obtained. Mössbauer spectroscopy revealed predominantly Fe3+ in all samples, while also verifying an ordered magnetic structure with a low to moderate surface spin canting. Relative spectral areas of Mössbauer subspectra indicated a mainly random distribution of Co2+ ions rather than the more pronounced octahedral site-preference of bulk CoFe2O4. Cell vitality studies confirmed no increased toxicity of the Co-doped iron oxide nanoparticles compared to the pure iron oxide ones. Magnetic heating performance was confirmed to be a function of coercivity as well. The here presented non-toxic magnetic nanoparticle system enables the tuning of the magnetic properties of the particles without a remarkable change in particles size. The found heating performance is suitable for magnetic hyperthermia application. © 2020 by the authors. Licensee MDPI, Basel, Switzerland

The Structure and Mechanism of Cytochrome P450

The unusual hemoprotein called cytochrome P450 is now recognized as representing a variety of monooxygenases with entirely different substrate specificities. In comparison with hememercaptide models it can be concluded that the unusual spectral properties reside in a heme-mercaptide linkage to the protein. The sixth ligand in the ferric form could be a hydroxyl group which is absent in the enzyme-substrate complex. In the reaction cycle the enzyme-substrate complex is reduced and then reacts with dioxygen to form an oxy-complex. Further reduction is believed to yield an »oxenoid« complex of the structure [Fe0]3+, which transfers the oxygen atom to the substrate