Recrystallization and composition dependent thermal fatigue response of different tungsten grades

Industrial pure tungsten grades, manufactured by using a variety of manufactured techniques, are available worldwide in many different types of semifinished products, i.e. rods, wires, ribbons, and sheets. Thereby, the recrystallization temperature varies depending on the applied degree of deformation but also depending on the materials composition, i.e. the materials purity and in particular the level of certain impurities. In order to compare different available industrial tungsten grades and a newly developed PIM-W grade, on the one hand recrystallization studies at three different temperatures from 1300 to 1800 °C for 1 h were performed using Vickers hardness testing. On the other hand, the thermal shock induced low cycle thermal fatigue response of the material in its different recrystallization stages was done using high heat flux tests at 1000 °C base temperature, applying 1000 shots with 1 ms and 0.38 GW/m2 and post mortem characterization, i.e. profilometry and metallography. The obtained results are related to the chemical composition of the individual tungsten grades obtained from Auger electron spectroscopy analyses on cold fracture surfaces

Screening in Ionic Systems: Simulations for the Lebowitz Length

Simulations of the Lebowitz length, $\xi_{\text{L}}(T,\rho)$, are reported for t he restricted primitive model hard-core (diameter $a$) 1:1 electrolyte for densi ties $\rho\lesssim 4\rho_c$ and $T_c \lesssim T \lesssim 40T_c$. Finite-size eff ects are elucidated for the charge fluctuations in various subdomains that serve to evaluate $\xi_{\text{L}}$. On extrapolation to the bulk limit for $T\gtrsim 10T_c$ the low-density expansions (Bekiranov and Fisher, 1998) are seen to fail badly when $\rho > {1/10}\rho_c$ (with $\rho_c a^3 \simeq 0.08$). At highe r densities $\xi_{\text{L}}$ rises above the Debye length, \xi_{\text{D}} \prop to \sqrt{T/\rho}, by 10-30% (upto $\rho\simeq 1.3\rho_c$); the variation is portrayed fairly well by generalized Debye-H\"{u}ckel theory (Lee and Fisher, 19 96). On approaching criticality at fixed $\rho$ or fixed $T$, $\xi_{\text{L}}(T, \rho)$ remains finite with $\xi_{\text{L}}^c \simeq 0.30 a \simeq 1.3 \xi_{\text {D}}^c$ but displays a weak entropy-like singularity.Comment: 4 pages 5 figure

Discretization Dependence of Criticality in Model Fluids: a Hard-core Electrolyte

Grand canonical simulations at various levels, $\zeta=5$-20, of fine- lattice discretization are reported for the near-critical 1:1 hard-core electrolyte or RPM. With the aid of finite-size scaling analyses it is shown convincingly that, contrary to recent suggestions, the universal critical behavior is independent of $\zeta$ (\grtsim 4); thus the continuum $(\zeta\to\infty)$ RPM exhibits Ising-type (as against classical, SAW, XY, etc.) criticality. A general consideration of lattice discretization provides effective extrapolation of the {\em intrinsically} erratic $\zeta$-dependence, yielding (\Tc^ {\ast},\rhoc^{\ast})\simeq (0.0493_{3},0.075) for the $\zeta=\infty$ RPM.Comment: 4 pages including 4 figure

Ionic fluids: charge and density correlations near gas-liquid criticality

The correlation functions of an ionic fluid with charge and size asymmetry are studied within the framework of the random phase approximation. The results obtained for the charge-charge correlation function demonstrate that the second-moment Stillinger-Lovett (SL) rule is satisfied away from the gas-liquid critical point (CP) but not, in general, at the CP. However in the special case of a model without size assymetry the SL rules are satisfied even at the CP. The expressions for the density-density and charge-density correlation functions valid far and close to the CP are obtained explicitely

Density Fluctuations in an Electrolyte from Generalized Debye-Hueckel Theory

Near-critical thermodynamics in the hard-sphere (1,1) electrolyte is well described, at a classical level, by Debye-Hueckel (DH) theory with (+,-) ion pairing and dipolar-pair-ionic-fluid coupling. But DH-based theories do not address density fluctuations. Here density correlations are obtained by functional differentiation of DH theory generalized to {\it non}-uniform densities of various species. The correlation length $\xi$ diverges universally at low density $\rho$ as $(T\rho)^{-1/4}$ (correcting GMSA theory). When $\rho=\rho_c$ one has $\xi\approx\xi_0^+/t^{1/2}$ as $t\equiv(T-T_c)/T_c\to 0+$ where the amplitudes $\xi_0^+$ compare informatively with experimental data.Comment: 5 pages, REVTeX, 1 ps figure included with epsf. Minor changes, references added. Accepted for publication in Phys. Rev. Let

Universality class of criticality in the restricted primitive model electrolyte

The 1:1 equisized hard-sphere electrolyte or restricted primitive model has been simulated via grand-canonical fine-discretization Monte Carlo. Newly devised unbiased finite-size extrapolation methods using temperature-density, (T, rho), loci of inflections, Q = ^2/ maxima, canonical and C_V criticality, yield estimates of (T_c, rho_c) to +- (0.04, 3)%. Extrapolated exponents and Q-ratio are (gamma, nu, Q_c) = [1.24(3), 0.63(3); 0.624(2)] which support Ising (n = 1) behavior with (1.23_9, 0.630_3; 0.623_6), but exclude classical, XY (n = 2), SAW (n = 0), and n = 1 criticality with potentials phi(r)>Phi/r^{4.9} when r \to \infty

Ginzburg Criterion for Coulombic Criticality

To understand the range of close-to-classical critical behavior seen in various electrolytes, generalized Debye-Hueckel theories (that yield density correlation functions) are applied to the restricted primitive model of equisized hard spheres. The results yield a Landau-Ginzburg free-energy functional for which the Ginzburg criterion can be explicitly evaluated. The predicted scale of crossover from classical to Ising character is found to be similar in magnitude to that derived for simple fluids in comparable fashion. The consequences in relation to experiments are discussed briefly.Comment: 4 pages, revtex, 2 tables (latex2.09 required due to revtex's incompatibility with latex2e tables