296 research outputs found
Recrystallization and composition dependent thermal fatigue response of different tungsten grades
Industrial pure tungsten grades, manufactured by using a variety of manufactured techniques, are available worldwide in many different types of semifinished products, i.e. rods, wires, ribbons, and sheets. Thereby, the recrystallization temperature varies depending on the applied degree of deformation but also depending on the materials composition, i.e. the materials purity and in particular the level of certain impurities.
In order to compare different available industrial tungsten grades and a newly developed PIM-W grade, on the one hand recrystallization studies at three different temperatures from 1300 to 1800 °C for 1 h were performed using Vickers hardness testing. On the other hand, the thermal shock induced low cycle thermal fatigue response of the material in its different recrystallization stages was done using high heat flux tests at 1000 °C base temperature, applying 1000 shots with 1 ms and 0.38 GW/m2 and post mortem characterization, i.e. profilometry and metallography. The obtained results are related to the chemical composition of the individual tungsten grades obtained from Auger electron spectroscopy analyses on cold fracture surfaces
Screening in Ionic Systems: Simulations for the Lebowitz Length
Simulations of the Lebowitz length, , are reported
for t he restricted primitive model hard-core (diameter ) 1:1 electrolyte
for densi ties and .
Finite-size eff ects are elucidated for the charge fluctuations in various
subdomains that serve to evaluate . On extrapolation to the
bulk limit for the low-density expansions (Bekiranov and
Fisher, 1998) are seen to fail badly when (with ). At highe r densities rises above the Debye
length, \xi_{\text{D}} \prop to \sqrt{T/\rho}, by 10-30% (upto ); the variation is portrayed fairly well by generalized
Debye-H\"{u}ckel theory (Lee and Fisher, 19 96). On approaching criticality at
fixed or fixed , remains finite with
but displays a
weak entropy-like singularity.Comment: 4 pages 5 figure
Discretization Dependence of Criticality in Model Fluids: a Hard-core Electrolyte
Grand canonical simulations at various levels, -20, of fine- lattice
discretization are reported for the near-critical 1:1 hard-core electrolyte or
RPM. With the aid of finite-size scaling analyses it is shown convincingly
that, contrary to recent suggestions, the universal critical behavior is
independent of (\grtsim 4); thus the continuum RPM
exhibits Ising-type (as against classical, SAW, XY, etc.) criticality. A
general consideration of lattice discretization provides effective
extrapolation of the {\em intrinsically} erratic -dependence, yielding
(\Tc^ {\ast},\rhoc^{\ast})\simeq (0.0493_{3},0.075) for the
RPM.Comment: 4 pages including 4 figure
Ionic fluids: charge and density correlations near gas-liquid criticality
The correlation functions of an ionic fluid with charge and size asymmetry
are studied within the framework of the random phase approximation. The results
obtained for the charge-charge correlation function demonstrate that the
second-moment Stillinger-Lovett (SL) rule is satisfied away from the gas-liquid
critical point (CP) but not, in general, at the CP. However in the special case
of a model without size assymetry the SL rules are satisfied even at the CP.
The expressions for the density-density and charge-density correlation
functions valid far and close to the CP are obtained explicitely
Density Fluctuations in an Electrolyte from Generalized Debye-Hueckel Theory
Near-critical thermodynamics in the hard-sphere (1,1) electrolyte is well
described, at a classical level, by Debye-Hueckel (DH) theory with (+,-) ion
pairing and dipolar-pair-ionic-fluid coupling. But DH-based theories do not
address density fluctuations. Here density correlations are obtained by
functional differentiation of DH theory generalized to {\it non}-uniform
densities of various species. The correlation length diverges universally
at low density as (correcting GMSA theory). When
one has as
where the amplitudes compare informatively with experimental data.Comment: 5 pages, REVTeX, 1 ps figure included with epsf. Minor changes,
references added. Accepted for publication in Phys. Rev. Let
Universality class of criticality in the restricted primitive model electrolyte
The 1:1 equisized hard-sphere electrolyte or restricted primitive model has
been simulated via grand-canonical fine-discretization Monte Carlo. Newly
devised unbiased finite-size extrapolation methods using temperature-density,
(T, rho), loci of inflections, Q = ^2/ maxima, canonical and C_V
criticality, yield estimates of (T_c, rho_c) to +- (0.04, 3)%. Extrapolated
exponents and Q-ratio are (gamma, nu, Q_c) = [1.24(3), 0.63(3); 0.624(2)] which
support Ising (n = 1) behavior with (1.23_9, 0.630_3; 0.623_6), but exclude
classical, XY (n = 2), SAW (n = 0), and n = 1 criticality with potentials
phi(r)>Phi/r^{4.9} when r \to \infty
Ginzburg Criterion for Coulombic Criticality
To understand the range of close-to-classical critical behavior seen in
various electrolytes, generalized Debye-Hueckel theories (that yield density
correlation functions) are applied to the restricted primitive model of
equisized hard spheres. The results yield a Landau-Ginzburg free-energy
functional for which the Ginzburg criterion can be explicitly evaluated. The
predicted scale of crossover from classical to Ising character is found to be
similar in magnitude to that derived for simple fluids in comparable fashion.
The consequences in relation to experiments are discussed briefly.Comment: 4 pages, revtex, 2 tables (latex2.09 required due to revtex's
incompatibility with latex2e tables
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