Atomic helium scattering and diffraction from solid surfaces

It is shown that whether or not diffractive scattering is observed from solid surfaces depends not only on the elastic scattering cross section, i.e. the normalized Debye-Waller factor, but also on the surface structure or local surface potential of the particular solid

Nitric oxide adsorption on Ru(001) at 78 and 120 K: Temperature dependence on the bonding geometry

The influence of surface temperature on NO adsorption on Ru(001) between 78 and 120 K has been investigated by high-resolution electron energy-loss spectroscopy (EELS) and thermal desorption mass spectrometry. Metastable NO adsorption states were isolated at 78 K and were identified by EELS. In all cases, heating of the NO overlayer from 78 to 120 K resulted in an irreversible conversion between adsites. All the measurements were performed in an UHV system that has been described in detail previously. Experimental techniques were employed that have also been documented thoroughly

Effective theory of excitations in a Feshbach resonant superfluid

A strongly interacting Fermi gas, such as that of cold atoms operative near a Feshbach resonance, is difficult to study by perturbative many-body theory to go beyond mean field approximation. Here I develop an effective field theory for the resonant superfluid based on broken symmetry. The theory retains both fermionic quasiparticles and superfluid phonons, the interaction between them being derived non-perturbatively. The theory converges and can be improved order by order, in a manner governed by a low energy expansion rather than by coupling constant. I apply the effective theory to calculate the specific heat and propose a mechanism of understanding the empirical power law of energy versus temperature recently measured in a heat capacity experiment.Comment: 4+ pages, 1 figure; Added references, corrected and clarified minor statements (v.2

Chemisorption on a model bcc metal

The system considered here is that of a single atom with one energy level chemisorbed on the (001) surface of a model bcc metal. We present the change in the density of electronic states Δn (E) due to chemisorption for two cases: one when the adatom is bound to a single substrate atom in the "on‐site" configuration and the other when it is bound to four substrate atoms in the "centered fourfold site." In principle, this change in the density of states Δn can be related to the results of photoemission measurements

Points of General Relativisitic Shock Wave Interaction are "Regularity Singularities" where Spacetime is Not Locally Flat

We show that the regularity of the gravitational metric tensor in spherically symmetric spacetimes cannot be lifted from $C^{0,1}$ to $C^{1,1}$ within the class of $C^{1,1}$ coordinate transformations in a neighborhood of a point of shock wave interaction in General Relativity, without forcing the determinant of the metric tensor to vanish at the point of interaction. This is in contrast to Israel's Theorem which states that such coordinate transformations always exist in a neighborhood of a point on a smooth single shock surface. The results thus imply that points of shock wave interaction represent a new kind of singularity for perfect fluids evolving in spacetime, singularities that make perfectly good sense physically, that can form from the evolution of smooth initial data, but at which the spacetime is not locally Minkowskian under any coordinate transformation. In particular, at such singularities, delta function sources in the second derivatives of the gravitational metric tensor exist in all coordinate systems of the $C^{1,1}$ atlas, but due to cancelation, the curvature tensor remains uniformly bounded.Comment: This article has been withdrawn since the main result is wrong due to an computational error. See arXiv:1506.04081 and arXiv:1409.5060 for a correction of this error and a proof of the opposite statemen

Kinetics of dissociative chemisorption of methane and ethane on Pt(110)-(1X2)

The initial probability of dissociative chemisorption Pr of methane and ethane on the highly corrugated, reconstructed Pt(110)‐(1×2) surface has been measured in a microreactor by counting the number of carbon atoms on the surface following the reaction of methane and ethane on the surface which was held at various constant temperatures between 450 and 900 K during the reaction. Methane dissociatively chemisorbs on the Pt(110)‐(1×2) surface with an apparent activation energy of 14.4 kcal/mol and an apparent preexponential factor of 0.6. Ethane chemisorbs dissociatively with an apparent activation energy of 2.8 kcal/mol and an apparent preexponential factor of 4.7×10^(−3). Kinetic isotope effects were observed for both reactions. The fact that P_r is a strong function of surface temperature implies that the dissociation reactions proceed via a trapping‐mediated mechanism. A model based on a trapping‐mediated mechanism is used to explain the observed kinetic behavior. Kinetic parameters for C–H bond dissociation of the thermally accommodated methane and ethane are extracted from the model

Interaction of H_2 and O_2 on platinum (111)

Abstract Unavailabl

The fate of cannibalized fundamental-plane ellipticals

Evolution and disruption of galaxies orbiting in the gravitational field of a larger cluster galaxy are driven by three coupled mechanisms: 1) the heating due to its time dependent motion in the primary; 2) mass loss due to the tidal strain field; and 3) orbital decay. Previous work demonstrated that tidal heating is effective well inside the impulse approximation limit. Not only does the overall energy increase over previous predictions, but the work is done deep inside the secondary galaxy, e.g. at or inside the half mass radius in most cases. Here, these ideas applied to cannibalization of elliptical galaxies with fundamental-plane parameters. In summary, satellites which can fall to the center of a cluster giant by dynamical friction are evaporated by internal heating by the time they reach the center. This suggests that true merger-produced multiple nuclei giants should be rare. Specifically, secondaries with mass ratios as small as 1\% on any initial orbit evaporate and those on eccentric orbits with mass ratios as small as 0.1\% evolve significantly and nearly evaporate in a galaxian age. Captured satellites with mass ratios smaller than roughly 1\% have insufficient time to decay to the center. After many accretion events, the model predicts that the merged system has a profile similar to that of the original primary with a weak increase in concentration.Comment: 19 pages, 10 Postscript figures, uses aaspp4.sty. Submitted to Astrophysical Journa