136 research outputs found
Carbon superatom thin films
Assembling clusters on surfaces has emerged as a novel way to grow thin films
with targeted properties. In particular, it has been proposed from experimental
findings that fullerenes deposited on surfaces could give rise to thin films
retaining the bonding properties of the incident clusters. However the
microscopic structure of such films is still unclear. By performing quantum
molecular dynamics simulations, we show that C_28 fullerenes can be deposited
on a surface to form a thin film of nearly defect free molecules, which act as
carbon superatoms. Our findings help clarify the structure of disordered small
fullerene films and also support the recently proposed hyperdiamond model for
solid C_28.Comment: 13 pages, RevTeX, 2 figures available as black and white PostScript
files; color PostScript and/or gif files available upon reques
THE SPECTRA OF IN BARIUM, STRONTIUM, AND CALCIUM HALOFLUORIDES
Author Institution: RCA LaboratoriesDivalent samarium in single crystals of the halofluorides of barium, strontium, and calcium has a number of groups of emission lines in the spectral range . The transitions, which correspond to where and , are primarily electric dipole ones. Magnetic dipole transitions are observed in many cases where the symmetry selection rules forbid electric dipole ones. A rather complete spectral assignment has been made with the aid of emission, absorption, and Zeeman spectra. Experimental values of the crystal field parameters for in a site of symmetry mm have been obtained and a comparison of the crystal field matrix elements of the and states has been made. The fluorescence lifetimes as a function of temperature provide information about relative values of some of the non-radiative processes
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