Spin dynamics of frustrated easy-axis triangular antiferromagnet 2H-AgNiO2 explored by inelastic neutron scattering

We report inelastic neutron scattering measurements of the spin dynamics in the layered hexagonal magnet 2H-AgNiO2 which has stacked triangular layers of antiferromagnetically-coupled Ni2+ spins (S=1) ordered in a collinear alternating stripe pattern. We observe a broad band of magnetic excitations above a small gap of 1.8 meV and extending up to 7.5 meV, indicating strongly dispersive excitations. The measured dispersions of the boundaries of the powder-averaged spectrum can be quantitatively explained by a linear spin-wave dispersion for triangular layers with antiferromagnetic nearest- and weak next-nearest neighbor couplings, a strong easy-axis anisotropy and additional weak inter-layer couplings. The resulting dispersion relation has global minima not at magnetic Bragg wavevectors but at symmetry-related soft points and we attribute this anomalous feature to the strong competition between the easy-axis anisotropy and the frustrated antiferromagnetic couplings. We have also calculated the quantum corrections to the dispersion relation to order 1/S in spin-wave theory by extending the work of Chubukov and Jolicoeur [Phys. Rev. B v46, 11137 (1992)] and find that the presence of easy-axis anisotropy significantly reduces the quantum renormalizations predicted for the isotropic model.Comment: 17 pages and 15 figures. To appear in Physical Review

Mean-field Study of Charge, Spin, and Orbital Orderings in Triangular-lattice Compounds ANiO2 (A=Na, Li, Ag)

We present our theoretical results on the ground states in layered triangular-lattice compounds ANiO2 (A=Na, Li, Ag). To describe the interplay between charge, spin, orbital, and lattice degrees of freedom in these materials, we study a doubly-degenerate Hubbard model with electron-phonon couplings by the Hartree-Fock approximation combined with the adiabatic approximation. In a weakly-correlated region, we find a metallic state accompanied by \sqroot3x\sqroot3 charge ordering. On the other hand, we obtain an insulating phase with spin-ferro and orbital-ferro ordering in a wide range from intermediate to strong correlation. These phases share many characteristics with the low-temperature states of AgNiO2 and NaNiO2, respectively. The charge-ordered metallic phase is stabilized by a compromise between Coulomb repulsions and effective attractive interactions originating from the breathing-type electronphonon coupling as well as the Hund's-rule coupling. The spin-orbital-ordered insulating phase is stabilized by the cooperative effect of electron correlations and the Jahn-Teller coupling, while the Hund's-rule coupling also plays a role in the competition with other orbital-ordered phases. The results suggest a unified way of understanding a variety of low-temperature phases in ANiO2. We also discuss a keen competition among different spin-orbital-ordered phases in relation to a puzzling behavior observed in LiNiO2

Graphene coating obtained in a cold-wall CVD process on the Co-Cr Alloy (L-605) for medical applications

Graphene coating on the cobalt-chromium alloy was optimized and successfully carried out by a cold-wall chemical vapor deposition (CW-CVD) method. A uniform layer of graphene for a large area of the Co-Cr alloy (discs of 10 mm diameter) was confirmed by Raman mapping coated area and analyzing specific G and 2D bands; in particular, the intensity ratio and the number of layers were calculated. The effect of the CW-CVD process on the microstructure and the mor-phology of the Co-Cr surface was investigated by scanning X-ray photoelectron microscope (SPEM), atomic force microscopy (AFM), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). Nanoindentation and scratch tests were performed to determine mechanical properties of Co-Cr disks. The results of microbiological tests indicate that the studied Co-Cr alloys covered with a graphene layer did not show a pro-coagulant effect. The obtained results confirm the possibility of using the developed coating method in medical applications, in particular in the field of cardiovascular diseases

On the weak confinement of kinks in the one-dimensional quantum ferromagnet CoNb2O6

In a recent paper Coldea et al (2010 Science {\bf 327} 177) report observation of the weak confinement of kinks in the Ising spin chain ferromagnet CoNb2O6 at low temperatures. To interpret the entire spectra of magnetic excitations measured via neutron scattering, they introduce a phenomenological model, which takes into account only the two-kink configurations of the spin chain. We present the exact solution of this model. The explicit expressions for the two-kink bound-state energy spectra and for the relative intensities of neutron scattering on these magnetic modes are obtained in terms of the Bessel function.Comment: 18 pages, 9 figures; v2: figures 1,3,4 replaced, few misprints correcte

Graphene Coating Obtained in a Cold Wall CVD Process on the Co Cr Alloy L 605 for Medical Applications

Graphene coating on the cobalt chromium alloy was optimized and successfully carried out by a cold wall chemical vapor deposition CW CVD method. A uniform layer of graphene for a large area of the Co Cr alloy discs of 10 mm diameter was confirmed by Raman mapping coated area and analyzing specific G and 2D bands; in particular, the intensity ratio and the number of layers were calculated. The effect of the CW CVD process on the microstructure and the morphology of the Co Cr surface was investigated by scanning X ray photoelectron microscope SPEM , atomic force microscopy AFM , scanning electron microscopy SEM , and energy dispersive X ray spectroscopy EDS . Nanoindentation and scratch tests were performed to determine mechanical properties of Co Cr disks. The results of microbiological tests indicate that the studied Co Cr alloys covered with a graphene layer did not show a pro coagulant effect. The obtained results confirm the possibility of using the developed coating method in medical applications, in particular in the field of cardiovascular disease

The Enzymatic Activity of Type 1 Iodothyronine Deiodinase (D1) is Low in Liver Hemangioma: A Preliminary Study

Type 1 iodothyronine deiodinase (D1) is a crucial enzyme which converts the prohormone thyroxine (T4) into active tri-iodothyronine (T3). There has been strong evidence that the metabolism of thyroid hormones is disturbed in some neoplastic tissues such as thyroid, renal, and breast cancer. However, there are few available data about D1 enzyme activity in benign tumors such as hemangioma, which is the most common primary liver tumor. Hence this study aimed to determine the enzymatic activity of D1 in hemangiomas in relation to healthy liver tissue. Seven tumors and healthy control tissues were obtained from patients who had liver resection due to hemangioma. The activity was assessed by measurement of radioactive iodine released by deiodination catalyzed by D1. It was found that D1 activity was significantly lower in the hemagiomas than in the healthy surrounding tissue (p = 0.0017). The results indicated that thyroid hormones play important roles not only in the regulation of cell metabolism, but also in cell growth, division, and apoptosis. The active form T3 acts through its nuclear receptors and influences the up- and down-regulation of target genes. Healthy liver tissue expresses a high level of D1, but disturbed D1 activity may result in changes in the local concentration of T3 which may impair gene transcription. These finding demonstrate a low enzymatic activity of D1 in liver hemangioma and suggest an as yet unknown role of thyroid hormones in this type of benign liver tumor

A Glycine-Rich Protein Encoded by Sulfur-Deficiency Induced Gene Is Involved in the Regulation of Callose Level and Root Elongation

Glycine-rich proteins (GRPs) with characteristic repetitive glycine stretches are ubiquitous in organisms of all Kingdoms and have distinct functions. It is believed that Gly-rich domains serve mainly for interactions with other proteins. Previously, we identified the tobacco UP30 gene as strongly upregulated by sulfur deficiency. It encodes a protein highly similar to cdiGRP involved in tobacco defense response by elevating cell wall callose deposits thus blocking systemic movement of viruses. The closest Arabidopsis thaliana homologue of UP30 is GRP-3 (At2g05520). Here we report that GRP-3 is induced in Arabidopsis seedlings in both sulfur and nitrogen deficiency conditions. The transgenic Arabidopsis plants either overexpressing or with silenced GRP-3 expression tend to have longer roots especially in the conditions of sulfur deficiency. The effect could be reduced by the addition of auxin to the media. Moreover, we observed the increased callose deposition in both Arabidopsis lines suggesting its negative effects on shoot-to-root movement of auxins in nutrient deficient conditions