Using a plant bioassay to detect herbicide residue

Non-Peer ReviewedSoil residual herbicide activity has been investigated since the early 1960s. One objective has been to provide producers with specific re-crop recommendations. Numerous plant bioassays have been developed to meet this need. The Alberta Research Council (ARC) has been providing a bioassay service to detect symptoms consistent with herbicide carryover since 1986. The objective of this paper is to describe our bioassay methodology and to provide basic information arising from our experience. Soil samples suspected of containing active residues are submitted to the ARC. Once the soil sample is received, the target crop and a sensitive species are planted in both the submitted soil and a check soil, known to be herbicide-free. Samples are evaluated for initial severity of symptoms and recovery over time. Symptoms consistent with herbicide carryover were found in 77% of all samples submitted. The most common crop-herbicide type combination requested is canola-imidazolinone. The primary limitation of bioassays is that damage in the bioassay may not reflect yield loss in a producer’s field. However, bioassays are the only risk-management tool available to producers and can detect the presence of residues below chemical detection thresholds

Use of AlInN layers in optical monitoring of growth of GaN-based structures on free-standing GaN substrates

When lattice matched to GaN, the AlInN ternary alloy has a refractive index ~7% lower than that of GaN. This characteristic can be exploited to perform in situ reflectometry during epitaxial growth of GaN-based multilayer structures on free-standing GaN substrates, by insertion of a suitable Al0.82In0.18N layer. The real-time information on growth rates and cumulative layer thicknesses thus obtainable is particularly valuable in the growth of optical resonant cavity structures. We illustrate this capability with reference to the growth of InGaN/GaN multiple quantum-well structures, including a doubly periodic structure with relatively thick GaN spacer layers between groups of wells. Al0.82In0.18N insertion layers can also assist in the fabrication of resonant cavity structures in postgrowth processing, for example, acting as sacrificial layers in a lift-off process exploiting etch selectivity between Al0.82In0.18N and GaN

Increasing yield and profit by straight-cutting canola

Non-Peer ReviewedStraight combining canola (Brassica napus) can save producers time, fuel costs, and equipment wear. Research was undertaken at three locations to determine if straight combining shatter losses would be reduced sufficiently with higher yield potential to make straight combining viable in western Canada. This research employed a randomized complete block design. Treatments included crop density (low and high), fertility (low and high), time of weed removal (early and late), and harvest time (early and late). Factors were selected to offer a range of yields to evaluate the relationship between potential yield and shatter loss. Different components of potential yield were important in determining yield and seed losses before and during harvest operations. In Lacombe, fertility has been the most important factor. In Vegreville, timing of weed removal was paramount in 2006. At Scott in 2006, it appears that all operations must be conducted under best management practices or there is a substantially increased probability of reduced yield when straight-cutting. These results generally fit the hypothesis that ability to straight-cut is dependent upon maximizing potential yield. Under higher-yielding conditions, a key factor has led to success at straight-cutting. Under low-yielding conditions, all factors contributing to increased potential yield must be used to ensure feasibility of straight-cutting

Increasing yield and profit by straight-cutting canola

Non-Peer ReviewedStraight combining canola (Brassica napus) can save producers time, fuel costs, and equipment wear. Research was undertaken at three locations to determine if straight combining shatter losses would be reduced sufficiently with higher yield potential to make straight combining viable in western Canada. This research employed a randomized complete block design. Treatments included crop density (low and high), fertility (low and high), time of weed removal (early and late), and harvest time (early and late). Factors were selected to offer a range of yields to evaluate the relationship between potential yield and shatter loss. Overall, factors causing shatter loss and crop yield differed between locations. Not surprisingly, crop density was affected by target crop density and percent green seed was affected by harvest timing

Quantum dot emission from site-controlled ngan/gan micropyramid arrays

InxGa1−xN quantum dots have been fabricated by the selective growth of GaN micropyramid arrays topped with InGaN/GaN quantum wells. The spatially, spectrally, and time-resolved emission properties of these structures were measured using cathodoluminescence hyperspectral imaging and low-temperature microphotoluminescence spectroscopy. The presence of InGaN quantum dots was confirmed directly by the observation of sharp peaks in the emission spectrum at the pyramid apices. These luminescence peaks exhibit decay lifetimes of approximately 0.5 ns, with linewidths down to 650 me

Optical spectroscopy of gan microcavities with thicknesses controlled using a plasma etch-back

The effect of an etch-back step to control the cavity length within GaN-based microcavities formed between two dielectric Bragg mirrors was investigated using photoluminescence and reflectivity. The structures are fabricated using a combination of a laser lift-off technique to separate epitaxial III-N layers from their sapphire substrates and electron-beam evaporation to deposit silica/zirconia multilayer mirrors. The photoluminescence measurements reveal cavity modes from both etched and nonetched microcavities. Similar cavity finesses are measured for 2.0 and 0.8 mm GaN cavities fabricated from the same wafer, indicating that the etchback has had little effect on the microcavity quality. For InGaN quantum well samples the etchback is shown to allow controllable reduction of the cavity length. Two etch steps of 100 nm are demonstrated with an accuracy of approximately 5%. The etchback, achieved using inductively coupled plasma and wet chemical etching, allows removal of the low-quality GaN nucleation layer, control of the cavity length, and modification of the surface resulting from lift-off

(In,Ga)N/GaN microcavities with double dielectric mirrors fabricated by selective removal of an (Al,In)N sacrificial layer

Comparable microcavities with 3/2 (~240 nm) active regions containing distributed (In,Ga)N quantum wells, grown on GaN substrates and bounded by two dielectric mirrors, have been fabricated by two different routes: one using laser lift-off to process structures grown on GaN-on-sapphire templates and the second using freestanding GaN substrates, which are initially processed by mechanical thinning. Both exploit the properties of an Al0.83In0.17N layer, lattice matched to the GaN substrate and spacer layers. In both cases cavity quality factors >400 are demonstrated by measurements of the cavity-filtered room-temperature excitonic emission near 410 nm

Measurement of species flux from a bubble using an acousto-electrochemical technique

An acousto-electrochemical technique is presented which, for the first time, offers the potential for measuring the flux of dissolved species in a liquid resulting from bubbles of a specific chosen size in the population. Laboratory trials are presented, but the device itself was damaged in the surf zone and no data was obtained from the ocean deployment. Nevertheless, the preceding laboratory tests demonstrate the viability of the technique. The device responds to perturbations of the fluid around a small electrode. Three such sources of motion must be characterised if it is to achieve the objective stated above. First, the perturbations resulting form the translatory motions of bubbles in the liquid. To obtain bubble radius resolution in the measurement of mass flux, however, it is necessary to apply to driving (‘pump’) sound field. Bubbles close to resonance will, in addition to a translatory motion, impart to the liquid a component of mass flux at the pump frequency. This is detected. However to show that this is the result of bubble wall pulsation, and not someother coupling, the amplitude of the pump field is increased until the electrochemical sensor detects Faraday waves on the bubble wall. Not only does this prove the relation between mass flux to bubble wall motion, it provides a second route by which the radius-resolved component of mass flux might be identified. In these preliminary laboratory tests, electrochemical detection of these motions was achieved through the observation of current produced by the reduction of a suitable redox agent present within the liquid phase of the solution employed. Preparations were made to obtain preliminary data from the Hurst Spit 2000 surf zone trial, but the device was damaged by the environment

Prairie Carnation®: a new crop for western Canada

Non-Peer ReviewedPrairie Carnation (Saponaria vaccaria L.) is a member of the family Caryophyllaceae. The crop is intended for large-scale contract production on the prairies. Several members of this plant family are grown as ornamentals. No members of the Caryopyhllaceae are used as food or feed products in Canada. Prairie Carnation® will be used as a renewable bio-product crop to produce fine starches for cosmetics and other industries. Saponins extracted from the seed will be used for veterinary and medical applications and are being tested as a vaccine adjuvant and also as an active compound for some clinical treatments. Peptides from Saponaria seeds show antibiotic effects and are tested as cosmetic active compounds. Research has been conducted to advance crop development in 2005 and 2006 at the Alberta Research Council (ARC) in Vegreville, Alberta. Trials included seeding date, seeding rate x spatial arrangement, fertility, timing of fungicide application and crop tolerance to herbicides. Preliminary results indicate that Prairie Carnation® has considerable potential to be a commercially and agronomically successful crop