1 research outputs found
Studies of phase diagram of a liquid crystal with 4-[2-(3-fluorophenyl)ethyl]biphenyl core of molecules
Basing on the results of di erential scanning calorimetry and transmitted light intensity methods and texture
observations in the temperature range from −50 ◦C to 90 ◦C phase diagram of 1-[3- uoro-4-(1-methylheptyloxycarbonyl)phenyl]-2-[4′
-(2,2,3,3,4,4,4-hepta uorobutoxybutoxy)biphenyl-4-yl]ethane was established. Monotropic
system of thermodynamic phases was found. On cooling the isotropic phase transforms at 85 ◦C to ferroelectric
SmC∗ phase and further two liquid crystalline phases, antiferroelectric SmC∗
A and SmI, and a metastable crystal
Cr2 reveal. During heating exothermic anomaly in the wide temperature range was observed and ascribed to
evolution of Cr2 to the stable crystal Cr1. On further heating both SmC∗
A and SmC∗ phases were observed.
Thermodynamic parameters were calculated for all phase transitions. During rapid cooling (10 K/min) vitri cation
of metastable Cr2 crystal at T_g = −115 ◦C was registered