A supramolecular radical cation: folding-enhanced electrostatic effect for promoting radical-mediated oxidation.

We report a supramolecular strategy to promote radical-mediated Fenton oxidation by the rational design of a folded host-guest complex based on cucurbit[8]uril (CB[8]). In the supramolecular complex between CB[8] and a derivative of 1,4-diketopyrrolo[3,4-c]pyrrole (DPP), the carbonyl groups of CB[8] and the DPP moiety are brought together through the formation of a folded conformation. In this way, the electrostatic effect of the carbonyl groups of CB[8] is fully applied to highly improve the reactivity of the DPP radical cation, which is the key intermediate of Fenton oxidation. As a result, the Fenton oxidation is extraordinarily accelerated by over 100 times. It is anticipated that this strategy could be applied to other radical reactions and enrich the field of supramolecular radical chemistry in radical polymerization, photocatalysis, and organic radical battery and holds potential in supramolecular catalysis and biocatalysis

Revisiting the Ω(2012)\Omega(2012) as a hadronic molecule and its strong decays

Recently, the Belle collaboration measured the ratios of the branching fractions of the newly observed $\Omega(2012)$ excited state. They did not observe significant signals for the $\Omega(2012) \to \bar{K} \Xi^*(1530) \to \bar{K} \pi \Xi$ decay, and reported an upper limit for the ratio of the three body decay to the two body decay mode of $\Omega(2012) \to \bar{K} \Xi$. In this work, we revisit the newly observed $\Omega(2012)$ from the molecular perspective where this resonance appears to be a dynamically generated state with spin-parity $3/2^-$ from the coupled channels interactions of the $\bar{K} \Xi^*(1530)$ and $\eta \Omega$ in $s$-wave and $\bar{K} \Xi$ in $d$-wave. With the model parameters for the $d$-wave interaction, we show that the ratio of these decay fractions reported recently by the Belle collaboration can be easily accommodated.Comment: Published version. Published in Eur.\ Phys.\ J.\ C {\bf 80}, 361 (2020