1 research outputs found
Molecular Engineering of D–D−π–A-Based Organic Sensitizers for Enhanced Dye-Sensitized Solar Cell Performance
A series of molecularly engineered
and novel dyes WS1, WS2, WS3,
and WS4, based on the D35 donor, 1-(4-hexylphenyl)-2,5-diÂ(thiophen-2-yl)-1<i>H</i>-pyrrole and 4-(4-hexylphenyl)-4<i>H</i>-dithienoÂ[3,2-<i>b</i>:2′,3′-<i>d</i>]Âpyrrole as Ï€-conjugating
linkers, were synthesized and compared to the well-known LEG4 dye.
The performance of the dyes was investigated in combination with an
electrolyte based on CoÂ(II/III) complexes as redox shuttles. The electron
recombination between the redox mediators in the electrolyte and the
TiO<sub>2</sub> interface decreases upon the introduction of 4-hexylybenzene
entities on the 2,5-diÂ(thiophen-2-yl)-1<i>H</i>-pyrrole
and 4<i>H</i>-dithienoÂ[3,2-<i>b</i>:2′,3′-<i>d</i>]Âpyrrole linker units, probably because of steric hindrance.
The open circuit photovoltage of WS1-, WS2-, WS3-, and WS4-based devices
in combination with the CoÂ(II/III)-based electrolyte are consistently
higher than those based on a I<sup>–</sup>/I<sub>3</sub><sup>–</sup> electrolyte by 105, 147, 167, and 75 mV, respectively.
The WS3-based devices show the highest power conversion efficiency
of 7.4% at AM 1.5 G 100 mW/cm<sup>2</sup> illumination mainly attributable
to the high open-circuit voltage (<i>V</i><sub>OC</sub>)