Appraising Forgeability and Surface Cracking in New Generation Cast and Wrought Superalloys

Surface cracking poses a major problem in industrial forging, but the scientific understanding of the phenomenon is hampered by the difficulty of replicating it in a laboratory setting. In this work, a novel laboratory-scale experimental method is presented to investigate forgeability in new generation cast and wrought superalloys. This new approach makes possible appraising the prevalence and severity of surface cracking by mimicking the die chilling effects characteristic of hot die forging. Two high γ′-reinforced alloys are used to explore this methodology. A Gleeble thermo-mechanical simulator is used to conduct hot compression tests following a non-isothermal cycle, with the aim to simulate the cooling of the near-surface regions during the forging process. FEA simulations, sample geometry design, and heat-treatments are used to ensure the correspondence between laboratory and real-scale forging. A wide range of surface cracking results are obtained for different forging temperatures and cooling rates—proving the soundness of the method. Surprisingly, samples heated up to higher initial temperatures typically show more extensive surface cracking. These findings indicate that—along with the local mechanical conditions of the forging—die-chilling effects and forging temperatures are paramount in controlling surface cracking, as they dictate the key variables governing the distribution and kinetics of γ′ formation

Gold(I)-Catalyzed Coupling Reactions for the Synthesis of Diverse Small Molecules Using the Build/Couple/Pair Strategy

The build/couple/pair strategy has yielded small molecules with stereochemical and skeletal diversity by using short reaction sequences. Subsequent screening has shown that these compounds can achieve biological tasks considered challenging if not impossible (‘undruggable’) for small molecules. We have developed gold(I)-catalyzed cascade reactions of easily prepared propargyl propiolates as a means to achieve effective intermolecular coupling reactions for this strategy. Sequential alkyne activation of propargyl propiolates by a cationic gold(I) catalyst yields an oxocarbenium ion that we previously showed is trapped by C-based nucleophiles at an extrannular site to yield α-pyrones. Here, we report O-based nucleophiles react by ring opening to afford a novel polyfunctional product. In addition, by coupling suitable building blocks, we subsequently performed intramolecular pairing reactions that yield diverse and complex skeletons. These pairing reactions include one based on a novel aza-Wittig-6π-electrocyclization sequence and others based on ring-closing metathesis reactions.Chemistry and Chemical Biolog

Appraising Forgeability and Surface Cracking in New Generation Cast and Wrought Superalloys

Abstract Surface cracking poses a major problem in industrial forging, but the scientific understanding of the phenomenon is hampered by the difficulty of replicating it in a laboratory setting. In this work, a novel laboratory-scale experimental method is presented to investigate forgeability in new generation cast and wrought superalloys. This new approach makes possible appraising the prevalence and severity of surface cracking by mimicking the die chilling effects characteristic of hot die forging. Two high γ′-reinforced alloys are used to explore this methodology. A Gleeble thermo-mechanical simulator is used to conduct hot compression tests following a non-isothermal cycle, with the aim to simulate the cooling of the near-surface regions during the forging process. FEA simulations, sample geometry design, and heat-treatments are used to ensure the correspondence between laboratory and real-scale forging. A wide range of surface cracking results are obtained for different forging temperatures and cooling rates—proving the soundness of the method. Surprisingly, samples heated up to higher initial temperatures typically show more extensive surface cracking. These findings indicate that—along with the local mechanical conditions of the forging—die-chilling effects and forging temperatures are paramount in controlling surface cracking, as they dictate the key variables governing the distribution and kinetics of γ′ formation.</jats:p