84 research outputs found
Superdeformed rotational bands in the Mercury region; A Cranked Skyrme-Hartree-Fock-Bogoliubov study
A study of rotational properties of the ground superdeformed bands in \Hg{0},
\Hg{2}, \Hg{4}, and \Pb{4} is presented. We use the cranked
Hartree-Fock-Bogoliubov method with the {\skm} parametrization of the Skyrme
force in the particle-hole channel and a seniority interaction in the pairing
channel. An approximate particle number projection is performed by means of the
Lipkin-Nogami prescription. We analyze the proton and neutron quasiparticle
routhians in connection with the present information on about thirty presently
observed superdeformed bands in nuclei close neighbours of \Hg{2}.Comment: 26 LaTeX pages, 14 uuencoded postscript figures included, Preprint
IPN-TH 93-6
Description of superdeformed nuclei in the interacting boson model
The interacting boson model is extended to describe the spectroscopy of
superdeformed bands. Microscopic structure of the model in the second minimum
is discussed and superdeformed bosons are introduced as the new building
blocks. Solutions of a quadrupole Hamiltonian are implemented through the
expansion method. Effects of the quadrupole parameters on dynamic moment of
inertia and electric quadrupole transition rates are discussed and the results
are used in a description of superdeformed bands in the Hg-Pb and Gd-Dy
regions.Comment: 18 pages revtex, 9 figures available upon reques
Fabrication of Pt/Ru Nanoparticle Pair Arrays with Controlled Separation and their Electrocatalytic Properties
Aiming at the investigation of spillover and transport effects in electrocatalytic reactions on bimetallic catalyst electrodes, we have prepared novel, nanostructured electrodes consisting of arrays of homogeneously distributed pairs of Pt and Ru nanodisks of uniform size and with controlled separation on planar glassy carbon substrates. The nanodisk arrays (disk diameter approximate to 60 nm) were fabricated by hole-mask colloidal lithography; the separation between pairs of Pt and Ru disks was varied from -25 nm (overlapping) via +25 nm to +50 nm. Morphology and (surface) composition of the Pt/Ru nanodisk arrays Were characterized by scanning electron microscopy, energy dispersive X-ray analysis, and X-ray Photoelectron spectroscopy, the electrochemical/electrocatalytic properties were explored by cyclic voltammetry, COad monolayer oxidation ("COad stripping"), and potentiodynamic hydrogen oxidation. Detailed analysis of the 2 COad oxidation peaks revealed that on all bimetallic pairs these cannot be reproduced by superposition of the peaks obtained on electrodes with Pt/Pt or Ru/Ru pairs, pointing to effective Pt-Ru interactions even between rather distant pairs (50 nm). Possible reasons for this observation and its relevance for the understanding of previous reports of highly active catalysts with separate Pt and Ru nanoparticles are discussed. The results clearly demonstrate that this preparation method is perfectly suited for fabrication of planar model electrodes with well-defined arrays of bimetallic nanodisk pairs, which opens up new possibilities for model studies of electrochemical/electrocatalytic reactions
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