The ∼860-Ma, cordilleran-type guandaoshan dioritic pluton in the Yangtze Block, SW China: Implications for the origin of neoproterozoic magmatism

The tectonic setting of the widespread Neoproterozoic igneous rocks in South China has long been a matter of debate. Situated in the western margin of the Yangtze Block of South China, the Guandaoshan pluton is composed of diorite in the core and quartz diorite in the margin. Both types contain abundant mafic enclaves and mafic dikes. This pluton is dated at 858 ± 7 Ma by the SHRIMP zircon U-Pb method. The rocks have SiO 2 contents of 52.8-63.8 wt%, Al 2O 3 contents of 17.4-20.6 wt%, Na 2O contents of 2.14-3.74 wt%, and K 2O contents of 0.44-1.61 wt%. They are calcalkaline with an Al saturation index, A/CNK 1, and they have Fe numbers <0.8 (Fe 2O 3/[Fe 2O 3 + MgO]). Their total rare earth element (REE) contents range from 19 to 45 ppm, with concave chondrite-normalized patterns slightly depleted in middle REEs, indicating extensive amphibole fractionation. Their whole-rock ε Nd(t) values range from +3.9 to +5.1, and initial 87Sr/ 86Sr ratios range from 0.7028 to 0.7033. They have zircon ε Hf(t) values ranging from +11 to +17, with mean Hf model ages of around 860 Ma, clearly indicating a depleted-mantle source. In the primitive mantle-normalized trace element spider diagram, the rocks show pronounced enrichment of Rb, Ba, Th, and Pb and depletion of Nb, Ta, and Ti, a typical arc signature. The Guandaoshan pluton is an amphibole-rich, calc-alkaline, Cordilleran-type granitoid, a typical product of subduction-zone magmatism. The occurrence of this Neoproterozoic Cordilleran-type granitoid suggests that the western margin of the Yangtze Block was an Andean-type continental margin at that time, rather than mantle plume-related rifting setting. © 2008 by The University of Chicago. All rights reserved.published_or_final_versio

A Peer-Led, Social Media-Delivered, Safer Sex Intervention for Chinese College Students: Randomized Controlled Trial

Background: The peer-led, social media-delivered intervention is an emerging method in sexual health promotion. However, no research has yet investigated its effectiveness as compared with other online channels or in an Asian population. Objective: The objective of this study is to compare a peer-led, social media-delivered, safer sex intervention with a sexual health website. Both conditions target Chinese college students in Hong Kong. Methods: A randomized controlled trial was conducted with a peer-led, safer sex Facebook group as the intervention and an existing online sexual health website as the control. The intervention materials were developed with peer input and followed the information-motivation-behavioral skills model; the intervention was moderated by peer educators. The participants filled out the online questionnaires before and after the 6-week intervention period. Outcome evaluations included safer sex attitudes, behavioral skills, and behaviors, while process evaluation focused on online experience, online-visiting frequency, and online engagement. The effect of online-visiting frequency and online engagement on outcome variables was investigated. Results: Of 196 eligible participants—100 in the control group and 96 in the intervention group—who joined the study, 2 (1.0%) control participants joined the Facebook group and 24 of the remaining 194 participants (12.4%) were lost to follow-up. For the process evaluation, participants in the intervention group reported more satisfying online experiences (P<.001) and a higher level of online-visiting frequency (P<.001). They also had more positive comments when compared with the control group. For outcome evaluation, within-group analysis showed significant improvement in condom use attitude (P=.02) and behavioral skills (P<.001) in the intervention group, but not in the control group. No significant between-group difference was found. After adjusting for demographic data, increased online-visiting frequency was associated with better contraceptive use behavioral intention (P=.05), better behavioral skills (P=.02), and more frequent condom use (P=.04). Conclusions: A peer-led, social media-delivered, safer sex intervention was found to be feasible and effective in improving attitudes toward condom use and behavioral skills, but was not significantly more effective than a website. Future research may focus on the long-term effectiveness and cost-effectiveness of this popular method, as well as the potential cultural differences of using social media between different countries.published_or_final_versio

Preparation of continually graded barriers of YPrBaCuO for HTS Josephson junctions

We report preparation of a novel barrier structure for high Tc superconducting multilayer Josephson junctions using a simple composite target technique. Such a barrier consists of Yx Pr1-xBa2Cu3Oy with a continually varied concentration of yttrium. In this barrier no lattice mismatch and other incompatibility problems occur between adjacent layers. Thus the formation of interfacial defects and structural strain can be mostly prevented. The Josephson coupling takes place at the electrically formed interfaces rather than the structural interfaces. A particular feature of these junctions is that the effective thickness of the barrier strongly depends on the measuring temperature and the concentration gradient. The absence of the structural interface in the weak link region greatly enhances the reproducibility and the performance of these junctions.published_or_final_versio

A Quantile Variant of the EM Algorithm and Its Applications to Parameter Estimation with Interval Data

The expectation-maximization (EM) algorithm is a powerful computational technique for finding the maximum likelihood estimates for parametric models when the data are not fully observed. The EM is best suited for situations where the expectation in each E-step and the maximization in each M-step are straightforward. A difficulty with the implementation of the EM algorithm is that each E-step requires the integration of the log-likelihood function in closed form. The explicit integration can be avoided by using what is known as the Monte Carlo EM (MCEM) algorithm. The MCEM uses a random sample to estimate the integral at each E-step. However, the problem with the MCEM is that it often converges to the integral quite slowly and the convergence behavior can also be unstable, which causes a computational burden. In this paper, we propose what we refer to as the quantile variant of the EM (QEM) algorithm. We prove that the proposed QEM method has an accuracy of $O(1/K^2)$ while the MCEM method has an accuracy of $O_p(1/\sqrt{K})$. Thus, the proposed QEM method possesses faster and more stable convergence properties when compared with the MCEM algorithm. The improved performance is illustrated through the numerical studies. Several practical examples illustrating its use in interval-censored data problems are also provided

Provenance and tectonic setting of the Neoproterozoic Yanbian Group, western Yangtze Block (SW China)

Tectonic evolution of the Yangtze Block of South China during Neoproterozoic time has been a major focus of debate and is important in the reconstruction of the Rodinian supercontinent. The Yanbian Group in the western margin of the Yangtze Block is a well-preserved Neoproterozoic volcanic-sedimentary sequence and provides a rare opportunity to examine the provenance and tectonic setting. It consists of a lower part composed of ∼1500 m thick basaltic lavas and an upper part of ∼3500 m thick flysch deposits. The flysch sequence contains typical deep marine turbidites consisting mainly of fine-grained volcaniclastic sandstones and mudstones, indicating a submarine fan depositional system. Detrital zircon dating yields ages ranging from ca. 865 Ma to 1000 Ma with two peaks at ca. 900 Ma and 920 Ma, respectively. The Yanbian Group is intruded by the ∼860 Ma Guandaoshan dioritic pluton, constraining its depositional age at ca. 870 Ma. The sandstones contain abundant feldspar and lithic fragments with minor amounts of quartz and have an average composition of Q 16F 35L 49, suggesting a proximal source and an undissected to transitional arc setting. The lithic fragments in the sandstones point to andesitic and felsic volcanic rock sources. The sandstones and mudstones have intermediate SiO 2/Al 2O 3 (typically 3-6), high Fe 2O 3 + MgO contents (5-12 wt%), and moderate to high K 2O/Na 2O ratios (generally 0.1-1 and 1-10 for sandstones and mudstones, respectively). In comparison with average upper continental crust, they show strong negative Nb-Ta anomalies, slight depletion of Zr-Hf, La and Th, but moderate enrichment of V, Cr, Ni, and Sc. These rocks show LREE enrichment (La/Yb N = 5.3-7.4) with flat HREE, and pronounced negative Eu anomalies (Eu/Eu * = 0.6-0.74) in chondrite-normalized REE patterns, similar to post-Archean shales. Geochemical data for these rocks suggest an arc setting and intermediate-felsic volcanic source, consistent with a back-arc basin scenario for the basaltic lavas in the lower Yanbian Group. Together with regional geological evidence, the turbidites of the Yanbian Group strongly support a model in which the western margin of the Yangtze Block was a major magmatic arc, active probably from ∼920 Ma to 740 Ma, a period of more than 180 million years. © 2008 Elsevier B.V. All rights reserved.postprin

High-Tc ramp-type Josephson junctions with a continually graded Y1–xPrxBa2Cu3Oy barrier

High-Tc Josephson junctions with a graded barrier have been prepared by using a composite target. Such a barrier is synthesized by utilizing Y1–xPrxBa2Cu3Oy with a continually graded concentration of Pr, in which no lattice mismatch and other incompatible problems take place. The structural interfaces are absent in the weak link region and Josephson coupling occurs at the naturally formed superconducting/normal interfaces within the Y1–xPrxBa2Cu3Oy layer. Thus, it can significantly enhance the reproducibilty and performance of these junctions. The temperature dependences of the barrier thickness and Josephson were also studied. © 2001 American Institute of Physics.published_or_final_versio

Microwave Oscillations of a Nanomagnet Driven by a Spin-Polarized Current

We describe direct electrical measurements of microwave-frequency dynamics in individual nanomagnets that are driven by spin transfer from a DC spin-polarized current. We map out the dynamical stability diagram as a function of current and magnetic field, and we show that spin transfer can produce several different types of magnetic excitations, including small-angle precession, a more complicated large-angle motion, and a high-current state that generates little microwave signal. The large-angle mode can produce a significant emission of microwave energy, as large as 40 times the Johnson-noise background.Comment: 12 pages, 3 figure

Thermodynamic Properties of Supported and Embedded Metallic Nanocrystals: Gold on/in SiO2

We report on the calculations of the cohesive energy, melting temperature and vacancy formation energy for Au nanocrystals with different size supported on and embedded in SiO2. The calculations are performed crossing our previous data on the surface free energy of the supported and embedded nanocrystals with the theoretical surface-area-difference model developed by W. H. Qi for the description of the size-dependent thermodynamics properties of low-dimensional solid-state systems. Such calculations are employed as a function of the nanocrystals size and surface energy. For nanocrystals supported on SiO2, as results of the calculations, we obtain, for a fixed nanocrystal size, an almost constant cohesive energy, melting temperature and vacancy formation energy as a function of their surface energy; instead, for those embedded in SiO2, they decreases when the nanocrystal surface free energy increases. Furthermore, the cohesive energy, melting temperature and vacancy formation energy increase when the nanocrystal size increases: for the nanocrystals on SiO2, they tend to the values of the bulk Au; for the nanocrystals in SiO2 in correspondence to sufficiently small values of their surface energy, they are greater than the bulk values. In the case of the melting temperature, this phenomenon corresponds to the experimentally well-known superheating process

Assessing Participation and Effectiveness of the Peer-Led Approach in Youth Sexual Health Education: Systematic Review and Meta-Analysis in More Developed Countries

Sexual health education for young people is crucial not only for development of norms but also for protection against vulnerabilities during this stage in life. Although several systematic reviews have examined the effectiveness of peer-led sex education, none have focused on the extent of peer participation. The purpose of this review was to evaluate peer-led sexual health education interventions in more developed countries (MDCs). Electronic and manual searches across five social science, education, and medical databases were conducted. Fifteen articles were selected in total. Most (10 of 15) studies gave low or no responsibility to peers. The majority of articles found improvements in sexual health knowledge (13 of 14) and attitudes (11 of 15) at postintervention stages. Two studies showed improved self-efficacy, and three showed behavioral changes. A preliminary synthesis of effectiveness and level of participation was done. Meta-analysis revealed a large effect on knowledge change (Hedges’ g = 0.84, 95% confidence interval [CI]: 0.43 to 1.25) and a medium effect on attitude change (Hedges’ g = 0.49, 95% CI: 0.19 to 0.80). Peer-led interventions could be a powerful tool. This review shows that this approach is effective in changing knowledge and attitudes but not behaviors. Further research and action are needed to understand optimal implementation.postprin

Fiber metallic glass laminates

Author name used in this publication: J. LuVersion of RecordPublishe