Robust paramagnetism in Bi2-xMxRu2O7 (M=Mn,Fe,Co,Ni,Cu) pyrochlore

We report physical property characterization of Bi2-xMxRu2O7 pyrochlores, including magnetic suseptibility, resistivity, and Seebeck coefficients. The solid solution exists up to x=0.5 for (M=Cu,Ni,Co) and up to x=0.1 for (M=Fe,Mn). None of the doped materials exhibit ferromagnetism or any localized ruthenium moment behavior. Instead we find the Ru-O and Bi-O sublattices to be essentially independent, with any magnetism resulting from the unpaired transition metal dopant spins. Cobalt substitution for bismuth results in localized Co{2+}, and low temperature spin-glass transitions in several cases. Nickel moments on the pyrochlore lattice display properties intermediate to localized and itinerant. Finally, copper doping results in only an enhancement of the Pauli metallic density of states.Comment: submitted, Phys. Rev.

Study on the Failure Mechanism of the Polymorphic Mixture for Remanifactured Machinery Parts

The polymorphic mixture failure mode for multiple heterogeneity of remanifactured (RM) machinery parts makes it difficult to assess their lifetime. The Weibull distribution failure model of RM parts (substrate, coating layer, bonding surface and sudden failure) is constructed with failure time statistics of the parts in service, the latter is used to characterize the failure patterns of RM parts. In view of the multiple heterogeneity of RM parts, the Kaplan–Meier type decoupling method is used to analyze four sets of failure statistics, and each state of the Weibull failure function of the above parts is solved. It reveals the in-service failure mechanism of polymorphic mixtures for multiple heterogeneity of RM machinery parts. The validity and feasibility of the model are verified by the case study. Research results provide the theoretical basis for the design and preparation of a RM alloy powder and the improvement of RM technology. Moreover, the method for lifetime prediction and failure time evaluation of RM parts is proposed and validatedХарактер разрушения полиморфной смеси в условиях множественной гетерогенности модифицированных деталей затрудняет оценку срока службы оборудования. Модель разрушения распределения Вейбулла (разрушение подложки, наружного слоя, поверхости сцепления, мгновенное разрушение) построена на основании статистических данных о времени разрушения детелей в условиях эксплуатации. Использован метод разделения Каплана Мейера для анализа четырех множеств статистик разрушения, выполнено решение каждого состояния функции Вейбулла, что позволило установить механизм разрушения полиморфных смесей в условиях эксплуатации при множественной гетерогенности модифицированных деталей оборудования. На примере выполнения моделирования верифицированы достоверность и применимость модели. Создана теоретическая основа для разработки и изготовления порошка сплава и совершенствования технологии модифицирования. Разработан метод прогнозирования срока службы и оценки периода разрушения модифицированных деталей

Guiding and confining fast electrons by transient electric and magnetic fields with a plasma inverse cone

Copyright 2009 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Physics of Plasmas, 16(2), 020702, 2009 and may be found at http://dx.doi.org/10.1063/1.307592

A substitution-dependent light-up fluorescence probe for selectively detecting Fe3+ ions and its cell imaging application

Deliberate design of specific and sensitive molecular probes with distinctive physical/chemical properties for analyte sensing is of great significance. Herein, by taking advantage of the position-dependent substituent effects, an aggregation-induced emission featured iron (III) probe from ortho-substituted pyridinyl-functionalized tetraphenylethylene (TPE-o-Py) is synthesized. It displays high sensitivity and selectivity toward iron (III) detection. The recognition arises from the position isomer of ortho-substitution, and the fact that TPE-o-Py has a low acid dissociation constant (pKa) that is close to that of hydrolyzed Fe3+. Importantly, TPE-o-Py as a light-up fluorescence probe could be employed for Fe3+sensing in living cells with a pronounced red-shift in fluorescence emission

The role of SIRT6 protein in aging and reprogramming of human induced pluripotent stem cells

Aging is known to be the single most important risk factor for multiple diseases. Sirtuin 6, or SIRT6, has recently been identified as a critical regulator of transcription, genome stability, telomere integrity, DNA repair, and metabolic homeostasis. A knockout mouse model of SIRT6 has displayed dramatic phenotypes of accelerated aging. In keeping with its role in aging, we demonstrated that human dermal fibroblasts (HDFs) from older human subjects were more resistant to reprogramming by classic Yamanaka factors than those from younger human subjects, but the addition of SIRT6 during reprogramming improved such efficiency in older HDFs substantially. Despite the importance of SIRT6, little is known about the molecular mechanism of its regulation. We show, for the first, time posttranscriptional regulation of SIRT6 by miR-766 and inverse correlation in the expression of this microRNA in HDFs from different age groups. Our results suggest that SIRT6 regulates miR-766 transcription via a feedback regulatory loop, which has implications for the modulation of SIRT6 expression in reprogramming of aging cells

Charmless Bs→PP,PV,VVB_s\to PP, PV, VV Decays Based on the six-quark Effective Hamiltonian with Strong Phase Effects II

We provide a systematic study of charmless $B_s \to PP, PV, VV$ decays ($P$ and $V$ denote pseudoscalar and vector mesons, respectively) based on an approximate six-quark operator effective Hamiltonian from QCD. The calculation of the relevant hard-scattering kernels is carried out, the resulting transition form factors are consistent with the results of QCD sum rule calculations. By taking into account important classes of power corrections involving "chirally-enhanced" terms and the vertex corrections as well as weak annihilation contributions with non-trivial strong phase, we present predictions for the branching ratios and CP asymmetries of $B_s$ decays into PP, PV and VV final states, and also for the corresponding polarization observables in VV final states. It is found that the weak annihilation contributions with non-trivial strong phase have remarkable effects on the observables in the color-suppressed and penguin-dominated decay modes. In addition, we discuss the SU(3) flavor symmetry and show that the symmetry relations are generally respected

Optical properties of MgH2 measured in situ in a novel gas cell for ellipsometry/spectrophotometry

The dielectric properties of alpha-MgH2 are investigated in the photon energy range between 1 and 6.5 eV. For this purpose, a novel sample configuration and experimental setup are developed that allow both optical transmission and ellipsometric measurements of a transparent thin film in equilibrium with hydrogen. We show that alpha-MgH2 is a transparent, colour neutral insulator with a band gap of 5.6 +/- 0.1 eV. It has an intrinsic transparency of about 80% over the whole visible spectrum. The dielectric function found in this work confirms very recent band structure calculations using the GW approximation by Alford and Chou [J.A. Alford and M.Y. Chou (unpublished)]. As Pd is used as a cap layer we report also the optical properties of PdHx thin films.Comment: REVTeX4, 15 pages, 12 figures, 5 table

Inclusive Charmonium Production via Double ccˉc \bar c in e+e−e^+e^- Annihilation

Motivated by the recent observation of double charm quark pair production by the Belle Collaboration, we calculate the complete ${\cal O}(\alpha_{s}^{2})$ inclusive production cross sections for $\eta_{c}$, $J/\psi$, and $\chi_{cJ}$(J=0, 1, 2) plus $c\bar{c}$ in $e^+ e^-$ annihilation through a virtual photon. We consider both color-singlet and color-octet contributions, and give the analytical expressions for these cross sections. The complete color-singlet calculations are compared with the approximate fragmentation calculations as functions of the center-of-mass energy $\sqrt{s}$. We find that most of the fragmentation results substantially overestimate the cross sections (e.g. by a factor of $\sim$4 for $\chi_{c1}$ and $\chi_{c2}$) at the Belle and BaBar energy $\sqrt{s}=10.6$GeV. The fragmentation results become a good approximation only when $\sqrt{s}$ is higher than about 100GeV. We further calculate the color-octet contributions to these cross sections with analytical expressions. We find that while the color-octet contribution to $J/\psi$ inclusive production via double charm is negligible (only about 3%), the color-octet contributions to $\chi_{c1}$ and $\chi_{c2}$ can be significant.Comment: 23 pages, 9 figures; color-octet contributions to the double charm inclusive production of J/psi and chi_{cJ} (J=0,1,2) are added; references are added; No change for the color-singlet par