TEM observations of wear mechanisms of TiAlCrN and TiAlN/CrN coatings grown by combined steered-arc/unbalanced magnetron deposition

The dry sliding wear of monolayer TiAlCrN and TiAlCrYN and multilayer TiAlN/CrN coatings has been investigated against a BM2 tool steel counterface using a ring on block configuration at 91 N, 0.42 m/s. The coatings were deposited on a BM2 tool steel substrate by combined steered-arc/unbalanced-magnetron deposition. The wear rate of the multilayer was superior to the monolayer, although both provide a substantial improvement compared with the wear behaviour of the base BM2 tool steel (e.g., wear rate = 6.1 × 10-4 mm3/m for the BM2 tool steel; 3.98 × 10-5 mm3/m for the TiAlCrN monolayer and 2.58 × 10-5 mm3/m for the TiAlN/CrN multilayer). Wear of the coatings occurred by several mechanisms, fine scale (< 200 nm) detachment in the early stages and micron scale detachment associated with cracking in the coating in the later stages. Detailed transmission electron microscopy of cross-sections of the worn surface indicated that two dominant types of cracking were present within the coating: (1) cracking perpendicular to the coating surface, often along columnar grain boundaries, typically running through the entire coating; (2) cracking approximately parallel to the worn surface, extending across several columnar grains. For the multilayers, there was no evidence that the spalling was induced by decohesion along the interface of the multilayers. Limited surface deformation was detected at the worn surface of the TiAlCrYN and TiAlCrN, but not at the worn surface of the TiAlN/CrN, tested under identical conditions. In contrast, the uncoated BM2 tool steel worn surface exhibited extensive plastic deformation. The relationship between wear mechanism and coating structure is discussed. © 1999 Published by Elsevier Science S.A. All rights reserved

Lubricated sliding wear behaviour of aluminium alloy composites

Interest in aluminium alloy (Al-alloy) composites as wear resistant materials continues to grow. However, the use of the popular Al-alloy-SiC composite can be limited by the abrasive nature of the SiC, leading to increased counterface wear rates. This study reports new Al-alloy composites that offer high wear resistance, to a level similar to Al-alloy-SiC. Aluminium alloy (2124, 5056) matrix composites reinforced by nominally 15 vol.% of Cr3Si, MoSi2, Ni3Al and SiC particles were prepared by a powder metallurgy route. The aluminium alloy matrix was produced by gas atomisation, and the Cr3Si, MoSi2 and Ni3Al were prepared by self-propagating high temperature synthesis (SHS), while the SiC was from a standard commercial supply. Following blending, the particulates were consolidated by extrusion, producing a homogenous distribution of the reinforcement in the matrix. Wear testing was undertaken using a pin-on-ring configuration against an M2 steel counterface, with a commercial synthetic oil lubricant, at 0.94 m/s and a normal load of 630 N, corresponding to initial Hertzian contact pressures of 750–890 MPa (the exact value depending on the material properties). Specific wear rates at sliding distances exceeding 400 km were in the range 4.5–12.7 × 10?10 mm3/Nm. The monolithic alloys gave the highest specific wear rates, while the MoSi2 and Cr3Si reinforced alloys exhibited the lowest. The worn surface has been analysed in detail using focused ion beam (FIB) microscopy to determine the sub-surface structural evolution and by tomographic reconstruction of tilted scanning electron microscopy (SEM) images, to determine the local worn surface topography. Consequently, the wear mechanisms as a function of alloy composition and reinforcement type are discussed.<br/

Characterisation of L21-ordered Ni2TiAl precipitates in FeMn maraging steels

The precipitates formed in a new series of Fesingle bondMn maraging steels when aged at 500 °C were identified as the L21-ordered Ni2TiAl phase. The precipitate formed a coherent-coplanar microstructure analogously to γ/γ' Ni-based superalloys and maintained a high number density and homogeneous dispersion within α′-martensite matrix even after aging for 10,080 min. An increase in the Mn content of the alloy led to faster precipitation kinetics and thus rapid hardening kinetics

Microstructural evolution of Mn-based maraging steels and their influences on mechanical properties

The microstructural evolution in a set of Mn-based maraging steels (7–12 wt% Mn) when aged at 460–500 ºC for various durations up to 10,080 min and the influences on mechanical properties are systematically investigated. The improved yield strength of peak-aged samples is attributed to the formation of Ni2TiAl precipitates and the precipitation strengthening is governed by Orowan mechanism. Segregation of Mn at grain boundaries in the initial aging stage resulted in severe intergranular brittleness. During further aging, accumulated Mn segregation leading to the formation of ductile lath-like reverted austenite removed the embrittlement and significantly improved the ductility. In the overaged condition, the steady work hardening after yielding compensates the loss of yield strength resulting from the coarsening of precipitates and softening of α′-martensite matrix. There was only limited evidence of the TRIP effect in the reverted austenite, indicating that work hardening was associated with other deformation mechanisms. Increasing the aging temperature or the Mn content of alloy that promotes austenite reversion was demonstrated to accelerate the improvement of ductility

Investigating worn surfaces of nanoscale TiAlN/VN multilayer coating using FIB and TEM

TiAlN/VN multilayer coatings exhibit excellent dry sliding wear resistance and low friction coefficient, believed to be associated with the formation of tribo-films comprising Magnéli phases such as V2O5. In order to investigate this hypothesis, dry sliding wear of TiAlN/VN coatings was undertaken against Al2O3. Focused ion beam was used to generate site-specific TEM specimens. A thin (2-20nm) tribo-film was observed at the worn surface, with occasional 'roll-like' wear debris (φ 5-40nm). Both were amorphous and contained the same Ti, Al and V ratio as the coating, but with the nitrogen largely replaced by oxygen. No evidence of Magnéli phases was found. © 2006 IOP Publishing Ltd

Detailed in situ hot stage transmission electron microscope observations of the localized pinning of a mobile ferrite-austenite interface in a Fe-C-Mn alloy by a single oxidic particle

The current study reports the detailed analysis of an observation of the local pinning of a slowly moving austenite-ferrite interface by a single nanosized oxidic particle. The observations were made during an in situ cyclic partial phase transformation experiment on a Fe-0.1C-1.0Mn alloy close to the inversion stage at which the interface migrates at a rather low velocity. The low velocity allowed capturing the interface pinning effect over a period of no less than 16 seconds. From our observations, it was possible to follow the progression of the pinning effect from the initial stages all the way through to the release of the interface. The pinning force exerted by the individual particle having a diameter of 140 nm on the austenite-ferrite interface was estimated as 175 nJ m−1, while the maximum pinning length was approximately 750 nm to either side of the particle, leading to an interface line tension of 170 nJ m−1. The observed pinning behavior is compared with the most relevant models in the literature

ω phase strengthened 1.2GPa metastable β titanium alloy with high ductility

This paper provides a novel approach for exploiting ω phase strengthening in a metastable β titanium alloy while retaining high ductility. The addition of 1 wt% Fe into our previously designed Ti-7Mo-3Cr alloy can efficiently control the growth of ω phase following air-cooling, resulting in a ultrahigh yield strength (Rp0.2of 1210 MPa) with large ductility (εf of 0.15). Microstructural analysis of deformed alloys showed that the growth of ω phase in the air-cooled Ti-7Mo-3Cr-1Fe alloy modified the deformation mechanism from {332} twinning and dislocation slip, in the water-quenched alloy, to localized dislocation plasticity in ω-void channels

Microstructural evolution and wear mechanism of Ti3AlC2 – Ti2AlC dual MAX phase composite consolidated by spark plasma sintering (SPS)

In this work, we report the synthesis, deformation and tribological behaviour of a novel Ti3AlC2 – Ti2AlC MAX phase composite metallo-ceramic. The dual MAX phase composite was synthesized by spark plasma sintering (SPS) under a vacuum environment using Ti, Al, and C precursor powders. The deformation mechanism and the tribological behaviour were studied and analyzed by SEM, TEM, and Raman spectroscopy. The transition in friction and wear as well as the operative wear mechanisms involved were further discussed. Detailed analyses of the worn surface showed that Ti3AlC2 – Ti2AlC dual MAX phase composite is intrinsically self-lubricating

The formation mechanism of reverted austenite in Mn-based maraging steels

Based on the microstructural evolution in Mn-based maraging steels aged at 460–540 °C, the formation mechanism of reverted austenite is proposed. Reverted austenite formed at grain boundaries at the onset of aging. During further aging, the accumulated Mn enrichment at newly formed α′/γ interfaces led to thin austenite layers growing into lath-like austenite grains. The lateral growth of lath-like reverted austenite was sluggish, reflecting the low diffusivity of Mn. We show that reverted austenite formed by a shear-dominated mechanism assisted by a small amount of Mn diffusion, whereas the nucleation of reverted austenite within martensite laths was kinetically slower

Influence of protein adsorption on tribocorrosion behaviour of CoCrMo biomedical-grade alloys

CoCrMo alloys have been widely used in metal-on-metal hip replacements. They exhibit excellent long-term survival rates; however, recently, high failure rates associated with adverse local tissue reactions have been observed. CoCrMo alloys generally work extremely well; however, sometimes their wear rate is high. This work investigated protein adsorption effects on the tribocorrosion behaviour of CoCrMo biomedical-grade alloys under different surface and media conditions. The study of the wear mechanisms indicated that protein adsorption affects the corrosion and mechanical material loss of the investigated material. The synergistic and antagonistic behaviour of the material was correlated with the protein adsorption