150 research outputs found
Doping - dependent superconducting gap anisotropy in the two-dimensional 10-3-8 pnictide Ca(PtAs)[(FePt)As]
The characteristic features of
Ca(PtAs)[(FePt)As] ("10-3-8")
superconductor are relatively high anisotropy and a clear separation of
superconductivity and structural/magnetic transitions, which allows studying
the superconducting gap without complications due to the coexisting order
parameters. The London penetration depth, measured in underdoped single
crystals of 10-3-8 ( 0.028, 0.041, 0.042, and 0.097), shows behavior
remarkably similar to other Fe-based superconductors, exhibiting robust
power-law, . The exponent decreases from 2.36
( 0.097, close to optimal doping) to 1.7 ( 0.028, a heavily
underdoped composition), suggesting that the superconducting gap becomes more
anisotropic at the dome edge. A similar trend is found in low-anisotropy
superconductors based on BaFeAs ("122"), implying that it is an
intrinsic property of superconductivity in iron pnictides, unrelated to the
coexistence of magnetic order and superconductivity or the anisotropy of the
normal state. Overall this doping dependence is consistent with
pairing competing with intra-band repulsion
57-Fe Mossbauer study of magnetic ordering in superconducting K_0.85Fe_1.83Se_2.09 single crystals
The magnetic ordering of superconducting single crystals of
K_0.85Fe_1.83Se_2.09 has been studied between 10K and 550K using 57-Fe
Mossbauer spectroscopy. Despite being superconducting below T_sc ~30K, the iron
sublattice in K_0.85Fe_1.83Se_2.09 clearly exhibits magnetic order from well
below T_sc to its N\'eel temperature of T_N = 532 +/- 2K. The iron moments are
ordered perpendicular to the single crystal plates, i.e. parallel to the
crystal c-axis. The order collapses rapidly above 500K and the accompanying
growth of a paramagnetic component suggests that the magnetic transition may be
first order, which may explain the unusual temperature dependence reported in
recent neutron diffraction studies.Comment: 6 pages, 4 figures Submitted to Phys.Rev.
Remarkably robust and correlated coherence and antiferromagnetism in (CeLa)CuGe
We present magnetic susceptibility, resistivity, specific heat, and
thermoelectric power measurements on (CeLa)CuGe single
crystals (0 1). With La substitution, the antiferromagnetic
temperature is suppressed in an almost linear fashion and moves below
0.36 K, the base temperature of our measurements for 0.8. Surprisingly, in
addition to robust antiferromagnetism, the system also shows low temperature
coherent scattering below up to 0.9 of La, indicating a small
percolation limit 9 of Ce that separates a coherent regime from a
single-ion Kondo impurity regime. as a function of magnetic field was
found to have different behavior for 0.9. Remarkably,
at = 0 was found to be linearly proportional to . The
jump in the magnetic specific heat at as a function of
for (CeLa)CuGe follows the theoretical prediction
based on the molecular field calculation for the = 1/2 resonant level
model
Mounting Materials for Automated Image Analysis of Coals Using Backscattered Electron Imaging
In order to apply SEM-based automated image analysis (AIA) to the characterization of not only minerals in coal but to the coal itself, sample preparation methods need to be developed beyond common practice. A significant consideration is the degree of contrast achievable between the mount media chosen and the coal. Four low-atomic number materials (epoxy, polyethylene, polystyrene and carnauba wax) were compared for their potential as suitable mounting media for coal samples. Epoxy is satisfactory only for characterization of mineral particles since the contrast between epoxy and coal particles is negligible. Polyethylene or polystyrene have marginal application for use as mounting material for coal characterization due to limited contrast and sample preparation artifacts. Carnauba wax appears satisfactory as a mounting material since it provides good contrast with coal particles with minimal artifacts
Synthesis and Processing of powders and wires
Sintered powders and wires of superconducting have been fabricated
under a variety of conditions in order to determine details of the diffusion of
the into and to study the types of defects that arise during growth.
For samples prepared by exposure of boron to vapor at , the
conversion of particles of less than size particles to is
complete in about . The lattice parameters of the phase determined
from X-ray are independent of the starting stoichiometry and the time of
reaction. Wire segments of with very little porosity have been produced
by reacting diameter boron fibers in an atmosphere of excess
vapor at . Defects in the reacted fibers are predominantly the
voids left as the boron is converted to
Synthesis and characterization of Ca-doped LaMnAsO
We report on our attempt to hole-dope the antiferromagnetic semiconductor LaMnAsO by substitution of the La3+ site by Ca2+. We use neutron and x-ray diffraction, magnetic susceptibility, and transport techniques to characterize polycrystalline (La1−xCax)MnAsO samples prepared by solid-state reaction and find that the parent compound is highly resistant to substitution with an upper limit x≤0.01. Magnetic susceptibility of the parent and the x=0.002(xnom=0.04) compounds indicate a negligible presence of magnetic impurities (i.e., MnO or MnAs). Rietveld analysis of neutron and x-ray diffraction data shows the preservation of both the tetragonal (P4/nmm) structure upon doping and the antiferromagnetic ordering temperature, TN=355±5 K
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