Direct Emission of I_2 Molecule and IO Radical from the Heterogeneous Reactions of Gaseous Ozone with Aqueous Potassium Iodide Solution

Recent studies indicated that gaseous halogens mediate key tropospheric chemical processes. The inclusion of halogen-ozone chemistry in atmospheric box models actually closes the ~50% gap between estimated and measured ozone losses in the marine boundary layer. The additional source of gaseous halogens is deemed to involve previously unaccounted for reactions of O_3(g) with sea surface water and marine aerosols. Here, we report that molecular iodine, I_2(g), and iodine monoxide radical, IO(g), are released ([I_2(g)] > 100[IO(g)]) during the heterogeneous reaction of gaseous ozone, O_3(g), with aqueous potassium iodide, KI(aq). It was found that (1) the amounts of I_2(g) and IO(g) produced are directly proportional to [KI(aq)] up to 5 mM and (2) IO(g) yields are independent of bulk pH between 2 and 11, whereas I_2(g) production is markedly enhanced at pH < 4. We propose that O_3(g) reacts with I− at the air/water interface to produce I_2(g) and IO(g) via HOI and IOOO− intermediates, respectively

Spectroscopic Evidence for the Specific Na+ and K+ Interactions with the Hydrogen-bonded Water Molecules at the Electrolyte Aqueous Solution Surfaces

Sum frequency generation vibrational spectra of the water molecules at the NaF and KF aqueous solution surfaces showed significantly different spectral features and different concentration dependence. This result is the first direct observation of the cation effects of the simple alkali cations, which have been believed to be depleted from the aqueous surface, on the hydrogen bonding structure of the water molecules at the electrolyte solution surfaces. These observations may provide important clue to understand the fundamental phenomenon of ions at the air/water interface.Comment: 15 pages, 2 figure

Social Media Attention Increases Article Visits: An Investigation on Article-Level Referral Data of PeerJ

In order to better understand the effect of social media in the dissemination of scholarly articles, employing the daily updated referral data of 110 PeerJ articles collected over a period of 345 days, we analyze the relationship between social media attention and article visitors directed by social media. Our results show that social media presence of PeerJ articles is high. About 68.18% of the papers receive at least one tweet from Twitter accounts other than @PeerJ, the official account of the journal. Social media attention increases the dissemination of scholarly articles. Altmetrics could not only act as the complement of traditional citation measures but also play an important role in increasing the article downloads and promoting the impacts of scholarly articles. There also exists a significant correlation among the online attention from different social media platforms. Articles with more Facebook shares tend to get more tweets. The temporal trends show that social attention comes immediately following publication but does not last long, so do the social media directed article views

Utilising content marketing metrics and social networks for academic visibility

There are numerous assumptions on research evaluation in terms of quality and relevance of academic contributions. Researchers are becoming increasingly acquainted with bibliometric indicators, including; citation analysis, impact factor, h-index, webometrics and academic social networking sites. In this light, this chapter presents a review of these concepts as it considers relevant theoretical underpinnings that are related to the content marketing of scholars. Therefore, this contribution critically evaluates previous papers that revolve on the subject of academic reputation as it deliberates on the individual researchers’ personal branding. It also explains how metrics are currently being used to rank the academic standing of journals as well as higher educational institutions. In a nutshell, this chapter implies that the scholarly impact depends on a number of factors including accessibility of publications, peer review of academic work as well as social networking among scholars.peer-reviewe

MS-118: Letters Solicited by Jerold Wikoff for Gettysburg Alumni Magazine

This collection is comprised of letters written by Gettysburg College alumni to Mr. Jerold Wikoff concerning three distinct topics: World War II experiences, dinks, and alumni couple sweetheart stories. The alumni who contributed the letters that comprise this collection wrote in response to Mr. Wikoff‟s various requests within the Gettysburg alumni magazine. Special Collections and College Archives Finding Aids are discovery tools used to describe and provide access to our holdings. Finding aids include historical and biographical information about each collection in addition to inventories of their content. More information about our collections can be found on our website http://www.gettysburg.edu/special_collections/collections/.https://cupola.gettysburg.edu/findingaidsall/1107/thumbnail.jp