3,622 research outputs found
Influence of compressing pressure on macro void formation of carbon monolith for methane adsorption
Carbon monoliths for adsorbed natural gas (ANG) storage were prepared from Mongolian anthracite-based activated carbons using carboxy-methyl cellulose as a binder under different compressing pressures. Nitrogen adsorption/desorption experiments were carried out to obtain the specific surface area, pore volume, and pore size distribution of the monoliths. Methane adsorption experiments on the carbon monoliths were conducted at different temperatures and pressures up to around 3.5 MPa in a high pressure volumetric adsorption apparatus. As expected, adsorption results indicated that the methane adsorption capacity of the carbon monoliths increased with increasing specific surface area and packing density. The maximum volumetric adsorption of methane was observed as 163 V/V at 293 K and 3.5 MPa on a carbon monolith sample, PMAC1/2-3-65, that does not have the highest specific surface area but relatively high packing density comparing with other monoliths, which implies that two physical properties contribute contradictorily to the methane adsorption capacity. Based on experimental results, the carbon monoliths prepared from Mongolian anthracite-based activated carbons can be promising media for ANG storage application
Structured compressive sensing-based spatio-temporal joint channel estimation for FDD massive MIMO
Massive MIMO is a promising technique for future 5G communications due to its high spectrum and energy efficiency. To realize its potential performance gain, accurate channel estimation is essential. However, due to massive number of antennas at the base station (BS), the pilot overhead required by conventional channel estimation schemes will be unaffordable, especially for frequency division duplex (FDD) massive MIMO. To overcome this problem, we propose a structured compressive sensing (SCS)-based spatio-temporal joint channel estimation scheme to reduce the required pilot overhead, whereby the spatio-temporal common sparsity of delay-domain MIMO channels is leveraged. Particularly, we first propose the nonorthogonal pilots at the BS under the framework of CS theory to reduce the required pilot overhead. Then, an adaptive structured subspace pursuit (ASSP) algorithm at the user is proposed to jointly estimate channels associated with multiple OFDM symbols from the limited number of pilots, whereby the spatio-temporal common sparsity of MIMO channels is exploited to improve the channel estimation accuracy. Moreover, by exploiting the temporal channel correlation, we propose a space-time adaptive pilot scheme to further reduce the pilot overhead. Additionally, we discuss the proposed channel estimation scheme in multicell scenario. Simulation results demonstrate that the proposed scheme can accurately estimate channels with the reduced pilot overhead, and it is capable of approaching the optimal oracle least squares estimator
Retraction notice: Influence of compressing pressure on macro void formation carbon monolith for methane adsorption
RETRACTION NOTICEOn 21rd February 2019, the Editorial Board of the Mongolian Journal of Chemistry decided to retract this article entitled "Influence of compressing pressure on macro void formation of carbon monolith for methane adsorption" because of an authorship dispute. The article was originally published in Vol.18 No.44 2017 pp.24-35. doi: https://doi.org/10.5564/mjc.v18i44.93
Electronic structure of YbB: Is it a Topological Insulator or not?
To resolve the controversial issue of the topological nature of the
electronic structure of YbB, we have made a combined study using density
functional theory (DFT) and angle resolved photoemission spectroscopy (ARPES).
Accurate determination of the low energy band topology in DFT requires the use
of modified Becke-Johnson exchange potential incorporating the spin-orbit
coupling and the on-site Coulomb interaction of Yb electrons as large
as 7 eV. We have double-checked the DFT result with the more precise GW band
calculation. ARPES is done with the non-polar (110) surface termination to
avoid band bending and quantum well confinement that have confused ARPES
spectra taken on the polar (001) surface termination. Thereby we show
definitively that YbB has a topologically trivial B 2-Yb 5
semiconductor band gap, and hence is a non-Kondo non-topological insulator
(TI). In agreement with theory, ARPES shows pure divalency for Yb and a -
band gap of 0.3 eV, which clearly rules out both of the previous scenarios of
- band inversion Kondo TI and - band inversion non-Kondo TI. We
have also examined the pressure-dependent electronic structure of YbB,
and found that the high pressure phase is not a Kondo TI but a
\emph{p}-\emph{d} overlap semimetal.Comment: The main text is 6 pages with 4 figures, and the supplementary
information contains 6 figures. 11 pages, 10 figures in total To be appeared
in Phys. Rev. Lett. (Online publication is around March 16 if no delays.
Electronic structures of ZnCoO using photoemission and x-ray absorption spectroscopy
Electronic structures of ZnCoO have been investigated using
photoemission spectroscopy (PES) and x-ray absorption spectroscopy (XAS). The
Co 3d states are found to lie near the top of the O valence band, with a
peak around eV binding energy. The Co XAS spectrum provides
evidence that the Co ions in ZnCoO are in the divalent Co
() states under the tetrahedral symmetry. Our finding indicates that the
properly substituted Co ions for Zn sites will not produce the diluted
ferromagnetic semiconductor property.Comment: 3 pages, 2 figure
AMOD: a morpholino oligonucleotide selection tool
AMOD is a web-based program that aids in the functional evaluation of nucleotide sequences through sequence characterization and antisense morpholino oligonucleotide (target site) selection. Submitted sequences are analyzed by translation initiation site prediction algorithms and sequence-to-sequence comparisons; results are used to characterize sequence features required for morpholino design. Within a defined subsequence, base composition and homodimerization values are computed for all putative morpholino oligonucleotides. Using these properties, morpholino candidates are selected and compared with genomic and transcriptome databases with the goal to identify target-specific enriched morpholinos. AMOD has been used at the University of Minnesota to design ∼200 morpholinos for a functional genomics screen in zebrafish. The AMOD web server and a tutorial are freely available to both academic and commercial users at
Nonlinear software sensor for monitoring genetic regulation processes with noise and modeling errors
Nonlinear control techniques by means of a software sensor that are commonly
used in chemical engineering could be also applied to genetic regulation
processes. We provide here a realistic formulation of this procedure by
introducing an additive white Gaussian noise, which is usually found in
experimental data. Besides, we include model errors, meaning that we assume we
do not know the nonlinear regulation function of the process. In order to
illustrate this procedure, we employ the Goodwin dynamics of the concentrations
[B.C. Goodwin, Temporal Oscillations in Cells, (Academic Press, New York,
1963)] in the simple form recently applied to single gene systems and some
operon cases [H. De Jong, J. Comp. Biol. 9, 67 (2002)], which involves the
dynamics of the mRNA, given protein, and metabolite concentrations. Further, we
present results for a three gene case in co-regulated sets of transcription
units as they occur in prokaryotes. However, instead of considering their full
dynamics, we use only the data of the metabolites and a designed software
sensor. We also show, more generally, that it is possible to rebuild the
complete set of nonmeasured concentrations despite the uncertainties in the
regulation function or, even more, in the case of not knowing the mRNA
dynamics. In addition, the rebuilding of concentrations is not affected by the
perturbation due to the additive white Gaussian noise and also we managed to
filter the noisy output of the biological systemComment: 21 pages, 7 figures; also selected in vjbio of August 2005; this
version corrects a misorder in the last three references of the published
versio
Superconductivity Near Ferromagnetism in MgCNi3
An unusual quasi-two-dimensional heavy band mass van Hove singularity (vHs)
lies very near the Fermi energy in MgCNi3, recently reported to superconduct at
8.5 K. This compound is strongly exchange enhanced and is unstable to
ferromagnetism upon hole doping with 12% Mg --> Na or Li. The 1/4-depleted fcc
(frustrated) Ni sublattice and lack of Fermi surface nesting argues against
competing antiferromagnetic and charge density wave instabilities. We identify
an essentially infinite mass along the M-Gamma line, leading to
quasi-two-dimensionality of this vHs may promote unconventional p-wave pairing
that could coexist with superconductivity.Comment: 4 two-column pages, 4 figure
- …