29,134 research outputs found
Theoretical description of a DNA-linked nanoparticle self-assembly
Nanoparticles tethered with DNA strands are promising building blocks for
bottom-up nanotechnology, and a theoretical understanding is important for
future development. Here we build on approaches developed in polymer physics to
provide theoretical descriptions for the equilibrium clustering and dynamics,
as well as the self-assembly kinetics of DNA-linked nanoparticles. Striking
agreement is observed between the theory and molecular modeling of DNA tethered
nanoparticles.Comment: Accepted for publication in Physical Review Letter
Polyvinyl alcohol cross-linked with two aldehydes
A film forming polyvinyl alcohol resin is admixed, in aqueous solution, with a dialdehyde crosslinking agent which is capable of crosslinking the polyvinyl alcohol resin and a water soluble acid aldehyde containing a reactive aldehyde group capable of reacting with hydroxyl groups in the polyvinyl alcohol resin and an ionizable acid hydrogen atom. The dialdehyde is present in an amount sufficient to react with from 1 to 20% by weight of the theoretical amount required to react with all of the hydroxyl groups of the polyvinyl alcohol. The amount of acid aldehyde is from 1 to 50% by weight, same basis, and is sufficient to reduce the pH of the aqueous admixture to 5 or less. The admixture is then formed into a desired physical shape, such as by casting a sheet or film, and the shaped material is then heated to simultaneously dry and crosslink the article
Baryon resonances and hadronic interactions in a finite volume
In a finite volume, resonances and multi-hadron states are identified by
discrete energy levels. When comparing the results of lattice QCD calculations
to scattering experiments, it is important to have a way of associating the
energy spectrum of the finite-volume lattice with the asymptotic behaviour of
the S-matrix. A new technique for comparing energy eigenvalues with scattering
phase shifts is introduced, which involves the construction of an exactly
solvable matrix Hamiltonian model. The model framework is applied to the case
of decay, but is easily generalized to include
multi-channel scattering. Extracting resonance parameters involves matching the
energy spectrum of the model to that of a lattice QCD calculation. The
resulting fit parameters are then used to generate phase shifts. Using a sample
set of pseudodata, it is found that the extraction of the resonance position is
stable with respect to volume for a variety of regularization schemes, and
compares favorably with the well-known Luescher method. The model-dependence of
the result is briefly investigated.Comment: 7 pages, 3 figures. Talk presented at the 30th International
Symposium on Lattice Field Theory (Lattice 2012), June 24-29, 2012, Cairns,
Australi
Sagnac Interferometer Enhanced Particle Tracking in Optical Tweezers
A setup is proposed to enhance tracking of very small particles, by using
optical tweezers embedded within a Sagnac interferometer. The achievable
signal-to-noise ratio is shown to be enhanced over that for a standard optical
tweezers setup. The enhancement factor increases asymptotically as the
interferometer visibility approaches 100%, but is capped at a maximum given by
the ratio of the trapping field intensity to the detector saturation threshold.
For an achievable visibility of 99%, the signal-to-noise ratio is enhanced by a
factor of 200, and the minimum trackable particle size is 2.4 times smaller
than without the interferometer
Unitarity and the Hilbert space of quantum gravity
Under the premises that physics is unitary and black hole evaporation is
complete (no remnants, no topology change), there must exist a one-to-one
correspondence between states on future null and timelike infinity and on any
earlier spacelike Cauchy surface (e.g., slices preceding the formation of the
hole). We show that these requirements exclude a large set of semiclassical
spacetime configurations from the Hilbert space of quantum gravity. In
particular, the highest entropy configurations, which account for almost all of
the volume of semiclassical phase space, would not have quantum counterparts,
i.e. would not correspond to allowed states in a quantum theory of gravity.Comment: 7 pages, 3 figures, revtex; minor changes in v2 (version published in
Class. Quant. Grav.
STEPS - an approach for human mobility modeling
In this paper we introduce Spatio-TEmporal Parametric Stepping (STEPS) - a simple parametric mobility model which can cover a large spectrum of human mobility patterns. STEPS makes abstraction of spatio-temporal preferences in human mobility by using a power law to rule the nodes movement. Nodes in STEPS have preferential attachment to favorite locations where they spend most of their time. Via simulations, we show that STEPS is able, not only to express the peer to peer properties such as inter-ontact/contact time and to reflect accurately realistic routing performance, but also to express the structural properties of the underlying interaction graph such as small-world phenomenon. Moreover, STEPS is easy to implement, exible to configure and also theoretically tractable
Thermoelasticity of Fe2+-bearing bridgmanite
We present LDA+U calculations of high temperature elastic properties of
bridgmanite with composition (MgFe)SiO for
. Results of elastic moduli and acoustic velocities for the
Mg-end member (x=0) agree very well with the latest high pressure and high
temperature experimental measurements. In the iron-bearing system, we focus
particularly on the change in thermoelastic parameters across the state change
that occurs in ferrous iron above 30 GPa, often attributed to a high-spin
(HS) to intermediate spin (IS) crossover but explained by first principles
calculations as a lateral displacement of substitutional iron in the perovskite
cage. We show that the measured effect of this change on the equation of state
of this system can be explained by the lateral displacement of substitutional
iron, not by the HS to IS crossover. The calculated elastic properties of
(MgFe)SiO along an adiabatic mantle geotherm,
somewhat overestimate longitudinal velocities but produce densities and shear
velocities quite consistent with Preliminary Reference Earth Model data
throughout most of the lower mantle.Comment: Accepted for Geophysical Research Letters (DOI: 10.1002/2014GL062888
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