Solid State NMR Characterization of Complex Metal Hydrides systems for Hydrogen Storage Applications

Solid state NMR is widely applied in studies of solid state chemistries for hydrogen storage reactions. Use of ^(11)B MAS NMR in studies of metal borohydrides (BH_4) is mainly focused, revisiting the issue of dodecaborane formation and observation of ^(11)B{^1H} Nuclear Overhauser Effect

Classical stability of U(1)_A domain walls in dense matter QCD

It was recently shown that there exists metastable U(1)_A domain wall configurations in high-density QCD (\mu >> 1 GeV). In the following we will assess the stability of such non-trivial field configurations at intermediate densities (\mu < 1 GeV). The existence of such configurations at intermediate densities could have interesting consequences for the physics of neutron stars with high core density.Comment: 13 pages, 2 Postscript figures, typos correcte

Electroweak phase transition in a nonminimal supersymmetric model

The Higgs potential of the minimal nonminimal supersymmetric standard model (MNMSSM) is investigated within the context of electroweak phase transition. We investigate the allowed parameter space yielding correct electroweak phase transitoin employing a high temperature approximation. We devote to phenomenological consequences for the Higgs sector of the MNMSSM for electron-positron colliders. It is observed that a future $e^+ e^-$ linear collider with $\sqrt{s} = 1000$ GeV will be able to test the model with regard to electroweak baryogenesis.Comment: 28 pages, 5 tables, 12 figure

Spin injection across magnetic/non-magnetic interfaces with finite magnetic layers

We have reconsidered the problem of spin injection across ferromagnet/non-magnetic-semiconductor (FM/NMS) and dilute-magnetic-semiconductor/non-magnetic-semiconductor interfaces, for structures with \textit{finite} magnetic layers (FM or DMS). By using appropriate physical boundary conditions, we find expressions for the resistances of these structures which are in general different from previous results in the literature. When the magnetoresistance of the contacts is negligible, we find that the spin-accumulation effect alone cannot account for the $d$ dependence observed in recent magnetoresistance data. In a limited parameter range, our formulas predict a strong $d$ dependence arising from the magnetic contacts in systems where their magnetoresistances are sizable.Comment: 6 pages, 3 eps figs. (extended version- new title + two new figures added

Asymptotic deconfinement in high-density QCD

We discuss QCD with two light flavors at large baryon chemical potential mu. Color superconductivity leads to partial breaking of the color SU(3) group. We show that the infrared physics is governed by the gluodynamics of the remaining SU(2) group with an exponentially soft confinement scale Lambda_QCD' Delta*exp[-a*mu/(g*Delta)], where Delta<<mu is the superconducting gap, g is the strong coupling, and a=0.81... We estimate that at moderate baryon densities Lambda_QCD' is O(10 MeV) or smaller. The confinement radius increases exponentially with density, leading to "asymptotic deconfinement." The velocity of the SU(2) gluons is small due to the large dielectric constant of the medium.Comment: 4 pages; restructured, published versio

Hydrogenation of Magnesium Nickel Boride for Reversible Hydrogen Storage

We report that a ternary magnesium nickel boride (MgNi_(2.5)B_2) mixed with LiH and MgH_2 can be hydrogenated reversibly forming LiBH_4 and Mg_2NiH_4 at temperatures below 300 °C. The ternary boride was prepared by sintering a mechanically milled mixture of MgB_2 and Ni precursors at 975 °C under inert atmosphere. Hydrogenation of the ternary, milled with LiH and MgH_2, was performed under 100 to 160 bar H_2 at temperatures up to 350 °C. Analysis using X-ray diffraction, Fourier transform infrared, and ^(11)B magic angle spinning NMR confirmed that the ternary boride was hydrogenated forming borohydride anions. The reaction was reversible with hydrogenation kinetics that improved over three cycles. This work suggests that there may be other ternary or higher order boride phases useful for reversible hydrogen storage

Domain walls of high-density QCD

We show that in very dense quark matter there must exist metastable domain walls where the axial U(1) phase of the color-superconducting condensate changes by 2pi. The decay rate of the domain walls is exponentially suppressed and we compute it semiclassically. We give an estimate of the critical chemical potential above which our analysis is under theoretical control.Comment: 4 pages; Eq. (16) corrected, 2 new references added, published versio

Real-time pion propagation in finite-temperature QCD

We argue that in QCD near the chiral limit, at all temperatures below the chiral phase transition, the dispersion relation of soft pions can be expressed entirely in terms of three temperature-dependent quantities: the pion screening mass, a pion decay constant, and the axial isospin susceptibility. The definitions of these quantities are given in terms of equal-time (static) correlation functions. Thus, all three quantities can be determined directly by lattice methods. The precise meaning of the Gell-Mann--Oakes--Renner relation at finite temperature is given.Comment: 25 pages, 2 figures; v2: discussion on the region of applicability expanded, to be published in PR