Assessing Intra-Event Phosphorus Dynamics in Drainage Water Using Phosphate Stable Oxygen Isotopes

Quantifying fluxes and pathways of dissolved reactive phosphorus (DRP) in tile-drained landscapes has been hampered by a lack of measurements that are sensitive to P fate and transport processes. One potential tool to help understand these dynamics is the oxygen isotope signature of phosphate (δ18OPO4); however, its potential benefits and limitations are not well understood for intra-event dynamics at the field scale. The objectives of this study were to quantify intra-event variability of δ18OPO4 signatures in tile drainage water and assess the efficacy of δ18OPO4 to elucidate mechanisms and flow pathways controlling DRP transport to tile drains. We collected water samples during a summer storm event from a subsurface (tile)-drained field located in west-central Ohio and analyzed for δ18OPO4 of DRP. Supplementary water quality measurements, hydrologic modeling, and soil temperature data were used to help understand intra-event δ18OPO4 dynamics. Results of the soil extraction analysis from our study site highlight that the soil water-extractable P (WEP) pool was not in equilibrium with long-term, temperature-dependent water isotope values. This result suggests that P-rich soils may, at least partially, retain their original source signature, which has significant implications for identifying hotspots of P delivery in watershed-scale applications. Results of the storm event analysis highlight that equilibration of leached DRP in soil water creates a gradient between isotopic compositions of pre-event shallow subsurface sources, pre-event deep subsurface sources, and the WEP tied up in surface soils. The current study represents the first intra-event analysis of δ18OPO4 and highlights the potential for phosphate oxygen isotopes as a novel tool to improve understanding of P fate and transport in artificially drained agroecosystems

Interfacial Reactions of Ozone with Surfactant Protein B in a Model Lung Surfactant System

Oxidative stresses from irritants such as hydrogen peroxide and ozone (O_3) can cause dysfunction of the pulmonary surfactant (PS) layer in the human lung, resulting in chronic diseases of the respiratory tract. For identification of structural changes of pulmonary surfactant protein B (SP-B) due to the heterogeneous reaction with O_3, field-induced droplet ionization (FIDI) mass spectrometry has been utilized. FIDI is a soft ionization method in which ions are extracted from the surface of microliter-volume droplets. We report structurally specific oxidative changes of SP-B_(1−25) (a shortened version of human SP-B) at the air−liquid interface. We also present studies of the interfacial oxidation of SP-B_(1−25) in a nonionizable 1-palmitoyl-2-oleoyl-sn-glycerol (POG) surfactant layer as a model PS system, where competitive oxidation of the two components is observed. Our results indicate that the heterogeneous reaction of SP-B_(1−25) at the interface is quite different from that in the solution phase. In comparison with the nearly complete homogeneous oxidation of SP-B_(1−25), only a subset of the amino acids known to react with ozone are oxidized by direct ozonolysis in the hydrophobic interfacial environment, both with and without the lipid surfactant layer. Combining these experimental observations with the results of molecular dynamics simulations provides an improved understanding of the interfacial structure and chemistry of a model lung surfactant system subjected to oxidative stress

Transformation of Morphology and Luminosity Classes of the SDSS Galaxies

We present a unified picture on the evolution of galaxy luminosity and morphology. Galaxy morphology is found to depend critically on the local environment set up by the nearest neighbor galaxy in addition to luminosity and the large scale density. When a galaxy is located farther than the virial radius from its closest neighbor, the probability for the galaxy to have an early morphological type is an increasing function only of luminosity and the local density due to the nearest neighbor ($\rho_n$). The tide produced by the nearest neighbor is thought to be responsible for the morphology transformation toward the early type at these separations. When the separation is less than the virial radius, i.e. when $\rho_n > \rho_{\rm virial}$, its morphology depends also on the neighbor's morphology and the large-scale background density over a few Mpc scales ($\rho_{20}$) in addition to luminosity and $\rho_n$. The early type probability keeps increasing as $\rho_n$ increases if its neighbor is an early type. But the probability decreases as $\rho_n$ increases when the neighbor is a late type. The cold gas streaming from the late type neighbor can be the reason for the morphology transformation toward late type. The overall early-type fraction increases as $\rho_{20}$ increases when $\rho_n > \rho_{\rm virial}$. This can be attributed to the hot halo gas of the neighbor which is confined by the pressure of the ambient medium held by the background mass. We have also found that galaxy luminosity depends on $\rho_n$, and that the isolated bright galaxies are more likely to be recent merger products. We propose a scenario that a series of morphology and luminosity transformation occur through distant interactions and mergers, which results in the morphology--luminosity--local density relation.Comment: 14 pages, 7 figures, for higher resolution figures download PDF file at http://astro.kias.re.kr/docs/trans.pdf ; references added and typos in section 3.2 corrected; Final version accepted for publication in Ap

Absorbent particles, especially catamenials, having improved fluid directionality, comfort and fit

Absorbent articles, especially sanitary napkins, contain fibers with intra-fiber capillary channels. In-use, the capillary channel fibers direct menses to a storage layer, thereby minimizing product failure and staining of undergarments. The capillary channel fibers can protrude into, or through, a topsheet to provide very aggressive transport of vaginal discharges

Equation of state of warm condensed matter

Recent advances in computational condensed matter theory have yielded accurate calculations of properties of materials. These calculations have, for the most part, focused on the low temperature (T=0) limit. An accurate determination of the equation of state (EOS) at finite temperature also requires knowledge of the behavior of the electron and ion thermal pressure as a function of T. Current approaches often interpolate between calculated T=0 results and approximations valid in the high T limit. Plasma physics-based approaches are accurate in the high temperature limit, but lose accuracy below T{approximately}T{sub Fermi}. We seek to ``connect up`` these two regimes by using ab initio finite temperature methods (including linear-response[1] based phonon calculations) to derive an equation of state of condensed matter for T{100 GPa and temperatures T>10{sup 4}K, and compare our results with available experimental data

Nuclear Magnetic Resonance and Hyperfine Structure

Contains reports on three research projects

Absorbent articles, especially catamenials, having improved fluid directionality

The present invention provides absorbent articles, especially sanitary napkins, containing a fluid transport layer. In-use, the transport layer directs menses to a storage layer, thereby minimizing product failure and staining of undergarments. The transport layer can protrude into, or through, a topsheet to provide very aggressive transport of vaginal discharges. Preferably, the transport layer is a layer of fibers having external capillary channels

Optical and Infrared Spectroscopy

Contains research objectives and reports on one research project

Topology of structure in the Sloan Digital Sky Survey: model testing

We measure the three-dimensional topology of large-scale structure in the Sloan Digital Sky Survey (SDSS). This allows the genus statistic to be measured with unprecedented statistical accuracy. The sample size is now sufficiently large to allow the topology to be an important tool for testing galaxy formation models. For comparison, we make mock SDSS samples using several state-of-the-art N-body simulations: the Millennium run of Springel et al. (2005)(10 billion particles), Kim & Park (2006) CDM models (1.1 billion particles), and Cen & Ostriker (2006) hydrodynamic code models (8.6 billion cell hydro mesh). Each of these simulations uses a different method for modeling galaxy formation. The SDSS data show a genus curve that is broadly characteristic of that produced by Gaussian random phase initial conditions. Thus the data strongly support the standard model of inflation where Gaussian random phase initial conditions are produced by random quantum fluctuations in the early universe. But on top of this general shape there are measurable differences produced by non-linear gravitational effects (cf. Matsubara 1994), and biasing connected with galaxy formation. The N-body simulations have been tuned to reproduce the power spectrum and multiplicity function but not topology, so topology is an acid test for these models. The data show a ``meatball'' shift (only partly due to the Sloan Great Wall of Galaxies; this shift also appears in a sub-sample not containing the Wall) which differs at the 2.5\sigma level from the results of the Millennium run and the Kim & Park dark halo models, even including the effects of cosmic variance.Comment: 13 Apj pages, 7 figures High-resolution stereo graphic available at http://www.astro.princeton.edu/~dclayh/stereo50.ep