2,831 research outputs found
Thermal stability and grain growth behavior of mechanically alloyed nanocrystalline Fe-Cu alloys
X-ray diffraction, transmission electron microscopy, and differential scanning calorimetry were used to study the thermal stability of highly supersaturated nanocrystalline FexCu100−x alloys (10~80. For 60<=x<=80 fcc and bcc phases coexist. Heating to elevated temperatures leads to structural relaxation, phase separation, and grain growth of the metastable nanocrystalline solid solutions. Single-phase fcc and bcc alloys undergo significant strain release but no appreciable grain growth prior to phase separation. After phase separation pronounced grain growth sets in. In contrast, samples in the two-phase region show some grain growth and significant chemical redistribution even at low temperatures. The phase separation of single-phase fcc and bcc alloys proceeds via different mechanisms: fcc solid solutions decompose by forming small Fe precipitates, while demixing in bcc alloys starts by segregation of Cu atoms to bcc grain boundaries before nucleation of Cu precipitates. These results show that the stability and grain growth behavior of nanocrystalline alloys is strongly affected by the microstructure of the material
Gibbs free energy difference between the undercooled liquid and the beta-phase of a Ti-Cr alloy
The heat of fusion and the specific heats of the solid and liquid have been experimentally determined for a Ti60Cr40 alloy. The data are used to evaluate the Gibbs free energy difference, DELTA-G, between the liquid and the beta-phase as a function of temperature to verify a reported spontaneous vitrification (SV) of the beta-phase in Ti-Cr alloys. The results show that SV of an undistorted beta-phase in the Ti60Cr40 alloy at 873 K is not feasible because DELTA-G is positive at the temperature. However, DELTA-G may become negative with additional excess free energy to the beta-phase in the form of defects
Gibbs free-energy difference between the glass and crystalline phases of a Ni-Zr alloy
The heats of eutectic melting and devitrification, and the specific heats of the crystalline, glass, and liquid phases have been measured for a Ni24Zr76 alloy. The data are used to calculate the Gibbs free-energy difference, DeltaGAC, between the real glass and the crystal on an assumption that the liquid-glass transition is second order. The result shows that DeltaGAC continuously increases as the temperature decreases in contrast to the ideal glass case where DeltaGAC is assumed to be independent of temperature
Mechanically driven alloying and grain size changes in nanocrystalline Fe-Cu powders
Highly supersaturated nanocrystalline FexCu100-x alloys (10 less-than-or-equal-to x less-than-or-equal-to 95) have been prepared by mechanical alloying of elemental crystalline powders. The development of the microstructure is investigated by x-ray diffraction, differential scanning calorimetry, and transmission electron microscopy. The results are compared with data for ball-milled elemental Fe and Cu powders, samples prepared by inert gas condensation, and sputtered films. The deformation during milling reduces the grain size of the alloys to 6-20 nm. The final grain size of the powders depends on the composition of the material. Single-phase fcc alloys with x less-than-or-equal-to 60 and single-phase bcc alloys with x greater-than-or-equal-to 80 are formed even though the Fe-Cu system exhibits vanishingly small solid solubilities under equilibrium conditions. For 60 less-than-or-equal-to x less-than-or-equal-to 80, fcc and bcc solid solutions coexist. The alloy formation is discussed with respect to the thermodynamic conditions of the material. The role of the large volume fraction of grain boundaries between the nanometer-sized crystals, as well as the influence of internal strains and stored enthalpies introduced by ball milling, is critically assessed
Green's Relations in Finite Transformation Semigroups
We consider the complexity of Green's relations when the semigroup is given
by transformations on a finite set. Green's relations can be defined by
reachability in the (right/left/two-sided) Cayley graph. The equivalence
classes then correspond to the strongly connected components. It is not
difficult to show that, in the worst case, the number of equivalence classes is
in the same order of magnitude as the number of elements. Another important
parameter is the maximal length of a chain of components. Our main contribution
is an exponential lower bound for this parameter. There is a simple
construction for an arbitrary set of generators. However, the proof for
constant alphabet is rather involved. Our results also apply to automata and
their syntactic semigroups.Comment: Full version of a paper submitted to CSR 2017 on 2016-12-1
Measurements of heavy ion beam losses from collimation
The collimation efficiency for Pb ion beams in the LHC is predicted to be
lower than requirements. Nuclear fragmentation and electromagnetic dissociation
in the primary collimators create fragments with a wide range of Z/A ratios,
which are not intercepted by the secondary collimators but lost where the
dispersion has grown sufficiently large. In this article we present
measurements and simulations of loss patterns generated by a prototype LHC
collimator in the CERN SPS. Measurements were performed at two different
energies and angles of the collimator. We also compare with proton loss maps
and find a qualitative difference between Pb ions and protons, with the maximum
loss rate observed at different places in the ring. This behavior was predicted
by simulations and provides a valuable benchmark of our understanding of ion
beam losses caused by collimation.Comment: 12 pages, 20 figure
Direct measurement of shear-induced cross-correlations of Brownian motion
Shear-induced cross-correlations of particle fluctuations perpendicular and
along stream-lines are investigated experimentally and theoretically. Direct
measurements of the Brownian motion of micron-sized beads, held by optical
tweezers in a shear-flow cell, show a strong time-asymmetry in the
cross-correlation, which is caused by the non-normal amplification of
fluctuations. Complementary measurements on the single particle probability
distribution substantiate this behavior and both results are consistent with a
Langevin model. In addition, a shear-induced anti-correlation between
orthogonal random-displacements of two trapped and hydrodynamically interacting
particles is detected, having one or two extrema in time, depending on the
positions of the particles.Comment: 4 pages, 4 figure
Investigations on the individual and maternal components of calving performance in cattle
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