Titanium-Oxygen Reactivity Study

A program has been conducted at Astronautics to investigate the likelihood of occurrence of the catastrophic oxidation of titanium alloy sheet under conditions which simulate certain cases of accidental failure of the metal while it is in contact with liquid or gaseous oxygen. Three methods of fracturing the metal were used; they consisted of mechanical puncture, tensile fracture of welded joints, and perforation by very high velocity particles. The results of the tests which have been conducted provide further evidence of the reactivity of titanium with liquid and gaseous oxygen. The evidence indicates that the rapid fracturing of titanium sheet while it is in contact with oxygen initiates the catastrophic oxidation reaction. Initiation occurred when the speed of the fracture was some few feet per second, as in both the drop-weight puncture tests and the static tensile fracture tests of welded joints, as well as when the speed was several thousand feet per second, as in the simulated micrometeoroid penetration tests. The slow propagation of a crack, however, did not initiate the reaction. It may logically be concluded that the localized frictional heat of rapid fracture and/or spontaneous oxidation (exothermic) of minute particles emanating from the fracture cause initiation of the reaction. Under conditions of slow fracture, however, the small heat generated may be adequately dissipated and the reaction is not initiated. A portion of the study conducted consisted of investigating various means by which the reaction might be retarded or prevented. Providing a "barrier" at the titanium-oxygen interface consisting of either aluminum metal or a coating of a petroleum base corrosion inhibitor appeared to be only partially effective in retarding the reaction. The accidental puncturing or similar rupturing of thin-walled pressurized oxygen tanks on missiles and space vehicle will usually constitute loss of function, and may sometimes cause their catastrophic destruction by explosive decompression regardless of the type of material used for their construction. In the case of tanks constructed of titanium alloys the added risk is incurred of catastrophic burning of the tanks. In view of this it is recommended that thin-walled tanks constructed of titanium alloys should not be used to contain liquid or gaseous oxygen

Connector - Electrical

Distribution of currents to circuits using electrical adapto

The Helios mechanical despin drive assembly for the high-gain antenna reflector

Helios is the German-American solar probe which comes within 0.31 Astronomical Units of the sun. A special thermal design and a dry lubrication system have resulted in successful operation up to now, with Helios having finished its first orbit around the sun

Rapid method for determining nitrogen in tantalum and niobium alloys

Adaptation of commercial instrument which measures nitrogen and oxygen in steel gave results in less than four minutes. Sample is heated in helium atmosphere in single-use graphite crucible. Platinum flux facilitates melting of sample. Released gases are separated chromatographically and measured in thermal-conductivity cell

Missile stage separation indicator and stage initiator Patent

Piezoelectric means for missile stage separation indication and stage initiatio

Adaptive guidance and control for future remote sensing systems

A unique approach to onboard processing was developed that is capable of acquiring high quality image data for users in near real time. The approach is divided into two steps: the development of an onboard cloud detection system; and the development of a landmark tracker. The results of these two developments are outlined and the requirements of an operational guidance and control system capable of providing continuous estimation of the sensor boresight position are summarized

Corrosion reduction of aluminum alloys in flowing high-temperature water

Report describes a technique for reducing the corrosion rate of aluminum by adding colloidal substances in a closed-loop system. Experimental work shows that the addition of graphite and colloidal hydrated aluminum oxide significantly reduces the corrosion rate in flowing high-temperature water

Novel convolution-based signal processing techniques for an artificial olfactory mucosa

As our understanding of the human olfactory system has grown, so has our ability to design artificial devices that mimic its functionality, so called electronic noses (e-noses). This has led to the development of a more sophisticated biomimetic system known as an artificial olfactory mucosa (e-mucosa) that comprises a large distributed sensor array and artificial mucous layer. In order to exploit fully this new architecture, new approaches are required to analyzing the rich data sets that it generates. In this paper, we propose a novel convolution based approach to processing signals from the e-mucosa. Computer simulations are performed to investigate the robustness of this approach when subjected to different real-world problems, such as sensor drift and noise. Our results demonstrate a promising ability to classify odors from poor sensor signals

Electro-optic measurement of carrier mobility in an organic thin-film transistor

We have used an electro-optic technique to measure the position-dependent infrared absorption of holes injected into a thin crystal of the organic semiconductor, 6,13-bis(triisopropylsilylethynyl)-pentacene incorporated in a field-effect transistor. By applying square-wave voltages of variable frequency to the gate or drain, one can measure the time it takes for charges to accumulate on the surface, and therefore determine their mobility.Comment: 11 pages, 4 figures, to be published in Applied Physics Letter

Sonic limitations and startup problems of heat pipes

Introduction of small amounts of inert, noncombustible gas aids startup in certain types of heat pipes. When the heat pipe is closely coupled to the heat sink, the startup system must be designed to bring the heat sink on-line slowly