Electric and magnetic polarizabilities of hexagonal Ln2CuTiO6 (Ln=Y, Dy, Ho, Er and Yb)

We investigated the rare-earth transition metal oxide series, Ln2CuTiO6 (Ln=Y, Dy, Ho, Er and Yb), crystallizing in the hexagonal structure with non-centrosymmetric P63cm space group for possible occurrences of multiferroic properties. Our results show that while these compounds, except Ln=Y, exhibit a low temperature antiferromagnetic transition due to the ordering of the rare-earth moments, the expected ferroelectric transition is frustrated by the large size difference between Cu and Ti at the B-site. Interestingly, this leads these compounds to attain a rare and unique combination of desirable paraelectric properties with high dielectric constants, low losses and weak temperature and frequency dependencies. First-principles calculations establish these exceptional properties result from a combination of two effects. A significant difference in the MO5 polyhedral sizes for M = Cu and M = Ti suppress the expected co-operative tilt pattern of these polyhedra, required for the ferroelectric transition, leading to relatively large values of the dielectric constant for every compound investigated in this series. Additionally, it is shown that the majority contribution to the dielectric constant arises from intermediate-frequency polar vibrational modes, making it relatively stable against any temperature variation. Changes in the temperature stability of the dielectric constant amongst different members of this series are shown to arise from changes in relative contributions from soft polar modes.Comment: Accepted for publication in Phys. Rev. B (21 pages, 2 Table, 8 Figures

Tentative model for the incommensurate and ferroelectric phases in Pb₂CoWO₆

The sequence of cubic, incommensurate, and ferroelec. phases found in Pb2CoWO6 is described in the framework of the Landau theory. The model, which involves two different order parameters, accounts for the first-order character of the transitions, the reentrant behavior of the incommensurate phase, and its coexistence with the ferroelectric phase

Noble Gas Release during Reservoir Stimulation

ISSN:1029-7006ISSN:1607-796

The seismo-hydro-mechanical behaviour during deep geothermal reservoir stimulations: open question tackled in a decameter-scale in-situ stimulation experiment

In this contribution we present a review of scientific research results that address seismo-hydro-mechanical coupled processes relevant for the development of a sustainable heat exchanger in low permeability crystalline rock and introduce the design of the In-situ Stimulation and Circulation (ISC) experiment at the Grimsel Test Site dedicated to study such processes under controlled conditions. The review shows that research on reservoir stimulation for deep geothermal energy exploitation has been largely based on laboratory observations, large-scale projects and numerical models. Observations of full-scale reservoir stimulations have yielded important results. However, the limited access to the reservoir and limitations in the control on the experimental conditions during deep reservoir stimulations is insufficient to resolve the details of the hydro-mechanical processes that would enhance process understanding in a way that aids future stimulation design. Small scale laboratory experiments provide a fundamental insights into various processes relevant for enhanced geothermal energy, but suffer from 1) difficulties and uncertainties in upscaling the results to the field-scale and 2) relatively homogeneous material and stress conditions that lead to an over-simplistic fracture flow and/or hydraulic fracture propagation behaviour that is not representative for a heterogeneous reservoir. Thus, there is a need for intermediate-scale hydraulic stimulation experiments with high experimental control that bridge the various scales, and for which access to the target rock mass with a comprehensive monitoring system is possible. Only few intermediate-scale hydro-shearing and hydro-fracturing experiments have recently been performed in a densely instrumented rock mass. No such measurements have been performed on faults in crystalline basement rocks. The In-situ Stimulation and Circulation (ISC) experiment currently performed in a naturally fractured and faulted crystalline rock mass at the Grimsel Test Site (Switzerland) is designed to address open research questions, which could not be investigated in the required detail so far. Two hydraulic injection phases were executed to enhance the permeability of the rock mass: a hydro-shearing phase and then a hydraulic fracturing phase. During the injection phases the rock mass deformation across fractures and within intact rock, the pore pressure distribution and propagation and the micro-seismic response were monitored at a high spatial and temporal resolution.ISSN:1869-953