Substrate effect on the growth of iron clusters in Y zeolite

Investigation of the decomposition process and of the thermolytic products obtained from Fe(CO)5/faujasite adducts by thermogravimetric, IR-spectroscopic, Mössbauer spectroscopic and X-ray absorption measurements (EXAFS) provides evidence for a substrate effect on the growth process of iron clusters. CsY substrate increases the Fe---CO bond strength. The stabilized intermediates generated by this effect upon thermolysis at 500 K are easily oxidized to small iron(III) oxide clusters, whereas with NaY substrate to a large extent iron(O) particles are generated. The latter show Mössbauer effect and EXAFS spectra comparable to those obtained from bulk iron. An inner oxidation process is assumed to be involved in the generation of the zeolite-supported iron oxide

Energy Saving In Data Centers

Globally CO2 emissions attributable to Information Technology are on par with those resulting from aviation. Recent growth in cloud service demand has elevated energy efficiency of data centers to a critical area within green computing. Cloud computing represents a backbone of IT services and recently there has been an increase in high-definition multimedia delivery, which has placed new burdens on energy resources. Hardware innovations together with energy-efficient techniques and algorithms are key to controlling power usage in an ever-expanding IT landscape. This special issue contains a number of contributions that show that data center energy efficiency should be addressed from diverse vantage points. © 2017 by the authors. Licensee MDPI, Basel, Switzerland

Energy Efficiency and Renewable Energy Management with Multi-State Power-Down Systems

A power-down system has an on-state, an off-state, and a finite or infinite number of intermediate states. In the off-state, the system uses no energy and in the on-state energy it is used fully. Intermediate states consume only some fraction of energy but switching back to the on-state comes at a cost. Previous work has mainly focused on asymptotic results for systems with a large number of states. In contrast, the authors study problems with a few states as well as systems with one continuous state. Such systems play a role in energy-efficiency for information technology but are especially important in the management of renewable energy. The authors analyze power-down problems in the framework of online competitive analysis as to obtain performance guarantees in the absence of reliable forecasting. In a discrete case, the authors give detailed results for the case of three and five states, which corresponds to a system with on-off states and three additional intermediate states “power save”, “suspend”, and “hibernate”. The authors use a novel balancing technique to obtain optimally competitive solutions. With this, the authors show that the overall best competitive ratio for three-state systems is 95 role= presentation style= box-sizing: border-box; max-height: none; display: inline; line-height: normal; text-align: left; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative; \u3e95 and the authors obtain optimal ratios for various five state systems. For the continuous case, the authors develop various strategies, namely linear, optimal-following, progressive and exponential. The authors show that the best competitive strategies are those that follow the offline schedule in an accelerated manner. Strategy “progressive” consistently produces competitive ratios significantly better than 2

Inclusion Polymerization and Doping in Zeolite Channels. Polyaniline

Aniline has been polymerized in the three-dimensional channel system of zeolite Y. The monomer was diffused into zeolites with different levels of acidity from hexane solution. Subsequent admission of peroxydisulfate or iodate from aqueous solution yielded the intrazeolite polymers, as demonstrated by FT-IR, electronic absorption data and recovery of the included polymer. With S2O82-, the intrazeolite products are a function of the proton content of the zeolite. Polymer is only formed when a sufficient supply of protons is present in the zeolite host. When neutral iodate solution is used, no polymer is formed in NaY and acid zeolites, but at low pH aniline polymerizes in all zeolites. The open pore system of the zeolite host can be accessed by base such that the intrazeolite protonated polymer is transformed into the corresponding neutral polymer. The polymer chains encapsulated in zeolite hosts represent a new class of low- dimensional electronic materials

On the Effect of Quantum Interaction Distance on Quantum Addition Circuits

We investigate the theoretical limits of the effect of the quantum interaction distance on the speed of exact quantum addition circuits. For this study, we exploit graph embedding for quantum circuit analysis. We study a logical mapping of qubits and gates of any $\Omega(\log n)$-depth quantum adder circuit for two $n$-qubit registers onto a practical architecture, which limits interaction distance to the nearest neighbors only and supports only one- and two-qubit logical gates. Unfortunately, on the chosen $k$-dimensional practical architecture, we prove that the depth lower bound of any exact quantum addition circuits is no longer $\Omega(\log {n})$, but $\Omega(\sqrt[k]{n})$. This result, the first application of graph embedding to quantum circuits and devices, provides a new tool for compiler development, emphasizes the impact of quantum computer architecture on performance, and acts as a cautionary note when evaluating the time performance of quantum algorithms.Comment: accepted for ACM Journal on Emerging Technologies in Computing System