Hydrogen concentration measurements using a gel-filled electrochemical probe

A novel gel-filled electrochemical hydrogen probe was developed and used to measure hydrogen concentrations in carbon-manganese steels. The results were compared with those from an electrochemical permeation technique and a volumetric method. The probe was used to determine the distribution of hydrogen in 5mm steel plates cathodically charged on one side to represent the wall of a pipe or pressure vessel used in hydrogen service. The concentration measurements obtained by the three techniques were in good agreement with each other and with those predicted from diffusion equations and this permitted the precise boundary conditions on the charged metal surface to be determined. Surface reaction kinetics were investigated to model the hydrogen distribution and these were solved using solutions to Fick's diffusion equations. After long charging times the hydrogen concentration on the efflux surface of the plate approached that on the influx side, indicating that an almost uniform hydrogen distribution had been established. Rather than rapid loss of hydrogen from the free surface, as had been assumed previously, it was clear that there was a large resistance to hydrogen transport across the metal/air interface. Microstructural damage was examined both optically and using the scanning electron microscope. Separate investigations were carried out to help understand the effect that reversible and irreversible trapping had on the diffusion of hydrogen through the steel

Measurement of Time-of-Arrival in Quantum Mechanics

It is argued that the time-of-arrival cannot be precisely defined and measured in quantum mechanics. By constructing explicit toy models of a measurement, we show that for a free particle it cannot be measured more accurately then $\Delta t_A \sim 1/E_k$, where $E_k$ is the initial kinetic energy of the particle. With a better accuracy, particles reflect off the measuring device, and the resulting probability distribution becomes distorted. It is shown that a time-of-arrival operator cannot exist, and that approximate time-of-arrival operators do not correspond to the measurements considered here.Comment: References added. To appear in Phys. Rev.

Composite absorbing potentials

The multiple scattering interferences due to the addition of several contiguous potential units are used to construct composite absorbing potentials that absorb at an arbitrary set of incident momenta or for a broad momentum interval.Comment: 9 pages, Revtex, 2 postscript figures. Accepted in Phys. Rev. Let

Temporal Ordering in Quantum Mechanics

We examine the measurability of the temporal ordering of two events, as well as event coincidences. In classical mechanics, a measurement of the order-of-arrival of two particles is shown to be equivalent to a measurement involving only one particle (in higher dimensions). In quantum mechanics, we find that diffraction effects introduce a minimum inaccuracy to which the temporal order-of-arrival can be determined unambiguously. The minimum inaccuracy of the measurement is given by dt=1/E where E is the total kinetic energy of the two particles. Similar restrictions apply to the case of coincidence measurements. We show that these limitations are much weaker than limitations on measuring the time-of-arrival of a particle to a fixed location.Comment: New section added, arguing that order-of-arrival can be measured more accurately than time-of-arrival. To appear in Journal of Physics

Probability distribution of arrival times in quantum mechanics

In a previous paper [V. Delgado and J. G. Muga, Phys. Rev. A 56, 3425 (1997)] we introduced a self-adjoint operator $\hat {{\cal T}}(X)$ whose eigenstates can be used to define consistently a probability distribution of the time of arrival at a given spatial point. In the present work we show that the probability distribution previously proposed can be well understood on classical grounds in the sense that it is given by the expectation value of a certain positive definite operator $\hat J^{(+)}(X)$ which is nothing but a straightforward quantum version of the modulus of the classical current. For quantum states highly localized in momentum space about a certain momentum $p_0 \neq 0$, the expectation value of $\hat J^{(+)}(X)$ becomes indistinguishable from the quantum probability current. This fact may provide a justification for the common practice of using the latter quantity as a probability distribution of arrival times.Comment: 21 pages, LaTeX, no figures; A Note added; To be published in Phys. Rev.

Space-time properties of free motion time-of-arrival eigenstates

The properties of the time-of-arrival operator for free motion introduced by Aharonov and Bohm and of its self-adjoint variants are studied. The domains of applicability of the different approaches are clarified. It is shown that the arrival time of the eigenstates is not sharply defined. However, strongly peaked real-space (normalized) wave packets constructed with narrow Gaussian envelopes centred on one of the eigenstates provide an arbitrarily sharp arrival time.Comment: REVTEX, 12 pages, 4 postscript figure

Quantum probability distribution of arrival times and probability current density

This paper compares the proposal made in previous papers for a quantum probability distribution of the time of arrival at a certain point with the corresponding proposal based on the probability current density. Quantitative differences between the two formulations are examined analytically and numerically with the aim of establishing conditions under which the proposals might be tested by experiment. It is found that quantum regime conditions produce the biggest differences between the formulations which are otherwise near indistinguishable. These results indicate that in order to discriminate conclusively among the different alternatives, the corresponding experimental test should be performed in the quantum regime and with sufficiently high resolution so as to resolve small quantum efects.Comment: 21 pages, 7 figures, LaTeX; Revised version to appear in Phys. Rev. A (many small changes

Controlling trapping potentials and stray electric fields in a microfabricated ion trap through design and compensation

Recent advances in quantum information processing with trapped ions have demonstrated the need for new ion trap architectures capable of holding and manipulating chains of many (>10) ions. Here we present the design and detailed characterization of a new linear trap, microfabricated with scalable complementary metal-oxide-semiconductor (CMOS) techniques, that is well-suited to this challenge. Forty-four individually controlled DC electrodes provide the many degrees of freedom required to construct anharmonic potential wells, shuttle ions, merge and split ion chains, precisely tune secular mode frequencies, and adjust the orientation of trap axes. Microfabricated capacitors on DC electrodes suppress radio-frequency pickup and excess micromotion, while a top-level ground layer simplifies modeling of electric fields and protects trap structures underneath. A localized aperture in the substrate provides access to the trapping region from an oven below, permitting deterministic loading of particular isotopic/elemental sequences via species-selective photoionization. The shapes of the aperture and radio-frequency electrodes are optimized to minimize perturbation of the trapping pseudopotential. Laboratory experiments verify simulated potentials and characterize trapping lifetimes, stray electric fields, and ion heating rates, while measurement and cancellation of spatially-varying stray electric fields permits the formation of nearly-equally spaced ion chains.Comment: 17 pages (including references), 7 figure

Time in Quantum Mechanics and Quantum Field Theory

W. Pauli pointed out that the existence of a self-adjoint time operator is incompatible with the semibounded character of the Hamiltonian spectrum. As a result, people have been arguing a lot about the time-energy uncertainty relation and other related issues. In this article, we show in details that Pauli's definition of time operator is erroneous in several respects.Comment: 20 page

Time-of-Arrival States

Although one can show formally that a time-of-arrival operator cannot exist, one can modify the low momentum behaviour of the operator slightly so that it is self-adjoint. We show that such a modification results in the difficulty that the eigenstates are drastically altered. In an eigenstate of the modified time-of-arrival operator, the particle, at the predicted time-of-arrival, is found far away from the point of arrival with probability 1/2.Comment: 15 pages, 2 figure