Materiales activados alcalinamente a base de residuos de vidrio y escoria para aislamiento térmico y acústico

Porous alkali activated materials (AAM), can be obtained from waste glass powder and slag mixtures by alkali activation with NaOH solution. To obtain an adequate porous microstructure, the hardened AAM pastes were thermally treated at temperatures ranging between 900°C and 1000°C, for 60 or 30 minutes. Due to the intumescent behaviour specific for this type of materials, an important increase of the volume and porosity occurs during the thermal treatment. The partial substitution of waste glass powder with slag, determines the increase of compressive strength assessed before (up to 37 MPa) and after (around 10 MPa) thermal treatment; the increase of slag dosage also determines the increase of the activation temperature of the intumescent process (above 950°C). The high porosity and the specific microstructure (closed pores with various shapes and sizes) of these materials recommend them to be utilised as thermal and acoustical insulation materials.Los materiales activados alcalinamente porosos (AAM) se pueden obtener a base de polvo de residuos de vidrio y mezclas de escoria mediante activación alcalina con una solución de hidróxido de sodio (NaOH). Para obtener una microestructura porosa adecuada, las pastas de AAM endurecidas se trataron térmicamente a temperaturas que oscilan entre 900°C y 1000°C durante 60 o 30 minutos. Debido al comportamiento intumescente específico de este tipo de material, se produce un aumento significativo en el volumen y la porosidad durante el tratamiento térmico. La sustitución parcial del polvo de residuos de vidrio por escoria conlleva un aumento en las resistencias a compresión previamente evaluadas (hasta 37 MPa) y después (aproximadamente 10 MPa) del tratamiento térmico; el aumento de la dosis de escoria también determina el aumento de la temperatura de activación del proceso intumescente (por encima de 950°C). La alta porosidad y la microestructura específica de estos materiales recomiendan que se utilicen como materiales de aislamiento térmico y acústico

INFLUENCE OF THE NUMBER OF PASSES OF AGRICULTURAL MACHINERY ON PENETRATION RESISTANCE AND THE DEGREE OF SOIL COMPACTION

In the context of the ongoing development of mechanized agriculture, which implies the use of heavy agricultural machinery, often on soils with high moisture content, it increased significantly the risk of soil compaction. Compaction has become a problem of major proportions especially to farmers, because this phenomenon causes environmental damage, and affects soil quality and crop production. Penetration resistance is a valuable and easy to determine indicator of the degree of compaction of agricultural soil. In this paper are presented the results of some experimental research conducted to determine the penetration resistance of a plot of clover, under the influence of the number of passes of a tractor, in order to assess, from an qualitative point of view, the degree of soil compaction

Cellulose acetate membranes functionalized with resveratrol by covalent immobilization for improved osseointegration

Covalent immobilization of resveratrol onto cellulose acetate polymeric membranes used as coating on a Mg-1Ca-0.2Mn-0.6Zr alloy is presented for potential application in the improvement of osseointegration processes. For this purpose, cellulose acetate membrane is hydrolysed in the presence of potassium hydroxide, followed by covalent immobilization of aminopropyl triethoxy silane. Resveratrol was immobilized onto membranes using glutaraldehyde as linker. The newly synthesised functional membranes were thoroughly characterized for their structural characteristics determination employing X-ray photoelectron spectroscopy (XPS), infrared spectroscopy (FT-IR), Raman spectroscopy, thermogravimetric analysis (TGA/DTG) and scanning electron microscopy (SEM) techniques. Subsequently, in vitro cellular tests were performed for evaluating the cytotoxicity biocompatibility of synthesized materials and also the osseointegration potential of obtained derivatised membrane material. It was demonstrated that both polymeric membranes support viability and proliferation of the pre-osteoblastic MC3T3-E1 cells, thus providing a good protection against the potential harmful effects of the compounds released from coated alloys. Furthermore, cellulose acetate membrane functionalized with resveratrol exhibits a significant increase in alkaline phosphatase activity and extracellular matrix mineralization, suggesting its suitability to function as an implant surface coating for guided bone regeneration

TITANIUM FUNCTIONALIZING AND DERIVATIZING FOR IMPLANTABLE MATERIALS OSSEOINTEGRATION PROPERTIES ENHANCING

The article focuses on titanium functionalizing and derivatizing reactions for implantable materials osseointegration properties enhancing. Thus, the titanium dioxide was activated to the titanium hydroxide (functionalization), being further immobilized on the titanium surface by ethanolamine covalent reactions and (3-aminopropyl)triethoxysilane (APTS) for the osseointegration membranes reactive coating. The derivatizing was based on ether forming reactions between hydroxyl group from the titanium hydroxide surface and the ethanolamine hydroxyl groups and hydrolyzed APTS respectively. The obtained materials were characterized by scanning electron microscopy, FT-IR infrared spectroscopy, contact angle and X-Ray fluorescence

Childbearing intentions in a low fertility context: the case of Romania

This paper applies the Theory of Planned Behaviour (TPB) to find out the predictors of fertility intentions in Romania, a low-fertility country. We analyse how attitudes, subjective norms and perceived behavioural control relate to the intention to have a child among childless individuals and one-child parents. Principal axis factor analysis confirms which items proposed by the Generation and Gender Survey (GGS 2005) act as valid and reliable measures of the suggested theoretical socio-psychological factors. Four parity-specific logistic regression models are applied to evaluate the relationship between the socio-psychological factors and childbearing intentions. Social pressure emerges as the most important aspect in fertility decision-making among childless individuals and one-child parents, and positive attitudes towards childbearing are a strong component in planning for a child. This paper also underlines the importance of the region-specific factors when studying childbearing intentions: planning for the second child significantly differs among the development regions, representing the cultural and socio-economic divisions of the Romanian territory

Circulating adrenomedullin estimates survival and reversibility of organ failure in sepsis: the prospective observational multinational Adrenomedullin and Outcome in Sepsis and Septic Shock-1 (AdrenOSS-1) study

Background: Adrenomedullin (ADM) regulates vascular tone and endothelial permeability during sepsis. Levels of circulating biologically active ADM (bio-ADM) show an inverse relationship with blood pressure and a direct relationship with vasopressor requirement. In the present prospective observational multinational Adrenomedullin and Outcome in Sepsis and Septic Shock 1 (, AdrenOSS-1) study, we assessed relationships between circulating bio-ADM during the initial intensive care unit (ICU) stay and short-term outcome in order to eventually design a biomarker-guided randomized controlled trial. Methods: AdrenOSS-1 was a prospective observational multinational study. The primary outcome was 28-day mortality. Secondary outcomes included organ failure as defined by Sequential Organ Failure Assessment (SOFA) score, organ support with focus on vasopressor/inotropic use, and need for renal replacement therapy. AdrenOSS-1 included 583 patients admitted to the ICU with sepsis or septic shock. Results: Circulating bio-ADM levels were measured upon admission and at day 2. Median bio-ADM concentration upon admission was 80.5 pg/ml [IQR 41.5-148.1 pg/ml]. Initial SOFA score was 7 [IQR 5-10], and 28-day mortality was 22%. We found marked associations between bio-ADM upon admission and 28-day mortality (unadjusted standardized HR 2.3 [CI 1.9-2.9]; adjusted HR 1.6 [CI 1.1-2.5]) and between bio-ADM levels and SOFA score (p < 0.0001). Need of vasopressor/inotrope, renal replacement therapy, and positive fluid balance were more prevalent in patients with a bio-ADM > 70 pg/ml upon admission than in those with bio-ADM ≤ 70 pg/ml. In patients with bio-ADM > 70 pg/ml upon admission, decrease in bio-ADM below 70 pg/ml at day 2 was associated with recovery of organ function at day 7 and better 28-day outcome (9.5% mortality). By contrast, persistently elevated bio-ADM at day 2 was associated with prolonged organ dysfunction and high 28-day mortality (38.1% mortality, HR 4.9, 95% CI 2.5-9.8). Conclusions: AdrenOSS-1 shows that early levels and rapid changes in bio-ADM estimate short-term outcome in sepsis and septic shock. These data are the backbone of the design of the biomarker-guided AdrenOSS-2 trial. Trial registration: ClinicalTrials.gov, NCT02393781. Registered on March 19, 2015

On the definition and examples of cones and finsler spacetimes

The authors warmly acknowledge Professor Daniel Azagra (Universidad Complutense, Madrid) his advise on approximation of convex functions as well as Profs. Kostelecky (Indiana University), Fuster (University of Technology, Eindhoven), Stavrinos (University of Athens), Pfeifer (University of Tartu), Perlick (University of Bremen) and Makhmali (Institute of Mathematics, Warsaw) their comments on a preliminary version of the article. The careful revision by the referee is also acknowledged. This work is a result of the activity developed within the framework of the Programme in Support of Excellence Groups of the Region de Murcia, Spain, by Fundacion Seneca, Science and Technology Agency of the Region de Murcia. MAJ was partially supported by MINECO/FEDER project reference MTM2015-65430-P and Fundacion Seneca project reference 19901/GERM/15, Spain and MS by Spanish MINECO/ERDF project reference MTM2016-78807-C2-1-P.A systematic study of (smooth, strong) cone structures C and Lorentz–Finsler metrics L is carried out. As a link between both notions, cone triples (Ω,T,F), where Ω (resp. T) is a 1-form (resp. vector field) with Ω(T)≡1 and F, a Finsler metric on ker(Ω), are introduced. Explicit descriptions of all the Finsler spacetimes are given, paying special attention to stationary and static ones, as well as to issues related to differentiability. In particular, cone structures C are bijectively associated with classes of anisotropically conformal metrics L, and the notion of cone geodesic is introduced consistently with both structures. As a non-relativistic application, the time-dependent Zermelo navigation problem is posed rigorously, and its general solution is provided.MINECO/FEDER project, Spain MTM2015-65430-PFundacion Seneca 19901/GERM/15Spanish MINECO/ERDF project MTM2016-78807-C2-1-